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103-83-3

Basic Information
CAS No.: 103-83-3
Name: N,N-Dimethylbenzylamine
Molecular Structure:
Molecular Structure of 103-83-3 (N,N-Dimethylbenzylamine)
Formula: C9H13N
Molecular Weight: 135.23
Synonyms: Benzylamine,N,N-dimethyl- (8CI);Ancamine BDMA;Benzyl-N,N-dimethylamine;Benzyldimethylamine;Dimethylbenzylamine;N,N-Dimethyl-N-benzylamine;N,N-Dimethylbenzenemethanamine;N-(Phenylmethyl)dimethylamine;N-Benzyl-N,N-dimethylamine;N-Benzyldimethylamine;NSC 5342;Sumicure BD;[(Dimethylamino)methyl]benzene;N,N-Dimethylbenzylamine(BDMA);
EINECS: 203-149-1
Density: 0.9 g/mL at 25 °C(lit.)
Melting Point: -75 °C
Boiling Point: 181 °C at 760 mmHg
Flash Point: 130 °F
Solubility: 8 g/L (25 °C) in water
Appearance: Colourless to light yellow liquid
Hazard Symbols: CorrosiveC
Risk Codes: 10-20/21/22-34-52/53
Safety: 26-36-45-61
Transport Information: UN 2619 8/PG 2
PSA: 3.24000
LogP: 1.74820
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    The company is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds,

  •  Henan Wentao Chemical Product Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-370-2722992

    Address:32 Room, 5th Floor, Building 11, No. 6 Yinxing Road, High-tech Industrial Development Zone, Zhengzhou City, Henan Province

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  • N, N-dimethylbenzamine

  • Casno:

    103-83-3

    N, N-dimethylbenzamine

    Min.Order: 1 Kilogram

    FOB Price:  USD $ 0.0-0.0/Kilogram

    ★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support ★.Shortest delivery time . Appearance:it is colorless to light yellow transparent liquid at normal tempera

    Hangzhou Ocean Chemical Co.ltd is a comprehensive chemical enterprise which mainly integrates R&D, production, marketing business of chemical in lab-pack, semi-bulk and bulk-quanti

  •  Hangzhou Ocean Chemical Co., Ltd.

    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-571-88025872, 28272092, 28272096

    Address:Room 623 ,Building No 1 , COFCO Radius Commercial Center Xiwen Road, Xiacheng District, Hangzhou, Zhejiang Province, China

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  • N,N-Dimethylbenzylamine

  • Casno:

    103-83-3

    N,N-Dimethylbenzylamine

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0/

    Productname:N,N-dimethylbenzylamine CASnumber:103-83-3 …Appearance:colorless to light yellow transparent liquid Package:net weight 180 kg galvanized iron drum, also can according to the customer request. Application:: refrigerat

    Zouping Mingxing Chemical Co., Ltd lies at the west of the Huangshan Mountain in Zouping city, near to Zibo and Qingdao in the east, Japan in the west and Ji-Qing Expressway

  •  Zouping Mingxing Chemical Co.,Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-543-8178171

    Address:428 Daixi Third Road Zouping County Shandong Province China

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  • High Purity N,N-dimethylbenzyl amine;benzyldimethylamine; supplier in China

  • Casno:

    103-83-3

    High Purity N,N-dimethylbenzyl amine;benzyldimethylamine; supplier in China

    Min.Order: 0 Gram

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    Changsha EASCHEM is a leading company in marketing ang distributing chemicals and new materials with establishment in 2013 by reregistering from Easchem International from China. We, EASCHEM, are the brand with the aim for erecting up Big Chemica

    Changsha EASCHEM is a leading company in marketing ang distributing chemicals and new materials with establishment in 2013 by reregistering from Easchem International from China.

  •  Changsha Easchem Co.,Limited

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-731-89722861 89722891

    Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

DOT Classification:  8; Label: Corrosive

Specification

1. Introduction of N,N-Dimethylbenzylamine
The N,N-Dimethylbenzylamine with CAS registry number of 103-83-3 is also known as Benzyl-N,N-dimethylamine. The IUPAC name is N,N-Dimethyl-1-phenylmethanamine. It belongs to product categories of Anilines, Aromatic Amines and Nitro Compounds; Organics. Its EINECS registry number is 203-149-1. In addition, the formula is C9H13N and the molecular weight is 135.23. This chemical is a colourless to light yellow liquid with an amine odour that slightly soluble in water. It may destroy living tissue on contact and should be sealed in ventilated, cool room away from fire and heat. What's more, this chemical is used as organic synthesis intermediate and also used as dehydrogenation catalysts, preservatives, acid neutralizer and so on.

2. Properties of N,N-Dimethylbenzylamine
(1)ACD/LogP: 1.98; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -0.91; (4)ACD/LogD (pH 7.4): 0.57; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 11.11; (9)#H bond acceptors: 1; (10)#Freely Rotating Bonds: 2; (11)Index of Refraction: 1.516; (12)Molar Refractivity: 44.15 cm3; (13)Molar Volume: 146 cm3; (14)Surface Tension: 32.7 dyne/cm; (15)Density: 0.926 g/cm3; (16)Flash Point: 54.4 °C; (17)Enthalpy of Vaporization: 41.73 kJ/mol; (18)Boiling Point: 181 °C at 760 mmHg; (19)Vapour Pressure: 0.871 mmHg at 25 °C.

3. Structure Descriptors of N,N-Dimethylbenzylamine
1. Canonical SMILES: CN(C)CC1=CC=CC=C1
2. InChI: InChI=1S/C9H13N/c1-10(2)8-9-6-4-3-5-7-9/h3-7H,8H2,1-2H3
3. InChIKey: XXBDWLFCJWSEKW-UHFFFAOYSA-N

4. Toxicity of N,N-Dimethylbenzylamine

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LCLo inhalation 1200mg/m3/2H (1200mg/m3) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 5, Pg. 6, 1963.
rabbit LD50 skin 1660mg/kg (1660mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: EXCITEMENT
Drug and Chemical Toxicology. Vol. 8, Pg. 43, 1985.
rat LCLo inhalation 1200mg/m3/2H (1200mg/m3) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 5, Pg. 6, 1963.
rat LD50 oral 265mg/kg (265mg/kg)   Personal Communication from C.J. Korpics, Sherwin-Williams Chemicals, 1310 Expressway Drive, Toledo, OH 43608, Aug. 22, 1974Vol. 22AUG1974,

5. Safety Information of N,N-Dimethylbenzylamine
When you are using this chemical, please be cautious about it. As a chemical, it is not only harmful by inhalation, in contact with skin and if swallowed, but also harmful to aquatic organisms that may cause long-term adverse effects in the aquatic environment. This chemical is flammable and may cause burns. During using it, wear suitable protective clothing. Avoid release to the environment.. If contact with eyes accidently, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell seek medical advice immediately.

6. Preparation of N,N-Dimethylbenzylamine
N,N-Dimethylbenzylamine is prepared by reaction of benzyl with dimethylamine. Firstly, dimethylamine is added into reactor and mixed with benzyl chloride under stirring at the temperature of 25 °C for 1 hour. Then the reaction mixture is heated to 55-60 °C for 6 hours. After reaction, liquid caustic soda is added and oil reservoir is washed with hot water. At last, product is obtained by collecting distillate at 67-72 °C (1.87 kPa).

N,N-Dimethylbenzylamine is prepared by reaction of benzyl with dimethylamine.

7. Use of N,N-Dimethylbenzylamine
N,N-Dimethylbenzylamine is used to produce 2-trimethylsilylbenzyldimethylamin by reaction with chloro-trimethyl-silane. The reaction occurs with reagent BuLi and solvent diethyl ether at the temperature of -20 °C for 12 hours. The yield is about 35%.

N,N-Dimethylbenzylamine is used to produce 2-trimethylsilylbenzyldimethylamin by reaction with chloro-trimethyl-silane.

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