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Sulfurous acid

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Name

Sulfurous acid

EINECS 231-973-1
CAS No. 7782-99-2 Density 2.483 g/cm3
PSA 76.74000 LogP 0.54680
Solubility soluble in water Melting Point N/A
Formula H2O3S Boiling Point N/A
Molecular Weight 82.0801 Flash Point N/A
Transport Information UN 1833 8/PG 2 Appearance clear, colorless liquid
Safety 26-36/37/39-45 Risk Codes 20-34
Molecular Structure Molecular Structure of 7782-99-2 (Sulfurous acid) Hazard Symbols CorrosiveC
Synonyms

Schweflige saure;Schweflige saure [German];Sulfur dioxide solution;UNII-J1P7893F4J;

Article Data 208

Sulfurous acid Synthetic route

149-44-0

rongalite

A

36069-03-1

trithioformaldehyde

B

7446-09-5

sulfur dioxide

C

14808-79-8

Sulfate

D

7782-99-2

sulphurous acid

E

7704-34-9

sulfur

Conditions
ConditionsYield
With hydrogenchloride In not given byproducts: H2O, polythionic acids; digesting with HCl-soln.;A n/a
B 82%
C 0%
D n/a
E 82%
With HCl In not given byproducts: H2O, polythionic acids; digesting with HCl-soln.;A n/a
B 82%
C 0%
D n/a
E 82%

7,11b-dihydro-benzo[c]carbazole-1,6a-disulfonic acid

acid

acid

A

205-25-4

benzo[c]carbazole

B

7782-99-2

sulphurous acid

7647-01-0

hydrogenchloride

1,2-bis-[6]quinolylamino-ethane-1,2-disulfonic acid

A

580-15-4

6-aminoquinoline

B

131543-46-9

Glyoxal

C

7782-99-2

sulphurous acid

7647-01-0

hydrogenchloride

7-methoxy-1-methyl-β-carboline-9-sulfonic acid

A

442-51-3

harmine

B

7782-99-2

sulphurous acid

103264-22-8

4-methyl-quinoline-2-sulfonic acid

A

7782-99-2

sulphurous acid

B

2-oxy-4-methyl-quinoline

2-oxy-4-methyl-quinoline

2,5-dichloro-indol-3-one

sodium sulfite

sodium sulfite

A

17630-76-1

5-chloroindole 2,3-dione

B

7782-99-2

sulphurous acid

Conditions
ConditionsYield
at 90℃; Kochen der erhaltenen Natriumsalz mit Alkalien und folgenden Ansaeuern;

furan-2,3,5(4H)-trione pyridine (1:1)

60172-88-5

4,4'-diphenyl-2,4,2',4'-tetrahydro-5,5'-disulfanediyl-bis-[1,2,4]triazol-3-one

A

7782-99-2

sulphurous acid

B

sodium salt of 4-phenyl-3-mercapto-1.2.4-triazolone-(5)

sodium salt of 4-phenyl-3-mercapto-1.2.4-triazolone-(5)

7664-93-9

sulfuric acid

102-08-9

N,N-diphenylthiourea

A

463-79-6

carbonic-acid

B

7782-99-2

sulphurous acid

C

121-57-3

4-aminobenzene sulfonic acid

98-11-3

benzenesulfonic acid

A

127-63-9

diphenyl sulphone

B

7664-93-9

sulfuric acid

C

7782-99-2

sulphurous acid

D

71-43-2

benzene

Conditions
ConditionsYield
Destillation unter gewoehnlichem Druck;
7664-93-9

sulfuric acid

57-10-3

1-hexadecylcarboxylic acid

A

7782-99-2

sulphurous acid

B

carbon monoxide

carbon monoxide

Conditions
ConditionsYield
at 160 - 180℃;

Sulfurous acid Specification

The Sulfurous acid, with the CAS registry number 7782-99-2 and EINECS registry number 231-973-1, is also called Dihydrogen sulfite. It is a kind of air sensitive chemical, and belongs to the product category of Inorganics. And the molecular formula of the chemical is H2O3S. There is no evidence that sulfurous acid exists in solution, but the molecule has been detected in the gas phase. The conjugate bases of this elusive acid are, however, common anions, bisulfite (or hydrogensulfite) and sulfite. The conjugate bases of this elusive acid are, however, common anions, bisulfite (or hydrogensulfite) and sulfite.

The characteristics of Sulfurous acid are as followings: (1)ACD/LogP: -1.59; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -6.06; (4)ACD/LogD (pH 7.4): -6.09; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1 ; (7)#H bond acceptors: 3; (8)#H bond donors: 2; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 54.74 Å2; (11)Index of Refraction: 1.788; (12)Molar Refractivity: 13.98 cm3; (13)Molar Volume: 33 cm3; (14)olarizability: 5.54×10-24cm3; (15)Surface Tension: 291.3 dyne/cm; (16)Density: 2.483 g/cm3.

You should be cautious while dealing with this chemical. It is harmful by inhalation, and may cause burns. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice, or if in case of accident or if you feel unwell, seek medical advice immediately (show label where possible). 

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: O=S(O)O
(2)InChI: InChI=1/H2O3S/c1-4(2)3/h(H2,1,2,3)
(3)InChIKey: LSNNMFCWUKXFEE-UHFFFAOYAJ

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
human TDLo oral 500ug/kg (0.5mg/kg) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

GASTROINTESTINAL: NAUSEA OR VOMITING

GASTROINTESTINAL: OTHER CHANGES
Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 54, Pg. 421, 1906.

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