Electrochemical Reduction of 2-Bromo-carboxamides. Self-protonation Mechanism and Reaction with Dimethylformamide

DOI: 10.1039/c39850000660

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 660 (1985)

Update date:2022-09-26

Topics: Mechanism Dimethylformamide Reaction Electrochemical Reduction

Authors:

Maran, Flavio

Vianello, Elio

Cavicchioni, Giorgio

D'Angeli, Ferruccio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850000660

Electrochemical reduction of 2-bromo-carboxamides involves self-protonation of the electrogenerated bases and affords, among other products, cyclo-adducts incorporating a dimethylformamide unit.

Full text of DOI:10.1039/c39850000660

View Article Online / Journal Homepage / Table of Contents for this issue

Products guided by the article

Product name:5,5-dimethyl-2-dimethylamino-3-phenyl-oxazolidine-4-one

Cas No:98583-83-6

R&D Labs maybe for 98583-83-6

SHANGHAI SYSTEAM BIOCHEM CO., LTD

website:http://www.systeambc.com

Contact:86-021-58380978

Address:Building 87，Lane 669， Dong Jing Road Shanghai,P.R.China
LINYI FUDE FINE CHEMICAL CO.,LTD

Contact:86-539-2361184

Address:YISHUI, LINYI,SAHNDONG,CHINA
Radiant Pharma & Tech Company

Contact:+86-511-88790000

Address:338 North Yushan Rd, Zhenjiang, Jiangsu 212016
Shanghai Pinewood Fine Chemical Co., Ltd.

website:http://www.pinewoodchem.com

Contact:0086-21-62417129，62414096

Address:Suite B, 27F, No.2, Lane 600, Tianshan Road, Shanghai
Jiangxi Hessence Chemicals Co., Ltd.

Contact:+86 796 3511924

Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.

Relevant to this article

Practical and Selective sp³ C?H Bond Chlorination via Aminium Radicals

Doi:10.1002/anie.202100030
(2021)
Synthesis and hybridization properties of oligodeoxynucleotides with long-chain linkers

Doi:10.1002/hlca.200790203
(2007)
Biosynthetic tailoring of microcin E492m: Post-translational modification affords an antibacterial siderophore-peptide conjugate

Doi:10.1021/ja074650f
(2007)
One-Pot Synthesis of Substituted Benzo[b]furans and Indoles from Dichlorophenols/Dichloroanilines Using a Palladium-Dihydroxyterphenylphosphine Catalyst

Doi:10.1021/acs.joc.6b00824
(2016)
Convergent Versus Divergent Three-Step Synthesis of the First (4-Aminophenoxy)alkanoic Acid-Based Tripodal Melamines

Doi:10.1080/00397911.2015.1041048
(2015)
Sintered silicon carbide: A new ceramic vessel material for microwave chemistry in single-mode reactors

Doi:10.1002/chem.201001703
(2010)

Article Doi