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Cas Database |
| Name |
SPERMIDINE |
EINECS | 204-689-0 |
| CAS No. | 124-20-9 | Density | 0.906 g/cm3 |
| PSA | 64.07000 | LogP | 1.45520 |
| Solubility | Miscible with water, ethanol and ether. | Melting Point |
23-25 °C |
| Formula | C7H19N3 | Boiling Point | 246.57 °C at 760 mmHg |
| Molecular Weight | 145.248 | Flash Point | 118.078 °C |
| Transport Information | UN 2735 8/PG 2 | Appearance | Colorless clear liquid |
| Safety | 26-36/37/39-45-27 | Risk Codes | 34 |
| Molecular Structure |
|
Hazard Symbols |
 C
|
| Synonyms |
1,4-Butanediamine,N-(3-aminopropyl)- (8CI,9CI);Spermidine (6CI);1,5,10-Triazadecane;1,8-Diamino-4-azaoctane;4-Azaoctane-1,8-diamine;N-(3-Aminopropyl)-1,4-butanediamine;N-(3-Aminopropyl)-1,4-diaminobutane;N-(3-Aminopropyl)-4-aminobutylamine;N-(4-Aminobutyl)-1,3-diaminopropane;Spermidine; |
Article Data | 28 |
SPERMIDINE Synthetic route
- 143565-69-9
4-aza-1,3-bis(1,3-dibenzylhexahydro-2-oxo-1,3,5-triazin-5-yl)octane
- 124-20-9
N-(3-aminopropyl)-1,4-diaminobutane
| Conditions | Yield |
|---|---|
| With piperidine In methanol at 65℃; | 90% |
- 177085-34-6
[4-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-butyl]-[3-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-propyl]-carbamic acid tert-butyl ester
- 124-20-9
N-(3-aminopropyl)-1,4-diaminobutane
| Conditions | Yield |
|---|---|
| With hydrazine hydrate In ethanol at 60℃; for 12h; | 45% |
- 124-20-9
N-(3-aminopropyl)-1,4-diaminobutane
| Conditions | Yield |
|---|---|
| With ammonia |
- 124-20-9
N-(3-aminopropyl)-1,4-diaminobutane
| Conditions | Yield |
|---|---|
| With hydrogenchloride; platinum Hydrogenation; |
- 34450-15-2, 120205-19-8
N8-acetylspermidine dihydrochloride
- 124-20-9
N-(3-aminopropyl)-1,4-diaminobutane
| Conditions | Yield |
|---|---|
| With hydrogenchloride |
| Conditions | Yield |
|---|---|
| With ammonia; hydrogen; nickel In ethanol |
| Conditions | Yield |
|---|---|
| With pyrroloquinoline quinone In water at 37℃; examination of PQQ oxidation effect; phosphate buffer (pH=7.2); |
- 71-44-3
Spermine
A
- 124-20-9
N-(3-aminopropyl)-1,4-diaminobutane
B
- 110-60-1
1,4-diaminobutane
C
- 107-02-8
acrolein
| Conditions | Yield |
|---|---|
| With phosphate buffer In water at 37℃; Product distribution; bovine serum amine oxidase; other polyamines; |
- 525-79-1
kinetin
A
- 124-20-9
N-(3-aminopropyl)-1,4-diaminobutane
B
- 71-44-3
Spermine
C
- 110-60-1
1,4-diaminobutane
| Conditions | Yield |
|---|---|
| at 30℃; for 24h; effect on poliamine content and ratio in rice embryos of Oryza sativa; |
- 14398-53-9
(R)-(-)-abscisic acid
A
- 124-20-9
N-(3-aminopropyl)-1,4-diaminobutane
B
- 71-44-3
Spermine
C
- 110-60-1
1,4-diaminobutane
| Conditions | Yield |
|---|---|
| at 30℃; for 24h; effect on poliamine content and ratio in rice embryos of Oryza sativa; |
SPERMIDINE Chemical Properties
IUPAC Name: N-(3-aminopropyl)Butane-1,4-diamine
Synonyms N-(3-Aminopropyl)-1,4-Butanediamine ; 1,8-Diamino-4-azaoctane
Molecular Structure: 
Molecular Formula : C7H19N3
Molecular Weight: 145.25
CAS : 124-20-9
EINECS: 204-689-0
Density : 0.925
Melting point: 22-25 ºC
Boiling point : 128-130 ºC
Refractive index : 1.4785-1.4805
Flash point: 112 ºC
Surface Tension: 37.5 dyne/cm
Enthalpy of Vaporization: 48.37 kJ/mol
Vapour Pressure: 0.0269 mmHg at 25°C
Storage temp: 2-8°C
Solubility : H2O: 1 M at 20 °C, clear, colorless
Appearance: Colorless clear liquid
Sensitive : Air Sensitive
Merck: 14,8742
BRN : 1698591
Stability: Stable, but air-sensitive and very hygroscopic - store under argon. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents.
SPERMIDINE Uses
Spermidine (CAS NO.124-20-9 ) has a protective effect of salt and senility.
SPERMIDINE Production
Spermidine (CAS NO.124-20-9 ) is widely distributed in vivo,and can be derived by biosynthesis of putrescine (putrescine) and adenosine-L-methionine
SPERMIDINE Toxicity Data With Reference
| 1. | oms-bcs 50 mg/L | MGGEAE Molecular and General Genetics. 178 (1980),21. | ||
| 2. | dnd-ham:ovr 300 µmol/L | CNREA8 Cancer Research. 46 (1986),175. | ||
| 3. | ivn-mus LD50:78 mg/kg | AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. 198 (1972),36. |
SPERMIDINE Consensus Reports
Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.
SPERMIDINE Safety Profile
Hazard Codes C .gif){kind=small}
Risk Statements 34
34: Causes burns
Safety Statements 26-36/37/39-45-27
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27: Take off immediately all contaminated clothing
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RIDADR UN 2735 8/PG 2
WGK Germany 3
RTECS EJ7000000
F 3-10-34
HazardClass 8
PackingGroup III
SPERMIDINE Specification
C1.
R34:Causes burns.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
2.Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use foam, dry chemical, or carbon dioxide
3.Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
4.Storage: Store Spermidine (CAS NO.124-20-9 ) in a tightly closed container. Store in a dry area. Keep refrigerated. (Store below 4°C/39°F.) Store under an inert atmosphere.
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