CAS No.147-14-8,(29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)copper Suppliers

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Basic Information

Molecular Structure:
CAS No.:	147-14-8
Name:	(29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32)copper
Article Data:	117
Cas Database

Formula:	C₃₂H₁₆CuN₈
Molecular Weight:	576.079
Synonyms:	Chromatex Blue BN;Chromofine Blue4920G;Chromofine Blue 4930PK;Chromofine Blue 4950;Chromofine Blue 4973;Chromofine Blue 5108;Chromofine Blue 5187;Chromofine Blue 5206;Chromofine Blue 6310PK;Chromofine Blue 6335JC;Phthalocyanine blue (6CI);127EPS;402SD;7075M;79S26C;79S26C chip;A220;Acnalin Supra Blue G;Akrochem626;Chromofine Blue A220JC;Chromofine Blue HS 3;Chromofine Blue S 200;Chromofine Blue S 4920;
EINECS:	205-685-1
Density:	1.62[at 20℃]
Melting Point:	600 °C (dec.)
Solubility:	<0.1 g/100 mL at 20 °C in water
Appearance:	dark blue fine crystalline powder
Hazard Symbols:	Xi,Xn
Risk Codes:	R36/37/38; R48; R41; R37/38; R20/21/22
Safety:	22-24/25
PSA:	84.02000
LogP:	1.46190

Synthetic route

: 91-15-6
phthalonitrile

: 147-14-8
copper phthalocyanine

Conditions

Conditions	Yield
With CuCl2*2H2O for 0.166667h; microwave irradiation;	98%
With CuCl2*2H2O at 190 - 210℃; for 0.25h; microwave irradiation;	88%
With copper diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene at 140℃; for 0.0833333h;	76%
With 1,1,1,3,3,3-hexamethyl-disilazane; copper(ll) bromide In N,N-dimethyl-formamide at 100℃; for 10h;	74%

: 85-44-9
phthalic anhydride

: 147-14-8
copper phthalocyanine

Conditions

Conditions	Yield
With ammonium molybdate tetrahydrate; urea for 0.0833333h; microwave irradiation;	93%
With ammonium molybdate; urea at 200℃; for 0.166667h; microwave irradiation;	80%
Stage #1: phthalic anhydride With N,N-dimethyl-formamide; 1,1,1,3,3,3-hexamethyl-disilazane; copper dichloride; toluene-4-sulfonic acid at 150℃; for 10h; Stage #2: With sulfuric acid	62%

: 136918-14-4
phthalimide

: 147-14-8
copper phthalocyanine

Conditions

Conditions	Yield
Stage #1: phthalimide With toluene-4-sulfonic acid; 1,1,1,3,3,3-hexamethyl-disilazane; copper(ll) bromide; N,N-dimethyl-formamide at 150℃; for 10h; Stage #2: With sulfuric acid	72%

: 147-14-8
copper phthalocyanine

: copper ftalocyanine tetra-3-sulfonyl chloride

Conditions

Conditions	Yield
With chlorosulfonic acid; thionyl chloride 1.) 138 - 140 deg C, 3 h, 2.) 80 - 85 deg C, 3 h; Multistep reaction;

Raw Materials

7787-70-4

7789-45-9

999-97-3

91-15-6

574-93-6

Downstream Products

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Chemistry

Molecule structure of Copper phthalocyanine (CAS NO.147-14-8):

Molecular Weight: 576.06904 g/mol
Molecular Formula: C₃₂H₁₆CuN₈
Melting Point: 600°C (dec.)
Water Solubility: <0.1 g/100 mL at 20 °C
H-Bond Acceptor: 8
Exact Mass: 575.079394
MonoIsotopic Mass: 575.079394
Topological Polar Surface Area: 98.9
Heavy Atom Count: 41
Canonical SMILES: C1=CC=C2C(=C1)C3=NC4=NC(=NC5=NC(=NC6=NC(=NC2=N3)C7=CC=CC=C76)8=CC=CC=C85)C9=CC=CC=C94.[Cu]
InChI: InChI=1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;
InChIKey: VVOLVFOSOPJKED-UHFFFAOYSA-N
EINECS: 205-685-1
Product Categories: Dyes and Pigments; INORGANIC & ORGANIC CHEMICALS; Organometallics; electronic; Classes of Metal Compounds; Cu (Copper) Compounds; Functional Materials; Phthalocyanines; Phthalonitriles & Naphthalonitriles; Transition Metal Compounds; Electroluminescence; Blue needle crystal

History

Copper phthalocyanine (CAS NO.147-14-8) was first developed as a pigment in the mid-1930s.

Uses

Copper phthalocyanine (CAS NO.147-14-8)'s brilliant blue is frequently used in paints and dyes. Due to its stability, Copper phthalocyanine is also used in inks, coatings, and many plastics. It is a standard pigment used in printing ink and the packaging industry. Copper phthalocyanine is also used as a source material for manufacture of Phthalocyanine Green G. As presently produced, they are highly stable pigments, resistant to crystallization in organic solvents, and essentially free from flocculation in coatings. Both the green and the blue dyes have high tinting power and are used in latex paints and in printing inks, as well as all types of interior and exterior coatings.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD	intraperitoneal	> 3gm/kg (3000mg/kg)	KIDNEY, URETER, AND BLADDER: URINE VOLUME DECREASED KIDNEY, URETER, AND BLADDER: PROTEINURIS	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(1), Pg. 92, 1985.
rat	LD	oral	> 15gm/kg (15000mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 50(1), Pg. 92, 1985.

Safety Profile

Safety Statements: 22-24/25
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
RTECS: GL8510000
TSCA: Yes
Low toxicity by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic vapors of NO_x and Cu.

Specification

Copper phthalocyanine (CAS NO.147-14-8) is also named as AI3-26192 ; Accosperse Cyan Blue GT ; Aqualine Blue ; Arlocyanine Blue PS ; Bahama Blue BC ; Bahama Blue BNC ; Bahama Blue Lake NCNF ; Bahama Blue WD ; Bermuda Blue ; Blue GLA ; Blue Toner GTNF ; Blue pigment ; C.I. 74160 l C.I. Ingrain Blue 2 ; CI Ingrain Blue 2 ; CI Pigment Blue 15 ; Copper Phthaloycanine Blue ; Copper phthalocyanin ; Copper tetrabenzoporphyrazine ; Copper(2+) phthalocyanine ; Copper(II) phthalocyanine ; Copper, (29H,31H-phthalocyaninato(2-)- ; Cromophtal Blue 4GN ; Cromophtal Blue GF ; Cyan Blue BNC 55-3745 ; Cyan Blue BNF 55-3753 ; Cyan Blue GT ; Cyan Blue GT 55-3295 ; Cyan Blue GT 55-3300 ; Cyan Blue GTNF ; Cyan Blue Toner GT 3000 ; Cyan Blue XR 55-3758 ; Cyanine Blue HB ; Cyanine Blue LBG ; Cyanine Blue Rnf ; Dainichi Cyanine Blue B ; Fastogen Blue BS ; Fastogen Blue BSF ; Graphtol Blue BL ; Graphtol Blue BLF ; HSDB 2925 ; Helio Blue B ; Helio Fast Blue B ; Heliogen Blue BWS ; Isol Phthalo Blue BT ; Isol Phthalo Blue CBG ; Isol Phthalo Blue E 7543 ; Monarch Blue NCNF X-2658 ; Monarch Blue Toner NC X-2371 ; Monarch Blue Toner NCNF X-2810 ; Monarch Blue Toner X-2303 ; Monarch Blue Toner X-2763 ; NSC 15976 ; UNII-3VEX9T7UT5 . Copper phthalocyanine (CAS NO.147-14-8) has the appearance of a blue powder, insoluble in water and most solvents.