Thallium, chlorodiphenyl-

Base Information

• Chemical Name: Thallium, chlorodiphenyl-
• CAS No.: 19859-84-8
• Molecular Formula: C12H10ClTl
• Molecular Weight: 394.047
• Mol file: 19859-84-8.mol

Synonyms:

Chemical Property of Thallium, chlorodiphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Thallium, chlorodiphenyl-

There total 18 articles about Thallium, chlorodiphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

thallium (III) chloride (13453-32-2) + phenyllithium (591-51-5) → diphenylthallium chloride (19859-84-8)

Guidance literature:

With HCl; In diethyl ether; byproducts: LiCl; TlCl3 in Et2O stirred at 0°C; added dropwise to PhLi soln.; heated under reflux for 2 h; stirred for 18 h at 20°C; poured into ice-cooled aq. HCl; stirred; suspn. filtered; precipitate washed with H2O, EtOH and Et2O; dried in vacuum; elem. anal.;

DOI:10.1002/zaac.200600092

Reference yield:

thallium (III) chloride (13453-32-2) + triphenylbismuthane (603-33-8) → bismuth(III) chloride (7787-60-2) + diphenylbismuth(III) chloride (5153-28-6) + diphenylthallium chloride (19859-84-8)

Guidance literature:

In chloroform; byproducts: C6H6; reflux, 5h;

DOI:10.1039/CT9222100104 DOI:10.1039/CT9242500864 DOI:10.1039/CT9222100036

Reference yield:

tetraphenyltin(IV) (595-90-4) + thallium (III) chloride (13453-32-2) → diphenyltin(IV) dichloride (1135-99-5) + triphenyltin chloride (639-58-7) + diphenylthallium chloride (19859-84-8)

Guidance literature:

In diethyl ether; xylene;

DOI:10.1039/CT9222100256

upstream raw materials:

triphenyl-arsane

tetraphenyltin(IV)

triphenylbismuthane

Tetraphenyllead

Downstream raw materials:

tetramethylammonium diphenylthallium chloride iodide

Na⁽¹⁺⁾*[(C₆H₅)2Tl(C₁₄H₉NO₃S)]^(1-)=Na[(C₆H₅)2Tl(C₁₄H₉NO₃S)]

Ph₂TlN(SO₂Me)2

diphenyl-thallium⁽¹⁺⁾; fluoride

Refernces

• 1、 Gun'kin. "Thallium(III) oxide as an oxidative reagent in organic chemistry". . p. 451 - 454. Retrieved 2010/08/04.
• 2、 Gun'kin. "Organothallium compounds. Reaction of phenylhydrazine with thallium(III) oxide". . p. 824 - 825. Retrieved 2007/10/03.