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2537-36-2

Basic Information
CAS No.: 2537-36-2
Name: TETRAMETHYLAMMONIUM PERCHLORATE
Article Data: 10
Molecular Structure:
Molecular Structure of 2537-36-2 (TETRAMETHYLAMMONIUM PERCHLORATE)
Formula: C8H20N•ClO4
Molecular Weight: 173.597
Synonyms: Tetramethylammonium perchlorate;Methanaminium, N,N, N-trimethyl-, perchlorate;
EINECS: 219-805-5
Density: g/cm3
Melting Point: 300 °C
Boiling Point: °Cat760mmHg
Flash Point: °C
Solubility: Soluble in water.
Appearance: solid
Hazard Symbols:
Risk Codes: 8
Safety: Poison by intravenous route. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl. See also PERCHLORATES.
PSA: 74.27000
LogP: 0.53670
Synthetic route
67-56-1

methanol

C21H30N4OPbS(2+)*2ClO4(1-)

75-59-2

tetramethyl ammoniumhydroxide

A

598-98-1

Methyl pivalate

B

N-((ethylthio)ethyl)-N-((6-amino-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine

C

2537-36-2

tetramethylammonium perchlorate

Conditions
ConditionsYield
Stage #1: methanol; C21H30N4OPbS(2+)*2ClO4(1-); tetramethyl ammoniumhydroxide at 20℃; for 24h;
Stage #2: tetramethyl ammoniumhydroxide In water for 0.333333h;
A n/a
B 96%
C n/a
21511-55-7, 34643-89-5

(methoxymethylidene)dimethylammonium methyl sulfate

4637-24-5

N,N-dimethyl-formamide dimethyl acetal

2537-36-2

tetramethylammonium perchlorate

Conditions
ConditionsYield
With silver perchlorate
64-20-0

tetramethylammonium bromide

2537-36-2

tetramethylammonium perchlorate

Conditions
ConditionsYield
With sodium perchlorate In water

silver perchlorate

75-57-0

tetramethlyammonium chloride

A

2537-36-2

tetramethylammonium perchlorate

B

silver(I) chloride

Conditions
ConditionsYield
In further solvent(s) addition of tetramethyl ammoniumchloride to AgClO4 in molten SbCl3;; extraction of the perchlorate with hot H2O;;
64-20-0

tetramethylammonium bromide

silver perchlorate

A

silver(I) bromide

B

2537-36-2

tetramethylammonium perchlorate

Conditions
ConditionsYield
In further solvent(s) addition of tetramethyl ammoniumbromide to AgClO4 in molten SbBr3, conductometric titration;; extraction of the perchlorate with hot H2O;;

nitrosonium perchlorate

999-77-9

tetramethylammonium azide

A

7727-37-9

nitrogen

B

2537-36-2

tetramethylammonium perchlorate

C

10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In liquid sulphur dioxideA n/a
B >99
C n/a
In sulfur dioxideA n/a
B >99
C n/a

nitrosonium perchlorate

75-57-0

tetramethlyammonium chloride

A

2537-36-2

tetramethylammonium perchlorate

B

2696-92-6

nitrosylchloride

Conditions
ConditionsYield
In neat (no solvent)
75-59-2

tetramethyl ammoniumhydroxide

2537-36-2

tetramethylammonium perchlorate

Conditions
ConditionsYield
With perchloric acid
811-98-3

d(4)-methanol

[(N-((2-ethylthio)ethyl)-N-((6-pivaloylamido-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)-Zn](ClO4)2

75-59-2

tetramethyl ammoniumhydroxide

A

34949-25-2

pivalate de methyle d3

B

C17H20(2)H5N4OSZn(1+)*ClO4(1-)

C

2537-36-2

tetramethylammonium perchlorate

Conditions
ConditionsYield
In [D3]acetonitrile Kinetics;
811-98-3

d(4)-methanol

C21H30N4OPbS(2+)*2ClO4(1-)

75-59-2

tetramethyl ammoniumhydroxide

A

34949-25-2

pivalate de methyle d3

B

C16H20(2)H2N4S

C

2537-36-2

tetramethylammonium perchlorate

Conditions
ConditionsYield
In [D3]acetonitrile Kinetics; Mechanism; Activation energy;
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    TETRAMETHYLAMMONIUM PERCHLORATE

    In 1846 the entrepreneur Mansuke Nakarai founded his apothecary business for Japanese and Chinese medicines. In 1906 the company started business activities for Western pharmaceuti

  • Nacalai Tesque, Inc.

    Japan  |  Contact Details

    Business Type:Trading Company

    Tel:81 75 251 1723 81-75-251-1730

    Address:Nijo Karasuma, Nakagyo-ku Kyoto 604-0855 Japan

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Chemistry

IUPAC Name: Tetramethylammonium perchlorate
Synonyms: N,N,N-Trimethylmethanaminium perchlorate ; Ammonium, tetramethyl-, perchlorate ; Methanaminium, N,N,N-trimethyl-, perchlorate
CAS NO: 2537-36-2
Molecular Formula of Tetramethylammonium perchlorate (CAS NO.2537-36-2) : C4H12ClNO4
Molecular Weight of Tetramethylammonium perchlorate (CAS NO.2537-36-2) : 173.6
Molecular Structure of Tetramethylammonium perchlorate (CAS NO.2537-36-2):
EINECS: 219-805-5
Melting point: 300 °C
Stability: Stable. Incompatible with strong oxidizing agents.
Appearance:solid
 

Toxicity Data With Reference

1.    

ivn-mus LD50:56 mg/kg

    CSLNX*    U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#01268 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intravenous route. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl. See also PERCHLORATES.
Hazard CodesOxidizingO,IrritantXi
Risk Statements 8-36/37/38
R8 :Contact with combustible material may cause fire. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 17-36-26
S17:Keep away from combustible material. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
RIDADR UN1479
RTECS BS8250000
HazardClass 5.1
PackingGroup II