MECHANISM OF ONE-ELECTRON ELECTROCHEMICAL REDUCTIVE CLEAVAGE REACTIONS OF SULFONIUM SALTS.

DOI: 10.1021/ja00327a010

Source and publish data:

Journal of the American Chemical Society p. 4121 - 4125 (1984)

Update date:2022-07-30

Topics: Mechanism Electrochemical Reduction

Authors:

Saeva Saeva

Morgan Morgan

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Article abstract of DOI:10.1021/ja00327a010

Irreversible one-electron reduction potentials (E//p) were measured for 12 arylmethyl(substituted-alkyl)sulfonium salts (aryl equals phenyl and 1-naphthyl). One-electron reduction produced homolytic sulfur-carbon sigma -bond cleavage in each of the sulfon

Full text of DOI:10.1021/ja00327a010

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