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CAS No.: | 1436-34-6 |
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Name: | 1,2-EPOXYHEXANE |
Article Data: | 138 |
Molecular Structure: | |
Formula: | C6H12 O |
Molecular Weight: | 100.161 |
Synonyms: | Hexane,1,2-epoxy- (7CI,8CI); Oxirane, butyl- (9CI); (?à)-1,2-Epoxyhexane; (?à)-Butyloxirane; 1,2-Epoxyhexane; 1,2-Hexene oxide;1-Hexene epoxide; 1-Hexene oxide; 2-Butyloxirane; Butyloxirane; NSC 24268 |
Density: | 0.871g/cm3 |
Melting Point: | 94°C |
Boiling Point: | 117.1°Cat760mmHg |
Flash Point: | 21.8°C |
Appearance: | clear colorless liquid |
Hazard Symbols: | |
Risk Codes: | 11-22-36/37/38 |
Safety: | Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors. |
PSA: | 12.53000 |
LogP: | 1.57540 |
Conditions | Yield |
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With C20H24CoN2O6(1+)*NO3(1-)*H2O; oxygen; isobutyraldehyde In acetonitrile at 60℃; under 760.051 Torr; for 8h; Time; chemoselective reaction; | 100% |
With dihydrogen peroxide; (Bu4N)3K[γ-SiW10O36(PhPO)2] In water at 65℃; for 2h; microwave irradiation; | 99% |
With tert.-butylhydroperoxide In acetonitrile at 65 - 68℃; for 24h; | 99% |
1,2-Epoxyhexane
Conditions | Yield |
---|---|
With Al2O3-Na2CO3 catalyst at 40 - 45℃; for 0.00833333h; Microwave irradiation; | 98% |
1,2-epoxy-5-hexene
1,2-Epoxyhexane
Conditions | Yield |
---|---|
With [Fe(nacnac)dippCH2SiMe3]; N-butylamine; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In benzene-d6 at 20℃; for 1h; Sealed tube; Schlenk technique; Glovebox; Inert atmosphere; | 91% |
Conditions | Yield |
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With tert.-butylhydroperoxide; Y2(N3)(nic)2(OH)3(Hnic)(H2O) In acetonitrile at 68 - 70℃; for 24h; | A 85% B 10% |
trans-2-hexene
A
1,2-Epoxyhexane
trans-2,3-epoxyhexane
cis-2,3-epoxyhexane
D
butyraldehyde
Conditions | Yield |
---|---|
With oxygen; titanium(IV) oxide for 19h; Irradiation; | A n/a B 66% C n/a D n/a |
1,2-epoxy-2-hexyl(triphenyl)silane
1,2-Epoxyhexane
Conditions | Yield |
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With potassium fluoride; N-benzyl-N,N,N-triethylammonium chloride In dimethyl sulfoxide for 2h; Ambient temperature; | 65% |
Conditions | Yield |
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With poly{[CuMg(pyridine-2,5-dicarboxylate)2(H2O)4]*2H2O}; dihydrogen peroxide In acetonitrile at 60℃; for 24h; Catalytic behavior; | A 22% B 61% |
With dihydrogen peroxide; large pore titanium silicate (MCM-41) In methanol at 55.9℃; for 5h; Product distribution; other hydrocarbon; var. oxidation compounds; var. time; | |
With urea-hydrogen peroxide; tegafur In methanol at 39.85℃; for 12h; Product distribution; Further Variations:; Reagents; |
cis-2-hexene
A
1,2-Epoxyhexane
trans-2,3-epoxyhexane
cis-2,3-epoxyhexane
D
butyraldehyde
Conditions | Yield |
---|---|
With oxygen; titanium(IV) oxide for 19h; Irradiation; | A n/a B n/a C 61% D n/a |
Conditions | Yield |
---|---|
With iodosylbenzene; (n-Bu4N)4H(Mn)PW11O39 In acetonitrile at 24℃; for 2h; Product distribution; other reagent, other catalysts, other time; | A 58% B n/a C 3.5% |
With sodium tetrahydroborate; 5,10,15,20-tetra(4-methoxyphenyl) porphyrinato manganese chloride; oxygen In ethanol; benzene for 24h; Product distribution; |
Conditions | Yield |
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With iodosylbenzene; (n-Bu4N)4H(Mn)PW11O39 In acetonitrile at 24℃; for 2h; | A 58% B 3.5% |
With tert.-butylhydroperoxide; 2C21H13N3O6(2-)*4Co(2+)*HO(1-)*17H2O In neat (no solvent) at 50℃; for 4h; Green chemistry; | A 80 %Chromat. B 20 %Chromat. |
With C60H62Fe2Li2N10O7(2+)*2ClO4(1-); dihydrogen peroxide; acetic acid In water; acetonitrile at 30℃; for 3h; | A 15 %Chromat. B n/a |
IUPAC Name: 2-Butyloxirane
The molecular formula of 2-Butyloxirane (CAS NO.1436-34-6) is C6H12O.
The molecular weight of 2-Butyloxirane (CAS NO.1436-34-6) is 100.16.
Synonyms of 2-Butyloxirane (CAS NO.1436-34-6): 2-Butyloxirane ; Hexene oxide ; 2-Hexene oxide ; 1,2-Hexeneoxide
Product Categories: Oxiranes;Simple 3-Membered Ring Compounds
Apperance: clear colorless liquid
Index of Refraction: 1.425
EINECS: 215-864-6
Density: 0.871 g/ml
Flash Point: 21.8 °C
Boiling Point: 117.1 °C
Storage temp: 2-8 °C
BRN: 102568
2-Butyloxirane (CAS NO.1436-34-6) is used as chemical reagent, organic intermediates, fine chemicals, pharmaceutical research and development.
1. | mmo-sat 20 µmol/plate | BCPCA6 Biochemical Pharmacology. 29 (1980),1068. | ||
2. | sce-ham:lng 1250 µmol/L | MUREAV Mutation Research. 249 (1991),55. |
Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.Safety information of 2-Butyloxirane (CAS NO.1436-34-6):
Hazard Codes F,Xn
Risk Statements 11-22-36/37/38
R11:Highly flammable.
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR UN 1993 3/PG 2
WGK Germany 3
RTECS MO3630000
F 10-21
HazardClass 3
PackingGroup III