Electrochemical reduction involves using an electrode (usually a cathode) to transfer electrons to the starting material. The conditions of the reduction (e.g., solvent, temperature, and current) need to be optimized to achieve the desired stereoselectivity. The chiral auxiliary and the reaction conditions should be chosen to favor the formation of the (1R,3R,4S) stereoisomer.
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(2R,5R)-2-(1-methyl-1-phenylethyl)-5-methylcyclohexanone
4,4,5,5-tetramethyl-2-(4-(1-phenylethyl)phenyl)-1,3,2-dioxaborolane
1-naphtyl phenacyl sulfide
trans-bis(tricyclohexylphosphine)(2-methylphenyl)nickel(II) chloride
5,5-dimethyl-2-dimethylamino-3-phenyl-oxazolidine-4-one
Benzenesulfonamide, N-[1,2,3,3a,4,8b-hexahydro-3a-hydroxy-6,8b-dimethyl-1-oxo-4-(phenyl methyl)cyclopent[b]indol-7-yl]-4-methyl-N-(phenylmethyl)-
1,2-diphenyl-1H-indene
Benzoic acid, 2,4-dichloro-3-methoxy-
