(η5-C5Me5)2WO

Base Information

• Chemical Name: (η5-C5Me5)2WO
• CAS No.: 115795-92-1
• Molecular Formula: C₂₀H₃₀OW
• Molecular Weight: 470.308
• Mol file: 115795-92-1.mol

Synonyms:(η5-C5Me5)2WO

Chemical Property of (η5-C5Me5)2WO

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of (η5-C5Me5)2WO

There total 1 articles about (η5-C5Me5)2WO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Cp*2W((17)OH)H → bis(η(5)-pentamethylcyclopentadienyl)dihydridotungsten + (η5-C5Me5)2WO (115795-92-1) + 17O-water (13968-48-4)

Guidance literature:

In benzene-d6; thermolysis (60°C, ca. 1 d); 17O NMR;

DOI:10.1021/om00107a008

Reference yield:

tert.-butylhydroperoxide (75-91-2) + (η5-C5Me5)2WO (115795-92-1) → (η5-pentamethylcyclopentadienyl)(η1-pentamethylcyclopentadienyl)W(O)2 + tert-butyl alcohol (75-65-0)

Guidance literature:

In benzene-d6; excess Me3CO2H, 5 min at room temp.; observed by (1)H-NMR;

DOI:10.1016/S0277-5387(00)80724-X

Reference yield:

chloro-trimethyl-silane (75-77-4) + (η5-C5Me5)2WO (115795-92-1) → (η5-pentamethylcyclopentadienyl)2WCl2 + Hexamethyldisiloxane (107-46-0)

Guidance literature:

In benzene-d6; in a NMR tube, over the period of 36 h; observed by (1)H-NMR, equimolar amounts od (C5Me5)2WO and (C5Me5)2WCl2;

DOI:10.1016/S0277-5387(00)80724-X

Downstream raw materials:

Hexamethyldisiloxane

tert-butyl alcohol