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Trimethylsilyl methacrylate

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Name

Trimethylsilyl methacrylate

EINECS N/A
CAS No. 13688-56-7 Density 0.888 g/cm3
PSA 26.30000 LogP 1.94060
Solubility N/A Melting Point N/A
Formula C7H14O2Si Boiling Point 146.824 °C at 760 mmHg
Molecular Weight 158.272 Flash Point 30.079 °C
Transport Information N/A Appearance clear slightly yellow liquid
Safety 22-26-36/37 Risk Codes 10-36/37/38-42/43
Molecular Structure Molecular Structure of 13688-56-7 (TRIMETHYLSILYL METHACRYLATE) Hazard Symbols HarmfulXn
Synonyms

Methacrylic acid,trimethylsilyl ester (7CI,8CI);Silanol, trimethyl-, methacrylate (6CI);T3633;Trimethylsilyl 2-methylacrylate;

Article Data 15

Trimethylsilyl methacrylate Synthetic route

80-62-6

methacrylic acid methyl ester

heptamethyltrisiloxane

heptamethyltrisiloxane

13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With tris(pentafluorophenyl)borate; 4-methoxy-phenol In tetrahydrofuran for 0.75h; Green chemistry;90.1%
79-41-4

poly(methacrylic acid)

18297-63-7

N,N'-bis(trimethylsilyl)urea

13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
In dichloromethane at 40℃; for 2h;80%
79-41-4

poly(methacrylic acid)

107-46-0

Hexamethyldisiloxane

13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With ammonium sulfate at 120℃;56%
75-77-4

chloro-trimethyl-silane

79-41-4

poly(methacrylic acid)

13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With N,N-diethylaniline
With 1-methyl-1H-imidazole at 45 - 90℃; for 3.75h; Product distribution / selectivity; Inert atmosphere; Industry scale;99 %Chromat.
75-77-4

chloro-trimethyl-silane

5536-61-8

sodium methacrylate

13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With hydroquinone In benzene
43112-38-5

3-(trimethylsilyl)-2-oxazolidinone

79-41-4

poly(methacrylic acid)

13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With triethylamine In dichloromethane for 0.5h; Ambient temperature;
79-41-4

poly(methacrylic acid)

999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With hydroquinone for 3h; Heating;
79-41-4

poly(methacrylic acid)

2754-27-0

trimethylsilyl acetate

13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
In hexane
427-36-1

trityl fluoride

13688-56-7

trimethylsilyl methacrylate

A

420-56-4

trimethylsilyl fluoride

B

19302-93-3

2-methylacrylic acid trityl ester

Conditions
ConditionsYield
With silicon tetrafluoride In acetonitrile at 14℃; for 6h;A n/a
B 94%
993-07-7

trimethylsilan

13688-56-7

trimethylsilyl methacrylate

31469-25-7

1,1-bis(trimethylsiloxy)-2-methylprop-1-ene

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; rhodium(III) chloride In tetrahydrofuran at 40 - 50℃;78%

Trimethylsilyl methacrylate Specification

The 2-Propenoic acid,2-methyl-, trimethylsilyl ester is an organic compound with the formula C7H14O2Si. The IUPAC name of this chemical is trimethylsilyl 2-methylprop-2-enoate. With the CAS registry number 13688-56-7, it is also named as Trimethylsilyl-2-methylacrylat.

Physical properties about 2-Propenoic acid,2-methyl-, trimethylsilyl ester are: (1)ACD/LogP: 2.39; (2)ACD/LogD (pH 5.5): 2.39; (3)ACD/LogD (pH 7.4): 2.39; (4)ACD/BCF (pH 5.5): 38.32; (5)ACD/BCF (pH 7.4): 38.32; (6)ACD/KOC (pH 5.5): 473.14; (7)ACD/KOC (pH 7.4): 473.14; (8)#H bond acceptors: 2; (9)#Freely Rotating Bonds: 3; (10)Polar Surface Area: 26.3 Å2; (11)Index of Refraction: 1.414; (12)Molar Refractivity: 44.53 cm3; (13)Molar Volume: 178.1 cm3; (14)Polarizability: 17.65×10-24cm3; (15)Surface Tension: 20.6 dyne/cm; (16)Density: 0.888 g/cm3; (17)Flash Point: 30.1 °C; (18)Enthalpy of Vaporization: 38.38 kJ/mol; (19)Boiling Point: 146.8 °C at 760 mmHg; (20)Vapour Pressure: 4.55 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(O[Si](C)(C)C)\C(=C)C
(2)InChI: InChI=1/C7H14O2Si/c1-6(2)7(8)9-10(3,4)5/h1H2,2-5H3
(3)InChIKey: PGQNYIRJCLTTOJ-UHFFFAOYAV
(4)Std. InChI: InChI=1S/C7H14O2Si/c1-6(2)7(8)9-10(3,4)5/h1H2,2-5H3
(5)Std. InChIKey: PGQNYIRJCLTTOJ-UHFFFAOYSA-N

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