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16853-85-3

Basic Information
CAS No.: 16853-85-3
Name: Lithium aluminium hydride
Molecular Structure:
Molecular Structure of 16853-85-3 (Lithium aluminium hydride)
Formula: AlH4.Li
Molecular Weight: 37.95 .
Synonyms: Aluminate(1-),tetrahydro-, lithium (8CI);Aluminate(1-), tetrahydro-, lithium, (T-4)- (9CI);Aluminum lithium hydride (LiAlH4) (6CI);Aluminum lithium tetrahydride;Lithiumalanate;Lithium aluminum hydride (LiAlH4);Lithiumaluminum tetrahydride;Lithium tetrahydridoaluminate;Lithiumtetrahydroaluminate;Lithium tetrahydroaluminate (AlLiH4);Lithiumtetrahydroaluminate(1-);
EINECS: 240-877-9
Density: 0.917
Melting Point: 125 °C (dec.)(lit.)
Boiling Point: 0 °C
Flash Point: 99 °F
Solubility: reacts with water
Appearance: white crystalline powder
Hazard Symbols: FlammableF,CorrosiveC
Risk Codes: 15-34-14/15-11-36/37-19-40-10-67-66-22-12
Safety: 43-7/8-6A-45-43B-36/37/39-33-26-16-24/25-27-29
Transport Information: UN 3399 4.3/PG 1
PSA: 0.00000
LogP: 0.45000
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Chemistry

Product Name: Lithium aluminium hydride (CAS NO.16853-85-3)

Molecular Formula: LiAlH4
Molecular Weight: 37.95g/mol
Mol File: 16853-85-3.mol
EINECS: 240-877-9
Appearance: Clear colourless liquid
Melting Point: 125 °C (dec.)(lit.)
Storage Temperature: 2-8°C
Water Solubility: Reacts
Sensitive: Air & Moisture Sensitive
Stability: Stable. Reacts violently with water, liberating hydrogen. Incompatible with strong oxidizing agents, alcohols, acids.
Product Categories: Inorganics; Al (Alminum) Compounds; Classes of Metal Compounds; Li (Lithium) Compounds; Reduction; Synthetic Organic Chemistry; Typical Metal Compounds; Aluminum Hydrides; Synthetic Reagents

Uses

Used for determination reagents of carbonyl, reducing agents, but also for preparation of the hydride, silane, boron, etc.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety Information of  Lithium aluminium hydride (CAS NO.16853-85-3):
Hazard Codes: FFlammable,CCorrosive,XiIrritant,XnHarmful,F+Highly
Risk Statements:  15-34-14/15-11-36/37-19-40-10-67-66-22-12    
R15:Contact with water liberates extremely flammable gases. 
R34:Causes burns.
R14 :Reacts violently with water. 
R11:Highly flammable. 
R36/37:Irritating to eyes and respiratory system. 
R19:May form explosive peroxides. 
R40:Limited evidence of a carcinogenic effect. 
R10:Flammable. 
R67:Vapours may cause drowsiness and dizziness. 
R66:Repeated exposure may cause skin dryness or cracking. 
R22:Harmful if swallowed. 
R12:Extremely flammable.
Safety Statements: 43-7/8-6A-45-43B-36/37/39-33-26-16-24/25-27-29 
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S43:In case of fire use ... (there follows the type of fire-fighting equipment to be used.) 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S33:Take precautionary measures against static discharges. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S16:Keep away from sources of ignition. 
S24/25:Avoid contact with skin and eyes. 
S27:Take off immediately all contaminated clothing. 
S29:Do not empty into drains.
RIDADR: UN 3399 4.3/PG 1
WGK Germany: 2
RTECS: BD0100000
F: 10-21
TSCA: Yes
HazardClass: 4.3
PackingGroup: I

Standards and Recommendations

ACGIH TLV: TWA 2 mg(Al)/m3
DOT Classification:  4.3; Label: Dangerous When Wet (UN 1410); DOT Class: 4.3; Label: Dangerous When Wet, Flammable Liquid (UN 1411)

Specification

 Lithium aluminium hydride , its CAS NO. is 16853-85-3, the synonyms are Aluminate(1-), tetrahydro-, lithium ; Aluminate(1-), tetrahydro-, lithium, (T-4)- ; Aluminum lithium hydride ; Lithium alanate ; Lithium aluminohydride ; Lithium aluminum hydride, ethereal ;  Lithium aluminum tetrahydride ; Lithium tetrahydroaluminate .