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CAS No.: | 993-07-7 |
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Name: | TRIMETHYLSILANE |
Article Data: | 135 |
Molecular Structure: | |
Formula: | C3H10Si |
Molecular Weight: | 74.1979 |
Synonyms: | 2-Methyl-2-silapropane;Dow Corning 9-5170;Trimethylsilyl hydride; |
EINECS: | 213-603-0 |
Density: | 0.638 g/cm3 |
Melting Point: | -135,9 °C |
Boiling Point: | 1.67 °C at 760 mmHg |
Flash Point: | -72.532 °C |
Solubility: | 1.4g/L at 20℃ |
Risk Codes: | 12-36/37/38 |
Safety: | 9-16-26-33 |
PSA: | 0.00000 |
LogP: | 1.10290 |
Conditions | Yield |
---|---|
aluminum (III) chloride; lithium chloride In xylene at 80℃; for 0.166667h; Product distribution / selectivity; | 95.4% |
In toluene at 80℃; for 0.166667h; Product distribution / selectivity; | 92.5% |
lithium tetrachloroaluminate In toluene at 80℃; for 0.166667h; Product distribution / selectivity; | 92.7% |
Conditions | Yield |
---|---|
With hydrogen; [RuCl(η2-H2)(dppe)2]OTf In 1,2-dichloro-ethane at 50℃; under 760 Torr; for 48h; Product distribution; Further Variations:; Catalysts; | A n/a B 95% |
With hydrogen; [RuCl(dppe)2]OTf In benzene-d6 at 50℃; for 3h; Hydrogenolysis; Title compound not separated from byproducts; |
trimethylsilyl trifluoromethanesulfonate
trimethylsilan
Conditions | Yield |
---|---|
With C35H37IrN2P(1+)*C24BF20(1-); hydrogen; N-ethyl-N,N-diisopropylamine; triphenylphosphine In (2)H8-toluene at 20℃; under 760.051 Torr; for 4.5h; | 94% |
With [N-[4-(dimethylamino)phenyl]-2-pyridinecarboxamidato](pentamethylcyclopentadienyl)iridium trifluorometanesulfonate; hydrogen; N-ethyl-N,N-diisopropylamine In benzene-d6 at -196 - 60℃; under 3040.2 Torr; for 48h; | 95 %Spectr. |
With 1,4-bis-(trimethylsilyl)benzene; [N-[4-(dimethylamino)phenyl]-2-pyridinecarboxamidato](pentamethylcyclopentadienyl)iridium trifluorometanesulfonate; hydrogen; N-ethyl-N,N-diisopropylamine In benzene-d6 at 60℃; under 3040.2 Torr; for 48h; Reagent/catalyst; | 95 %Spectr. |
With [Ru(H)2CO(HN(CH2CH2P(iPr)2)2)]; hydrogen; triethylamine In benzene-d6 at 20℃; under 3000.3 Torr; for 18h; Catalytic behavior; Pressure; | 85 %Spectr. |
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride; calcium hydride In diethylene glycol dimethyl ether for 11h; Inert atmosphere; Reflux; | 92% |
With lithium aluminium tetrahydride In toluene at 80℃; for 0.916667h; Inert atmosphere; | 82% |
With lithium aluminium tetrahydride In hexane at 40℃; for 3h; Irradiation; ultrasonic irradiation; | 80% |
C10H26OSi3
A
trimethyl(prop-1-ynyl)silane
B
trimethylsilan
C
Methoxytrimethylsilane
D
ethenyltrimethylsilane
Conditions | Yield |
---|---|
at 650℃; under 0.0001 Torr; | A 18% B n/a C 87% D 28% |
1,1,2,2-tetramethyldisilane
A
chloro-trimethyl-silane
B
dimethylmonochlorosilane
C
dimethylsilane
D
trimethylsilan
Conditions | Yield |
---|---|
With tetra-n-butylphosphonium chloride at 180℃; for 17h; Sealed tube; | A 2% B 4% C 87% D 7% |
Conditions | Yield |
---|---|
With 2-methylimidazole; tetra-n-butylphosphonium chloride at 175℃; for 89h; Sealed tube; | A 85% B 11% |
Conditions | Yield |
---|---|
With tris(pentafluorophenyl)borate In chlorobenzene at 100℃; for 24h; Mechanism; Glovebox; Inert atmosphere; chemoselective reaction; | A n/a B 81% |
A
trimethylsilan
Conditions | Yield |
---|---|
With trimethylphenylsilane; tris(pentafluorophenyl)borate In chlorobenzene at 100℃; for 24h; Mechanism; Glovebox; chemoselective reaction; | A n/a B 78% |
2-cyclopropyl-2-methoxyhexamethyltrisilane
A
trimethyl(prop-1-ynyl)silane
B
trimethylsilan
C
Methoxytrimethylsilane
D
ethenyltrimethylsilane
Conditions | Yield |
---|---|
at 590℃; under 0.0001 Torr; | A 18% B n/a C 72% D 27% |