((Et2O)μ-Li[PhB(μ-N(t)Bu)2])2Mg

Base Information

Chemical Name:((Et2O)μ-Li[PhB(μ-N(t)Bu)2])2Mg
CAS No.:881212-25-5
Molecular Formula:C₃₆H₆₆B₂Li₂MgN₄O₂
Molecular Weight:646.755
Hs Code.:

Synonyms:

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Chemical Property of ((Et2O)μ-Li[PhB(μ-N(t)Bu)2])2Mg

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Technology Process of ((Et2O)μ-Li[PhB(μ-N(t)Bu)2])2Mg

There total 5 articles about ((Et2O)μ-Li[PhB(μ-N(t)Bu)2])2Mg which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 60-29-7,927820-24-4
diethyl ether

: 478000-97-4
Li2[PhB(μ3-N(t)Bu)2]

: 677-22-5
tert-butylmagnesium chloride

: 881212-25-5
((Et2O)μ-Li[PhB(μ-N(t)Bu)2])2Mg

Guidance literature:: In diethyl ether; toluene; under Ar atm. soln. t-BuMgCl in Et2O was added to soln. Li2(PhB(μ3-N(t)Bu)2) in toluene and stirred at room temp. for 18 h; react. mixt. was filtered, solvent was removed in vacuo, residue was dissolved in Et2O, concd. and stored at room temp. for 30 min;
DOI:10.1021/ic0520014

Reference yield: 75.0%

: 60-29-7,927820-24-4
diethyl ether

: 478000-97-4
Li2[PhB(μ3-N(t)Bu)2]

: 7786-30-3
magnesium chloride

: 881212-25-5
((Et2O)μ-Li[PhB(μ-N(t)Bu)2])2Mg

Guidance literature:: In diethyl ether; under Ar atm. soln. Li2(PhB(μ3-N(t)Bu)2) in Et2O was added to MgCl2 at -78°C, allowed to warm to room temp. over 20 min and refluxed for 18 h; soln. was filtered, solvent was removed in vacuo, residue was washed with cold n-hexane; elem. anal.;
DOI:10.1021/ic0520014

Reference yield:

: 60-29-7,927820-24-4
diethyl ether

: 478000-97-4
Li2[PhB(μ3-N(t)Bu)2]

: 75-16-1
methylmagnesium bromide

: 881212-25-5
((Et2O)μ-Li[PhB(μ-N(t)Bu)2])2Mg

Guidance literature:: In diethyl ether; toluene; under Ar atm. soln. MeMgBr in Et2O was added to soln. Li2(PhB(μ3-N(t)Bu)2) in toluene and stirred at room temp. for 18 h; react. mixt. was filtered, solvent was removed in vacuo, residue was dissolved in Et2O, concd. and stored at room temp. for 30 min;
DOI:10.1021/ic0520014