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75-57-0

Basic Information
CAS No.: 75-57-0
Name: Tetramethyl ammonium chloride
Molecular Structure:
Molecular Structure of 75-57-0 (Tetramethyl ammonium chloride)
Formula: C4H12NCl
Molecular Weight: 109.62
Synonyms: Ammonium,tetramethyl-, chloride (8CI);Methanaminium, N,N,N-trimethyl-, chloride (9CI);Tetramethylammonium chloride (6CI);Tetramine chloride;
EINECS: 200-880-8
Density: 1.17 g/cm3
Melting Point: >300 °C(lit.)
Boiling Point: 165.26°C (rough estimate)
Flash Point:
Solubility: >60 g/100 mL (20 °C ) in water
Appearance: white crystals
Hazard Symbols: ToxicT, HarmfulXn
Risk Codes: 21-25-36/37/38-20/21/22
Safety: 26-36/37-45-37/39-28A-28-36
Transport Information: UN 2811 6.1/PG 2
PSA: 0.00000
LogP: -2.67360
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  • High Quality Tetramethylammonium chloride

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  • Casno:

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  • 75-57-0

  • Casno:

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  • Tetramethyl ammonium chloride

  • Casno:

    75-57-0

    Tetramethyl ammonium chloride

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Consensus Reports

Reported in EPA TSCA Inventory.

Specification

Tetramethyl ammonium chloride, with CAS number of 75-57-0, can be called methanaminium, N,N,N-trimethyl-, chloride (1:1); N,N,N-Trimethylmethanaminium chloride; TMAC. The chemical formula (CH3)4N+Cl- is often abbreviated further as Me4N+Cl-. It is a white crystal. It is a very hygroscopic colourless solid that is soluble in water and polar organic solvents.

Preparation of Tetramethyl ammonium chloride: Tetramethylammonium chloride can be synthesized by the alkylation of ammonium chloride with dimethyl carbonate, in the presence of 1-ethyl-3-methyl imidazolium bromide ([EMIM]+Br-) as an ionic liquid catalyst. The overall reaction is:
NH4+Cl- + 2 (CH3O)2CO → N(CH3)4+Cl- + 2 H2O + 2 CO2

Uses of Tetramethyl ammonium chloride: Tetramethyl ammonium chloride (CAS NO.75-57-0) is used as a phase transfer catalyst for anionic reactants. In small concentrations, also has been shown to enhance yield 5-10 fold at 3M by stabilizing the AT base pairs. Besidea used with polymerase chain reactions to increase yield and specificity.

When you are using this chemical, please be cautious about it as the following:
1. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;
2. Wear suitable protective clothing and gloves;
3. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible);
4. Wear suitable gloves and eye/face protection;
5. After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer);

You can still convert the following datas into molecular structure:
(1)InChI=1S/C4H12N.ClH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1;
(2)InChIKey=OKIZCWYLBDKLSU-UHFFFAOYSA-M;
(3)Smiles[N+](C)(C)(C)C.[ClH-];

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
frog LDLo subcutaneous 2gm/kg (2000mg/kg) PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)

CARDIAC: OTHER CHANGES
Skandinavisches Archiv fuer Physiologie. Vol. 10, Pg. 201, 1900.
guinea pig LDLo unreported 20mg/kg (20mg/kg) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Archives Internationales de Pharmacodynamie et de Therapie. Vol. 7, Pg. 183, 1900.
mouse LD50 intraperitoneal 10mg/kg (10mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) National Technical Information Service. Vol. OTS0536975,
mouse LD50 subcutaneous 40mg/kg (40mg/kg)   National Technical Information Service. Vol. ORNL-5576,
mouse LDLo oral 125mg/kg (125mg/kg)   Journal of Pharmaceutical Sciences. Vol. 69, Pg. 327, 1980.
 
mouse LDLo unreported 20mg/kg (20mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

BEHAVIORAL: ATAXIA
Archives Internationales de Pharmacodynamie et de Therapie. Vol. 7, Pg. 183, 1900.
rabbit LDLo subcutaneous 6mg/kg (6mg/kg) VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Archives Internationales de Pharmacodynamie et de Therapie. Vol. 7, Pg. 183, 1900.
rat LD50 intraperitoneal 10mg/kg (10mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

VASCULAR: REGIONAL OR GENERAL ARTERIOLAR OR VENOUS DILATION

LUNGS, THORAX, OR RESPIRATION: CYANOSIS
National Technical Information Service. Vol. OTS0536975,
rat LD50 oral 50mg/kg (50mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

SKIN AND APPENDAGES (SKIN): HAIR: OTHER

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
National Technical Information Service. Vol. OTS0536975,

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