Silane, (hexyloxy)trimethyl-

Base Information

• Chemical Name: Silane, (hexyloxy)trimethyl-
• CAS No.: 17888-62-9
• Molecular Formula: C9H22OSi
• Molecular Weight: 174.359
• Hs Code.: 2931900090
• European Community (EC) Number: 823-658-8
• DSSTox Substance ID: DTXSID30334042
• Nikkaji Number: J104.882A
• Wikidata: Q82099673
• Mol file: 17888-62-9.mol

Synonyms:Silane, (hexyloxy)trimethyl-;hexoxy(trimethyl)silane;(Hexyloxy)trimethylsilane;17888-62-9;Hexyl(trimethylsilyl) ether;1-Hexanol, TMS derivative;hexanoxytrimethylsilane;1-trimethylsilyloxyhexane;hexyloxy-trimethyl-silane;trimethyl-n-hexoxy silane;SCHEMBL594830;DTXSID30334042;Hexyl alcohol, trimethylsilyl ether

Chemical Property of Silane, (hexyloxy)trimethyl-

Chemical Property:

• PSA: 9.23000
• LogP: 3.41820
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 174.143991855
• Heavy Atom Count: 11
• Complexity: 86.1

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCO[Si](C)(C)C

Technology Process of Silane, (hexyloxy)trimethyl-

There total 7 articles about Silane, (hexyloxy)trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

trimethylsilyl formate (18243-21-5) + hexan-1-ol (111-27-3) → hexanoxytrimethylsilane (17888-62-9)

Guidance literature:

With [Ru(κ¹-OAc)(κ²-OAc)(κ³-1,1,1-tris(diphenylphosphinomethyl)ethane)]; In acetonitrile; at 70 ℃; for 1h; Inert atmosphere; Schlenk technique; Sealed tube;

Reference yield: 96.0%

1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) + hexan-1-ol (111-27-3) → hexanoxytrimethylsilane (17888-62-9)

Guidance literature:

With lithium perchlorate; silica gel; In dichloromethane; at 20 ℃; for 0.0833333h;

DOI:10.1016/j.jorganchem.2005.11.005

Reference yield: 92.6%

chloro-trimethyl-silane (75-77-4) + hexan-1-ol (111-27-3) → hexanoxytrimethylsilane (17888-62-9)

Guidance literature:

With urea; at 20 ℃; for 4h;

upstream raw materials:

chloro-trimethyl-silane

hexan-1-ol

Hexamethyldisiloxane

N,N-bis(trimethylsilyl)acetamide

Downstream raw materials:

Trimethylmethoxysilane

1-Allyl-1-hexyloxy-cyclohexane

hexan-1-ol

hexanal

Refernces

• 1、 Richter,W.J.,Hunnemann,D.H.. "-". . p. 1131 - 1136. Retrieved 1974.
• 2、 Chauvier, Clément,Godou, Timothé,Cantat, Thibault. "Silylation of O-H bonds by catalytic dehydrogenative and decarboxylative coupling of alcohols with silyl formates". supporting information. p. 11697 - 11700. Retrieved 2017/11/03.