Silane, [[3-(3-fluorophenyl)-1-cyclohexen-1-yl]oxy]trimethyl-

Base Information

Chemical Name:Silane, [[3-(3-fluorophenyl)-1-cyclohexen-1-yl]oxy]trimethyl-
CAS No.:207917-03-1
Molecular Formula:C₁₅H₂₁FOSi
Molecular Weight:264.415
Hs Code.:
DSSTox Substance ID:DTXSID50445467
Nikkaji Number:J980.163D

Synonyms:Silane, [[3-(3-fluorophenyl)-1-cyclohexen-1-yl]oxy]trimethyl-;207917-03-1;DTXSID50445467;1-[3-(Trimethylsilyloxy)-2-cyclohexenyl]-3-fluorobenzene

Suppliers and Price of Silane, [[3-(3-fluorophenyl)-1-cyclohexen-1-yl]oxy]trimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, [[3-(3-fluorophenyl)-1-cyclohexen-1-yl]oxy]trimethyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:264.13456999
Heavy Atom Count:18
Complexity:308

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)OC1=CC(CCC1)C2=CC(=CC=C2)F

Technology Process of Silane, [[3-(3-fluorophenyl)-1-cyclohexen-1-yl]oxy]trimethyl-

There total 1 articles about Silane, [[3-(3-fluorophenyl)-1-cyclohexen-1-yl]oxy]trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 4096-34-8
cyclohex-3-enone

: 17318-03-5
bromo(3-fluorophenyl)magnesium

: 207917-03-1
3-(3-fluorophenyl)-1-trimethylsilyloxycyclohexene

Guidance literature:: With CuI*LiCl; Yield given;
DOI:10.1021/jo982195n

Reference yield:

: 67-56-1
methanol

: 109-92-2,25104-37-4
ethyl vinyl ether

: 207917-03-1
3-(3-fluorophenyl)-1-trimethylsilyloxycyclohexene

: 4-(3-Fluoro-phenyl)-2,7a-dimethoxy-octahydro-benzofuran

: 2-(2,2-Dimethoxy-ethyl)-3-(3-fluoro-phenyl)-cyclohexanone

Guidance literature:: With ammonium cerium(IV) nitrate; at 20 ℃; Title compound not separated from byproducts;
DOI:10.1021/jo972233n DOI:10.1021/jo048294k

Reference yield:

: 207917-03-1
3-(3-fluorophenyl)-1-trimethylsilyloxycyclohexene

: 843614-94-8
ethyl 2-(8-bromo-1,3-difluorophenanthren-2-yl)-2,3,3,3-tetrafluoropropionate

Guidance literature:: Multi-step reaction with 6 steps

1.1: ceric ammonium nitrate / methanol / 20 °C

1.2: 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; aq. H₂SO₄ / 0 °C

2.1: hydrazine monohydrate / benzene; ethanol / 80 °C

3.1: CuBr₂; t-BuOLi / tetrahydrofuran; hexane / 3 h / 20 °C

4.1: 65 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone / toluene / 5 h / 90 °C

5.1: 83 percent / BuLi; diisopropylamine / tetrahydrofuran; hexane / -50 - 25 °C

6.1: 65 percent / diethylaminosulfur trifluoride / CH₂Cl₂ / 0.5 h / 0 °C

With n-butyllithium; ammonium cerium(IV) nitrate; diethylamino-sulfur trifluoride; hydrazine hydrate; diisopropylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; copper(ll) bromide; lithium tert-butoxide; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; toluene; benzene;
DOI:10.1021/jo048294k