[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane

Base Information

Chemical Name:[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane
CAS No.:313973-97-6
Molecular Formula:C₃₀H₂₄BiF₆NO₄
Molecular Weight:785.496
Hs Code.:

Synonyms:[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane

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Chemical Property of [(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane

Chemical Property:

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Technology Process of [(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane

There total 1 articles about [(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 121899-81-8
tris(2-methoxyphenyl)bismuth dichloride

: 22227-26-5
3,5-Bis(trifluoromethyl)benzamide

: 313973-97-6
[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane

Guidance literature:: With KOC(CH₃)3; In dichloromethane; under Ar; KOC(CH3)3 was added to a mixt. of the triarylbismuth dichloride, the amide and CH2Cl2 at -50°C, the mixt. was allowed to warm gradually to 25°C with stirring; the insol. solid was filtered through Celite, the filtrate was concd. under vac., the oily residue was crystd. from CH2Cl2/hexane;
DOI:10.1021/ja003623l

Reference yield: 92.0%

: 313973-97-6
[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane

: 762-42-5
dimethyl acetylenedicarboxylate

: (CH₃OC₆H₄)3BiC(CO₂CH₃)C(CO₂CH₃)NCOC₆H₃(CF₃)2

Guidance literature:: In dichloromethane; mixt. of Bi compd., dimethyl acetylenedicarboxylate (molar ratio 1:3), 4 ? molecular sieves, and CH2Cl2 stirred at room temp. for 20 h; filtered through Celite; filtrate concd. under reduced pressure; washedwith hexane; chromd. (silica gel column, CH2Cl2); recrystd.; elem. anal.;
DOI:10.1016/S0022-328X(00)00295-3

Reference yield:

: 313973-97-6
[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methoxyphenyl)-λ5-bismuthane

: 83724-41-8
tris(2-methoxyphenyl)bismuthine

: dimethyl 2-[3,5-bis(trifluoromethyl)phenyl]-oxazole-4,5-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane

2: 1,4-cyclohexadiene or 3-hexyne or cyclohexene / neat (no solvent)

With 1,4-cyclohexadiene or 3-hexyne or cyclohexene; In dichloromethane;
DOI:10.1016/S0022-328X(00)00295-3