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103-83-3

Basic Information
CAS No.: 103-83-3
Name: N,N-Dimethylbenzylamine
Article Data: 362
Cas Database
Molecular Structure:
Molecular Structure of 103-83-3 (N,N-Dimethylbenzylamine)
Formula: C9H13N
Molecular Weight: 135.209
Synonyms: Benzylamine,N,N-dimethyl- (8CI);Ancamine BDMA;Benzyl-N,N-dimethylamine;Benzyldimethylamine;Dimethylbenzylamine;N,N-Dimethyl-N-benzylamine;N,N-Dimethylbenzenemethanamine;N-(Phenylmethyl)dimethylamine;N-Benzyl-N,N-dimethylamine;N-Benzyldimethylamine;NSC 5342;Sumicure BD;[(Dimethylamino)methyl]benzene;N,N-Dimethylbenzylamine(BDMA);
EINECS: 203-149-1
Density: 0.9 g/mL at 25 °C(lit.)
Melting Point: -75 °C
Boiling Point: 181 °C at 760 mmHg
Flash Point: 130 °F
Solubility: 8 g/L (25 °C) in water
Appearance: Colourless to light yellow liquid
Hazard Symbols: CorrosiveC
Risk Codes: 10-20/21/22-34-52/53
Safety: 26-36-45-61
Transport Information: UN 2619 8/PG 2
PSA: 3.24000
LogP: 1.74820
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  • N,N-Dimethylbenzylamine   CAS.103-83-3

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    103-83-3

    N,N-Dimethylbenzylamine CAS.103-83-3

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    Hubei Xinrunde Chemical Co., Ltd. dedicated to the development, production and marketing of chemicals which is specialized in Organic compounds; Active Pharmaceutical Ingredient(s)

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  • N,N-Dimethylbenzylamine

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    N,N-Dimethylbenzylamine

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    Comply with CP,JP,EP,US GradeAppearance:White Solid Storage:Stored under room temperature in cool and dry place Package:In 25KG paper or plastic drums Application:Used as pharmaceutical Intermeidate Transportation:Shipped as non- dangerous chemicals

    Who we are ? Located in Zhengzhou City, China , Henan Daken Chemical Co.,Ltd was Established in June ,1983.We have a 35 years history for fine chemical synthesis .Daken has young

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  • N,N-Dimethyl Benzylamine

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    103-83-3

    N,N-Dimethyl Benzylamine

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    low price and good quality Application:N,N-Dimethyl Benzylamine

    Shanghai Yanchu Chemicals is dedicated to providing fine chemicals, building blocks and electronic chemcials with strictly quality contol . We have well equipped labs to provid

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  • N,N-Dimethylbenzylamine (BDMA)

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    103-83-3

    N,N-Dimethylbenzylamine (BDMA)

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    1.We have rich experience in the development and production 2.Our factory is in Shanghai of China,We have convenient traffic conditions.3.We have advanced testing equipment and shipping line. Package:5g, 10g, 50g, 100g, 1kg Application:Pharmaceutical

    Dine products include organic reagents, inorganic reagents and biochemical reagents, including pharmaceutical intermediates, bulk drugs, catalysts, high purity solvents, specialty

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  • Benzyldimethylamine

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    103-83-3

    Benzyldimethylamine

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    Hangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global pharmaceutical, ch

    Hangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service profession

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

DOT Classification:  8; Label: Corrosive

Specification

1. Introduction of N,N-Dimethylbenzylamine
The N,N-Dimethylbenzylamine with CAS registry number of 103-83-3 is also known as Benzyl-N,N-dimethylamine. The IUPAC name is N,N-Dimethyl-1-phenylmethanamine. It belongs to product categories of Anilines, Aromatic Amines and Nitro Compounds; Organics. Its EINECS registry number is 203-149-1. In addition, the formula is C9H13N and the molecular weight is 135.23. This chemical is a colourless to light yellow liquid with an amine odour that slightly soluble in water. It may destroy living tissue on contact and should be sealed in ventilated, cool room away from fire and heat. What's more, this chemical is used as organic synthesis intermediate and also used as dehydrogenation catalysts, preservatives, acid neutralizer and so on.

2. Properties of N,N-Dimethylbenzylamine
(1)ACD/LogP: 1.98; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.91; (4)ACD/LogD (pH 7.4): 0.57; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 11.11; (9)#H bond acceptors: 1; (10)#Freely Rotating Bonds: 2; (11)Index of Refraction: 1.516; (12)Molar Refractivity: 44.15 cm3; (13)Molar Volume: 146 cm3; (14)Surface Tension: 32.7 dyne/cm; (15)Density: 0.926 g/cm3; (16)Flash Point: 54.4 °C; (17)Enthalpy of Vaporization: 41.73 kJ/mol; (18)Boiling Point: 181 °C at 760 mmHg; (19)Vapour Pressure: 0.871 mmHg at 25 °C.

3. Structure Descriptors of N,N-Dimethylbenzylamine
1. Canonical SMILES: CN(C)CC1=CC=CC=C1
2. InChI: InChI=1S/C9H13N/c1-10(2)8-9-6-4-3-5-7-9/h3-7H,8H2,1-2H3
3. InChIKey: XXBDWLFCJWSEKW-UHFFFAOYSA-N

4. Toxicity of N,N-Dimethylbenzylamine

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LCLo inhalation 1200mg/m3/2H (1200mg/m3) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 5, Pg. 6, 1963.
rabbit LD50 skin 1660mg/kg (1660mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: EXCITEMENT
Drug and Chemical Toxicology. Vol. 8, Pg. 43, 1985.
rat LCLo inhalation 1200mg/m3/2H (1200mg/m3) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 5, Pg. 6, 1963.
rat LD50 oral 265mg/kg (265mg/kg)   Personal Communication from C.J. Korpics, Sherwin-Williams Chemicals, 1310 Expressway Drive, Toledo, OH 43608, Aug. 22, 1974Vol. 22AUG1974,

5. Safety Information of N,N-Dimethylbenzylamine
When you are using this chemical, please be cautious about it. As a chemical, it is not only harmful by inhalation, in contact with skin and if swallowed, but also harmful to aquatic organisms that may cause long-term adverse effects in the aquatic environment. This chemical is flammable and may cause burns. During using it, wear suitable protective clothing. Avoid release to the environment.. If contact with eyes accidently, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell seek medical advice immediately.

6. Preparation of N,N-Dimethylbenzylamine
N,N-Dimethylbenzylamine is prepared by reaction of benzyl with dimethylamine. Firstly, dimethylamine is added into reactor and mixed with benzyl chloride under stirring at the temperature of 25 °C for 1 hour. Then the reaction mixture is heated to 55-60 °C for 6 hours. After reaction, liquid caustic soda is added and oil reservoir is washed with hot water. At last, product is obtained by collecting distillate at 67-72 °C (1.87 kPa).

N,N-Dimethylbenzylamine is prepared by reaction of benzyl with dimethylamine.

7. Use of N,N-Dimethylbenzylamine
N,N-Dimethylbenzylamine is used to produce 2-trimethylsilylbenzyldimethylamin by reaction with chloro-trimethyl-silane. The reaction occurs with reagent BuLi and solvent diethyl ether at the temperature of -20 °C for 12 hours. The yield is about 35%.

N,N-Dimethylbenzylamine is used to produce 2-trimethylsilylbenzyldimethylamin by reaction with chloro-trimethyl-silane.