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13688-56-7

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13688-56-7 Usage

Chemical Properties

clear slightly yellow liquid

Check Digit Verification of cas no

The CAS Registry Mumber 13688-56-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,6,8 and 8 respectively; the second part has 2 digits, 5 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 13688-56:
(7*1)+(6*3)+(5*6)+(4*8)+(3*8)+(2*5)+(1*6)=127
127 % 10 = 7
So 13688-56-7 is a valid CAS Registry Number.
InChI:InChI=1/C7H14O2Si/c1-6(2)7(8)9-10(3,4)5/h1H2,2-5H3

13688-56-7 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
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  • Price
  • Detail
  • Aldrich

  • (347493)  (Trimethylsilyl)methacrylate  98%

  • 13688-56-7

  • 347493-25G

  • 1,661.40CNY

  • Detail
  • Aldrich

  • (347493)  (Trimethylsilyl)methacrylate  98%

  • 13688-56-7

  • 347493-100G

  • 5,087.16CNY

  • Detail

13688-56-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name TRIMETHYLSILYL METHACRYLATE

1.2 Other means of identification

Product number -
Other names trimethylsilyl 2-methylprop-2-enoate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13688-56-7 SDS

13688-56-7Synthetic route

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

heptamethyltrisiloxane

heptamethyltrisiloxane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With tris(pentafluorophenyl)borate; 4-methoxy-phenol In tetrahydrofuran for 0.75h; Green chemistry;90.1%
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

N,N'-bis(trimethylsilyl)urea
18297-63-7

N,N'-bis(trimethylsilyl)urea

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
In dichloromethane at 40℃; for 2h;80%
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With ammonium sulfate at 120℃;56%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With N,N-diethylaniline
With 1-methyl-1H-imidazole at 45 - 90℃; for 3.75h; Product distribution / selectivity; Inert atmosphere; Industry scale;99 %Chromat.
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

sodium methacrylate
5536-61-8

sodium methacrylate

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With hydroquinone In benzene
3-(trimethylsilyl)-2-oxazolidinone
43112-38-5

3-(trimethylsilyl)-2-oxazolidinone

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With triethylamine In dichloromethane for 0.5h; Ambient temperature;
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
With hydroquinone for 3h; Heating;
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

trimethylsilyl acetate
2754-27-0

trimethylsilyl acetate

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

Conditions
ConditionsYield
In hexane
trityl fluoride
427-36-1

trityl fluoride

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

A

trimethylsilyl fluoride
420-56-4

trimethylsilyl fluoride

B

2-methylacrylic acid trityl ester
19302-93-3

2-methylacrylic acid trityl ester

Conditions
ConditionsYield
With silicon tetrafluoride In acetonitrile at 14℃; for 6h;A n/a
B 94%
trimethylsilan
993-07-7

trimethylsilan

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

1,1-bis(trimethylsiloxy)-2-methylprop-1-ene
31469-25-7

1,1-bis(trimethylsiloxy)-2-methylprop-1-ene

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; rhodium(III) chloride In tetrahydrofuran at 40 - 50℃;78%
trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

dichloro(fluoro)(phenyl)silane
368-44-5

dichloro(fluoro)(phenyl)silane

PhSiF[OC(O)CCH3=CH2]2
1357518-85-4

PhSiF[OC(O)CCH3=CH2]2

Conditions
ConditionsYield
at 20℃; for 7 - 8h;75.1%
trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

chloro(difluoro)(phenyl)silane
368-45-6

chloro(difluoro)(phenyl)silane

PhSiF2OC(O)C(CH3)=CH2
1357518-67-2

PhSiF2OC(O)C(CH3)=CH2

Conditions
ConditionsYield
at 20℃; for 0.25 - 0.5h;74%
trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

trimethylsilyl triphenyl methyl ether
50653-07-1

trimethylsilyl triphenyl methyl ether

A

Hexamethyldisiloxane
107-46-0

Hexamethyldisiloxane

B

2-methylacrylic acid trityl ester
19302-93-3

2-methylacrylic acid trityl ester

Conditions
ConditionsYield
With trimethylsilyl trifluoromethanesulfonate In dichloromethane at 0℃; for 6h;A n/a
B 73%
trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

trimethylsilyl triphenyl methyl ether
50653-07-1

trimethylsilyl triphenyl methyl ether

2-methylacrylic acid trityl ester
19302-93-3

2-methylacrylic acid trityl ester

Conditions
ConditionsYield
trimethylsilyl trifluoromethanesulfonate In dichloromethane at 0℃; for 6h;73%
chlorotrimethoxysilane
4668-00-2

chlorotrimethoxysilane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

trimethoxysilyl methacrylate
27719-42-2

trimethoxysilyl methacrylate

Conditions
ConditionsYield
at 20℃; for 8h;A n/a
B 62%
trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

dichloro(fluoro)(phenyl)silane
368-44-5

dichloro(fluoro)(phenyl)silane

PhSiFClOC(O)C(CH3)=CH2
1344680-46-1

PhSiFClOC(O)C(CH3)=CH2

Conditions
ConditionsYield
at 20℃; for 0.25 - 0.5h;58.7%
triethylsilane
617-86-7

triethylsilane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

2-methyl-1-triethylsiloxy-1-trimethylsiloxy-propene

2-methyl-1-triethylsiloxy-1-trimethylsiloxy-propene

Conditions
ConditionsYield
Stage #1: triethylsilane With 1,3,5-trimethyl-2,4,6-tris-(3,5-di-tert-butyl-4-hydroxybenzyl)benzene; tris(pentafluorophenyl)borate at 20℃; for 0.25h; Neat (no solvent);
Stage #2: trimethylsilyl methacrylate at 4.5 - 8℃; for 4h; Neat (no solvent); Cooling with ice water;
Stage #3: trimethylsilyl methacrylate With triethylamine; tris(pentafluorophenyl)borate more than 3 stages;
49.2%
1H-indole-5-carbonitrile
15861-24-2

1H-indole-5-carbonitrile

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

C13H10N2O

C13H10N2O

Conditions
ConditionsYield
Stage #1: trimethylsilyl methacrylate With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 20℃; for 3h;
Stage #2: 1H-indole-5-carbonitrile With tetrabutyl ammonium fluoride; sodium hydroxide In dichloromethane
17%
trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

1-Phenyl-7,7-dihexyl-8,8-dimethyl-7,8-disilabicyclo[2.2.2]octa-2,5-diene

1-Phenyl-7,7-dihexyl-8,8-dimethyl-7,8-disilabicyclo[2.2.2]octa-2,5-diene

Poly(1,1-dimethyl-2,2-dihexyldisilene)-b-poly(methacrylic acid); Mn=2.4 E4

Poly(1,1-dimethyl-2,2-dihexyldisilene)-b-poly(methacrylic acid); Mn=2.4 E4

Conditions
ConditionsYield
Stage #1: 1-Phenyl-7,7-dihexyl-8,8-dimethyl-7,8-disilabicyclo[2.2.2]octa-2,5-diene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.333333h; Polymerization;
Stage #2: trimethylsilyl methacrylate In tetrahydrofuran; hexane at -78℃; for 2h; Polymerization;
Stage #3: With hydrogenchloride In tetrahydrofuran; hexane Hydrolysis;
15.2%
chloromethyldimethylsilane
3144-74-9

chloromethyldimethylsilane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

β--isobuttersaeure-trimethylsilylester
13688-53-4

β--isobuttersaeure-trimethylsilylester

Conditions
ConditionsYield
dihydrogen hexachloroplatinate In isopropyl alcohol Heating;
dimethylethylsilane
758-21-4

dimethylethylsilane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

C11H26O2Si2
13688-85-2

C11H26O2Si2

(3-chloropropyl)dimethylsilane
18157-31-8

(3-chloropropyl)dimethylsilane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

C12H27ClO2Si2
38110-03-1

C12H27ClO2Si2

Conditions
ConditionsYield
dihydrogen hexachloroplatinate
diethoxymethylane
2031-62-1

diethoxymethylane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

2-Methyl-3-(diethoxy-methylsilyl)-propionsaeure-trimethylsilylester
23416-03-7

2-Methyl-3-(diethoxy-methylsilyl)-propionsaeure-trimethylsilylester

Conditions
ConditionsYield
dihydrogen hexachloroplatinate In isopropyl alcohol at 180℃;
ethyldiethoxysilane
13175-88-7

ethyldiethoxysilane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

2-Methyl-3-(diethoxy-ethylsilyl)-propionsaeure-trimethylsilylester
23416-04-8

2-Methyl-3-(diethoxy-ethylsilyl)-propionsaeure-trimethylsilylester

Conditions
ConditionsYield
dihydrogen hexachloroplatinate In isopropyl alcohol at 180℃;
Triethoxysilane
998-30-1

Triethoxysilane

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

2-Methyl-3-triethoxysilyl-propionsaeure-trimethylsilylester
23416-05-9

2-Methyl-3-triethoxysilyl-propionsaeure-trimethylsilylester

Conditions
ConditionsYield
dihydrogen hexachloroplatinate In isopropyl alcohol at 180℃;
1,1,1,3,5,5,5-heptamethyltrisiloxan
1873-88-7

1,1,1,3,5,5,5-heptamethyltrisiloxan

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

C14H36O4Si4
63672-03-7

C14H36O4Si4

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate In isopropyl alcohol
trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

methacrylic acid bromide
6997-65-5

methacrylic acid bromide

Conditions
ConditionsYield
With dibromotriphenylphosphorane In dichloromethane at 15℃; for 0.166667h;
trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

4,4'-dicyano-4,4'-azo-di-valeric acid
2638-94-0

4,4'-dicyano-4,4'-azo-di-valeric acid

polymer, obtained by radical polymerization trimethylsilyl methacrylate using 4,4'-azobis(4-cyanopentanoic acid) as an initiator

polymer, obtained by radical polymerization trimethylsilyl methacrylate using 4,4'-azobis(4-cyanopentanoic acid) as an initiator

Conditions
ConditionsYield
In 1,4-dioxane at 60℃; for 18h;
divinyl benzene

divinyl benzene

acrylic acid n-butyl ester
141-32-2

acrylic acid n-butyl ester

trimethylsilyl methacrylate
13688-56-7

trimethylsilyl methacrylate

poly(butyl acrylate-co-divinyl benzene-co-trimethylsilyl methacrylate)

poly(butyl acrylate-co-divinyl benzene-co-trimethylsilyl methacrylate)

13688-56-7Related news

Studies on laser action from polymeric matrices based on TRIMETHYLSILYL METHACRYLATE (cas 13688-56-7) doped with pyrromethene 567 dye09/08/2019

The lasing properties of pyrromethene 567 (PM567) dissolved in solid poly-trimethylsilyl-methacrylate (TMSMA) cross-linked with ethylene glycol dimethacrylate (EGDMA) and copolymerized with methyl methacrylate (MMA) have been investigated. The vol/vol proportion of the different comonomers in ea...detailed

Statistical copolymers of styrene and 2-vinylpyridine with TRIMETHYLSILYL METHACRYLATE (cas 13688-56-7) and trimethylsilyloxyethyl methacrylate09/06/2019

Statistical copolymers of styrene with trimethylsilyl methacrylate, STMS, and trimethylsilyloxyethyl methacrylate, STME, and of 2-vinylpyridine with trimethylsilyloxyethyl methacrylate, VTME were prepared by free radical copolymerization in benzene with 2,2′-azobisisobutyronitrile, AIBN. The re...detailed

13688-56-7Relevant articles and documents

N,N'-Bis-urea: A Useful Silylating Agent for Alcohols and Carboxylic Acids

Verboom, W.,Visser, G. W.,Reinhoudt, D. N.

, p. 807 - 809 (1981)

-

PROCESS FOR SILYLATING MONOCARBOXYLIC ACIDS

-

Page/Page column 4, (2010/06/22)

A process for preparing silylated monocarboxylic acids by reacting C2-C10-monocarboxylic acids with halosilanes of the general formula (I) SiHal4-xRx??(I) in which Hal is a halogen atom selected from the group of fluorine, chlorine, bromine and iodine, R is independently hydrogen, Cl-C10-alkyl or aryl and x is an integer of 0 to 3 to form hydrogen halide in the presence of an auxiliary base, wherein the auxiliary base and the hydrogen halide form a salt which forms two immiscible phases with the product of value or the solution of the product of value in a suitable solvent and is removed.

Reagents and Synthetic Methods; 14. A Facile Synthesis of Carboxylic Acid Bromides and Esters under Neutral Conditions via Reaction of the Trimethylsilyl Esters with Triphenylphosphine Dibromide

Aizpurua, Jesus Mari,Palomo, Claudio

, p. 684 - 686 (2007/10/02)

-

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