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Cas Database |
| Name |
Tetramethylammonium perchlorate |
EINECS | 219-805-5 |
| CAS No. | 2537-36-2 | Density | g/cm3 |
| PSA | 74.27000 | LogP | 0.53670 |
| Solubility | Soluble in water. | Melting Point |
300 °C |
| Formula | C8H20N•ClO4 | Boiling Point | °Cat760mmHg |
| Molecular Weight | 173.597 | Flash Point | °C |
| Transport Information | N/A | Appearance | solid |
| Safety | Poison by intravenous route. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl−. See also PERCHLORATES. | Risk Codes | 8 |
| Molecular Structure |
|
Hazard Symbols |
 
|
| Synonyms |
Tetramethylammonium perchlorate;Methanaminium, N,N, N-trimethyl-, perchlorate; |
Article Data | 10 |
Tetramethylammonium perchlorate Synthetic route
- 67-56-1
methanol
- 75-59-2
tetramethyl ammoniumhydroxide
A
- 598-98-1
Methyl pivalate
C
- 2537-36-2
tetramethylammonium perchlorate
| Conditions | Yield |
|---|---|
| Stage #1: methanol; C21H30N4OPbS(2+)*2ClO4(1-); tetramethyl ammoniumhydroxide at 20℃; for 24h; Stage #2: tetramethyl ammoniumhydroxide In water for 0.333333h; | A n/a B 96% C n/a |
- 21511-55-7, 34643-89-5
(methoxymethylidene)dimethylammonium methyl sulfate
- 4637-24-5
N,N-dimethyl-formamide dimethyl acetal
- 2537-36-2
tetramethylammonium perchlorate
| Conditions | Yield |
|---|---|
| With silver perchlorate |
| Conditions | Yield |
|---|---|
| With sodium perchlorate In water |
| Conditions | Yield |
|---|---|
| In further solvent(s) addition of tetramethyl ammoniumchloride to AgClO4 in molten SbCl3;; extraction of the perchlorate with hot H2O;; |
| Conditions | Yield |
|---|---|
| In further solvent(s) addition of tetramethyl ammoniumbromide to AgClO4 in molten SbBr3, conductometric titration;; extraction of the perchlorate with hot H2O;; |
- 999-77-9
tetramethylammonium azide
A
- 7727-37-9
nitrogen
B
- 2537-36-2
tetramethylammonium perchlorate
C
- 10024-97-2
dinitrogen monoxide
| Conditions | Yield |
|---|---|
| In liquid sulphur dioxide | A n/a B >99 C n/a |
| In sulfur dioxide | A n/a B >99 C n/a |
- 75-57-0
tetramethlyammonium chloride
A
- 2537-36-2
tetramethylammonium perchlorate
B
- 2696-92-6
nitrosylchloride
| Conditions | Yield |
|---|---|
| In neat (no solvent) |
| Conditions | Yield |
|---|---|
| With perchloric acid |
- 811-98-3
d(4)-methanol
- 75-59-2
tetramethyl ammoniumhydroxide
A
- 34949-25-2
pivalate de methyle d3
C
- 2537-36-2
tetramethylammonium perchlorate
| Conditions | Yield |
|---|---|
| In [D3]acetonitrile Kinetics; |
- 811-98-3
d(4)-methanol
- 75-59-2
tetramethyl ammoniumhydroxide
A
- 34949-25-2
pivalate de methyle d3
C
- 2537-36-2
tetramethylammonium perchlorate
| Conditions | Yield |
|---|---|
| In [D3]acetonitrile Kinetics; Mechanism; Activation energy; |
Tetramethylammonium perchlorate Chemical Properties
IUPAC Name: Tetramethylammonium perchlorate
Synonyms: N,N,N-Trimethylmethanaminium perchlorate ; Ammonium, tetramethyl-, perchlorate ; Methanaminium, N,N,N-trimethyl-, perchlorate
CAS NO: 2537-36-2
Molecular Formula of Tetramethylammonium perchlorate (CAS NO.2537-36-2) : C4H12ClNO4
Molecular Weight of Tetramethylammonium perchlorate (CAS NO.2537-36-2) : 173.6
Molecular Structure of Tetramethylammonium perchlorate (CAS NO.2537-36-2): .png)
EINECS: 219-805-5
Melting point: 300 °C
Stability: Stable. Incompatible with strong oxidizing agents.
Appearance:solid
Tetramethylammonium perchlorate Toxicity Data With Reference
| 1. | ivn-mus LD50:56 mg/kg | CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#01268 . |
Tetramethylammonium perchlorate Consensus Reports
Reported in EPA TSCA Inventory.
Tetramethylammonium perchlorate Safety Profile
Poison by intravenous route. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl−. See also PERCHLORATES.
Hazard Codes
O,
Xi
Risk Statements 8-36/37/38
R8 :Contact with combustible material may cause fire.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 17-36-26
S17:Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
RIDADR UN1479
RTECS BS8250000
HazardClass 5.1
PackingGroup II
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