iron(II) thiocyanate

Base Information

• Chemical Name: iron(II) thiocyanate
• CAS No.: 127795-40-8
• Molecular Formula: 2CNS*Fe
• Molecular Weight: 172.014
• Mol file: 127795-40-8.mol

Synonyms:

Chemical Property of iron(II) thiocyanate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of iron(II) thiocyanate

There total 52 articles about iron(II) thiocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iron(III) chloride hexahydrate + potassium thioacyanate (333-20-0) → iron(III) thiocyanate (4119-52-2,6010-09-9,16998-54-2,127795-40-8)

Guidance literature:

In methanol;

DOI:10.1016/j.ica.2014.01.032

Reference yield:

ammonium thiocyanate + iron(III) chloride (7705-08-0) → iron(III) thiocyanate (4119-52-2,6010-09-9,16998-54-2,127795-40-8)

Guidance literature:

In further solvent(s); reaction in abs. isoamyl alcohol;;

Reference yield:

iron(III) sulfate + potassium thioacyanate (333-20-0) → iron(III) thiocyanate (4119-52-2,6010-09-9,16998-54-2,127795-40-8)

Guidance literature:

In sulfuric acid; no reaction in 100% H2SO4;;

upstream raw materials:

mercury(II) thiocyanate

potassium thioacyanate

iron(III)

Thiocyanate

Downstream raw materials:

2-Methylcyclohexylthiocyanat

1,2-Dimethylcyclohexylthiocyanat

thiocyanic acid

carbon dioxide

Refernces

• 1、 Ganguli, Prabuddha,Guetlich, Philipp,Mueller, E. Wolfgang,Irler, Werner. "Further Studies on the Spin Cross-over Phenomenon in Di-isothiocyanatobis(1,10-phenanthroline)iron(II)". . p. 441 - 446. Retrieved 1981.
• 2、 Bassey, Euan N.,Cliffe, Matthew J.,Da Silva, Ivan,Dutton, Sian E.,Grey, Clare P.,Keyzer, Evan N.,Lee, Jeongjae,Manuel, Pascal,Paddison, Joseph A. M.. "Strengthening the Magnetic Interactions in Pseudobinary First-Row Transition Metal Thiocyanates, M(NCS)2". . p. 11627 - 11639. Retrieved 2020.
• 3、 Zheng, Sipeng,Reintjens, Niels R. M.,Siegler, Maxime A.,Roubeau, Olivier,Bouwman, Elisabeth,Rudavskyi, Andrii,Havenith, Remco W. A.,Bonnet, Sylvestre. "Stabilization of the Low-Spin State in a Mononuclear Iron(II) Complex and High-Temperature Cooperative Spin Crossover Mediated by Hydrogen Bonding". . p. 331 - 339. Retrieved 2016.
• 4、 Romero-Morcillo, Tania,De La Pinta, Noelia,Callejo, Lorena M.,Pieiro-Lpez, Luca,Muoz, M. Carmen,Madariaga, Gotzon,Ferrer, Sacramento,Breczewski, Tomasz,Corts, Roberto,Real, Jos A.. "Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal-Organic Frameworks". . p. 12112 - 12120. Retrieved 2015.
• 5、 Uhrecky, Róbert,Ondrejkovi?ová, Iveta,Lacková, Darina,Fáberová, Zuzana,Mroziński, Jerzy,Kalińska, Bozena,Padělková, Zdeňka,Koman, Marian. "New thiocyanato iron(II) complex with 3,5-bis(3-pyridyl)-1,2,4-thiadiazole: Synthesis, structure, magnetic and spectral properties". . p. 33 - 38. Retrieved 2014.
• 6、 Dinsdale,Lough,Lemaire. "Structure and magnetic properties of an unusual homoleptic iron(iii) thiocyanate dimer". . p. 11077 - 11082. Retrieved 2015.
• 7、 Huxel, Timo,Leone, Selina,Lan, Yanhua,Demeshko, Serhiy,Klingele, Julia. "2-Amino-4-(2-pyridyl)thiazole as chelating ligand: A dinuclear oxido-bridged ferric complex and mononuclear 3d metal complexes". . p. 3114 - 3124. Retrieved 2014.
• 8、 Philip, J. C.,Bramley, A.. "". . p. 795 - 795. Retrieved 1913.
• 9、 Dodsworth, Elaine S.,O'Grady, Peter J.,Nicholls, David,Roberts, David. "". . p. 1191 - 1196. Retrieved 1987.
• 10、 Yang, Feng-Lei,Chen, Ming-Guang,Li, Xiu-Ling,Tao, Jun,Huang, Rong-Bin,Zheng, Lan-Sun. "Two-dimensional iron(ii) networks - Guest-dependent structures and spin-crossover behaviors". . p. 4234 - 4242. Retrieved 2013.