trimethylsilyldiethylgermane

Base Information

• Chemical Name: trimethylsilyldiethylgermane
• CAS No.: 100460-02-4
• Molecular Formula: C₇H₂₀GeSi
• Molecular Weight: 204.911
• Mol file: 100460-02-4.mol

Synonyms:trimethylsilyldiethylgermane

Chemical Property of trimethylsilyldiethylgermane

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of trimethylsilyldiethylgermane

There total 2 articles about trimethylsilyldiethylgermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.6%

chloro-trimethyl-silane (75-77-4) + triethylgermyllithium (6727-87-3) + diethylgermane (1631-46-5) → trimethylsilyldiethylgermane (100460-02-4) + Triethylgerman (1188-14-3) + trimethylsilyltriethylgermane (7749-85-1)

Guidance literature:

In N,N,N,N,N,N-hexamethylphosphoric triamide; Mixt. of Et3GeLi and Et2Ge(H)2 in HMPA is stirred for 10 h at 25°C, then Me3SiCl is added and stirred for 1 h.; Addn. of water and hexane, organic layer is analyzed by GLC.;

DOI:10.1016/0022-328X(81)80004-6

Reference yield:

triethylgermyllithium (6727-87-3) + trimethylsilyldiethylgermyllithium (104585-84-4) → trimethylsilyldiethylgermane (100460-02-4) + bis(trimethylsilyl)diethylgermane (104585-86-6) + pentaethyldigermane (993-84-0) + Triethylgerman (1188-14-3) + trimethylsilyltriethylgermane (7749-85-1)

Guidance literature:

With water; In N,N,N,N,N,N-hexamethylphosphoric triamide; byproducts: (C2H5)2GeH2; react. in evacuated quartz tube, equimolar mixt. of Et3GeLi and Me3SiGeEt2Li stirred for 94 h at 25°C; hydrolysis; extn. with ether; not isolated, detected by GLC and mass spectrometry;

Reference yield: 81.0%

trimethylsilyldiethylgermane (100460-02-4) + diethylmercury (627-44-1) → bis(trimethylsilyldiethylgermyl)mercury (100471-86-1) + ethane (74-84-0)

Guidance literature:

byproducts: ethane; Et2Hg and Me3SiGeEt2(H) are placed in an ampoule (equipped with a magnetic stirrer) in flow argon, after stopping of Ar feed the ampoule is kept at a water bath at 40°C until completion of synthesis, heating is stopped.; React. mixt. is vac. distd.;

DOI:10.1016/0022-328X(81)80004-6

upstream raw materials:

chloro-trimethyl-silane

triethylgermyllithium

diethylgermane

trimethylsilyldiethylgermyllithium

Downstream raw materials:

pentaethyldigermane

tetraethyldigermane

Triethylgerman

hexaethyldigermane