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112-67-4

Basic Information
CAS No.: 112-67-4
Name: Palmitoyl chloride
Article Data: 21
Molecular Structure:
Molecular Structure of 112-67-4 (Palmitoyl chloride)
Formula: C16H31ClO
Molecular Weight: 274.875
Synonyms: Palmitoylchloride (6CI,7CI,8CI);Hexadecanoic acid chloride;NSC 9854;Palmitic acidchloride;Palmityl acid chloride;
EINECS: 203-996-7
Density: 0.913 g/cm3
Melting Point: 11-13 °C(lit.)
Boiling Point: 323.492 °C at 760 mmHg
Flash Point: 155.505 °C
Solubility: decompose in water
Appearance: clear liquid
Hazard Symbols: CorrosiveC
Risk Codes: 14-34-29
Safety: 26-36/37/39-43-45-8
Transport Information: UN 3265 8/PG 2
PSA: 17.07000
LogP: 6.23310
Synthetic route
57-10-3

1-hexadecylcarboxylic acid

112-67-4

n-hexadecanoyl chloride

Conditions
ConditionsYield
With thionyl chloride Reflux;100%
With thionyl chloride In N,N-dimethyl-formamide for 3h; Reflux;97%
With thionyl chloride; N,N-dimethyl-formamide for 3h; Reflux;97%
112-39-0

hexadecanoic acid methyl ester

A

74-87-3

methylene chloride

B

112-67-4

n-hexadecanoyl chloride

C

WOCl4

WOCl4

Conditions
ConditionsYield
With tungsten(VI) chloride In benzene at 20℃; for 90h; Product distribution;
408-35-5

sodium palmitate

112-67-4

n-hexadecanoyl chloride

Conditions
ConditionsYield
With thionyl chloride at 20℃;
79-37-8

oxalyl dichloride

57-10-3

1-hexadecylcarboxylic acid

112-67-4

n-hexadecanoyl chloride

Conditions
ConditionsYield
With N,N-dimethyl-formamide In dichloromethane at 20℃; for 1h;
In dichloromethane for 12h; Inert atmosphere;
130277-53-1, 130324-58-2

DL-3,4,5,6-Tetra-O-benzyl-3,5/4,6-tetrahydroxycyclohex-1-ene-1-methanol

112-67-4

n-hexadecanoyl chloride

130277-54-2, 130324-59-3

methyl Hexadecanoate

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane for 2h; Ambient temperature;100%
88110-81-0

9-{[(1,3-dihydroxypropan-2-yl)oxy]methyl}-2-{[(4-methoxyphenyl)diphenylmethyl]amino}-6,9-dihydro-1H-purin-6-one

112-67-4

n-hexadecanoyl chloride

88110-83-2

Hexadecanoic acid 3-hexadecanoyloxy-2-(2-{[(4-methoxy-phenyl)-diphenyl-methyl]-amino}-6-oxo-1,6-dihydro-purin-9-ylmethoxy)-propyl ester

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane for 20h; Ambient temperature;100%
190505-04-5

1-(2',3',4',6'-tetra-O-benzyl-β-D-glucopyranosyl)-2-hydroxymethyl-3-propanol

112-67-4

n-hexadecanoyl chloride

190505-07-8

Hexadecanoic acid 2-hexadecanoyloxymethyl-3-((2S,3S,4R,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl)-propyl ester

Conditions
ConditionsYield
With dmap In pyridine for 2h; Heating;100%

7,11,15,28-tetrakis(4-aminophenyl)-1,21,23,25-tetraundecyl 2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3]dioxocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3]benzodioxin

112-67-4

n-hexadecanoyl chloride

7,11,15,28-tetrakis(4-palmitoylamidophenyl)-1,21,23,25-tetraundecyl 2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3]dioxocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3]benzodioxin

Conditions
ConditionsYield
With potassium carbonate In water; ethyl acetate for 2h; Ambient temperature;100%
177898-40-7

N-octyl-2,3:4,6-di-O-isopropylidene-5a-carba-β-D-xylo-hex-5(5a)-enopyranosylamine

112-67-4

n-hexadecanoyl chloride

218924-27-7

Hexadecanoic acid octyl-((3aS,4R,9aR,9bS)-2,2,8,8-tetramethyl-4,6,9a,9b-tetrahydro-3aH-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-yl)-amide

Conditions
ConditionsYield
In pyridine for 1h; Ambient temperature;100%
123-75-1

pyrrolidine

112-67-4

n-hexadecanoyl chloride

70974-48-0

1-(pyrrolidin-1-yl)hexadecan-1-one

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃;100%
With pyridine at 20℃; for 3h; Acylation;4.5 g
With triethylamine In dichloromethane at 20℃; for 4h; Inert atmosphere;
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Chemistry

IUPAC Name: Hexadecanoyl chloride
Synonyms of Palmitoyl chloride (CAS NO.112-67-4): AI3-52614 ; EINECS 203-996-7 ; HSDB 5573 ; Hexadecanoic acid, chloride ; NSC 9854 ; Palmitic acid chloride  ; Palmityl chloride ; Hexadecanoyl chloride
CAS NO: 112-67-4
Molecular Formula of Palmitoyl chloride (CAS NO.112-67-4): C16H31ClO
Molecular Weight: 274.8697
Molecular Structure:

Melting Point: 11-13 °C
ProductCategories: ACID CHLORIDES 
Polar Surface Area: 17.07 Å2
Index of Refraction: 1.45
Molar Refractivity: 81.05 cm3
Molar Volume: 301.1 cm3
Surface Tension: 31.2 dyne/cm
Density of Palmitoyl chloride (CAS NO.112-67-4): 0.912 g/cm3
Flash Point: 155.5 °C
Enthalpy of Vaporization: 56.54 kJ/mol
Boiling Point: 323.5 °C at 760 mmHg
Vapour Pressure: 0.000261 mmHg at 25°C

Uses

 Palmitoyl chloride (CAS NO.112-67-4) is used as intermediates in organic synthesis.

Safety Profile

Hazard Codes: CorrosiveC
Risk Statements: 14-34-29 
R14: Reacts violently with water. 
R34: Causes burns. 
R29: Contact with water liberates toxic gas.
Safety Statements: 26-36/37/39-43-45-8 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S43: In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S8: Keep container dry.
RIDADR: UN 3265 8/PG 2
WGK Germany: 1
F: 9-21
HazardClass: 8
PackingGrou:p II