Products Categories
CAS No.: | 2480-86-6 | ||||||||
---|---|---|---|---|---|---|---|---|---|
Name: | 4-(1-HYDROXYETHYL)-2-METHOXYPHENOL | ||||||||
Article Data: | 31 | ||||||||
Molecular Structure: | |||||||||
Formula: | C9H12 O3 | ||||||||
Molecular Weight: | 168.192 | ||||||||
Synonyms: | Vanillylalcohol, a-methyl- (6CI,7CI,8CI);1-(4-Hydroxy-3-methoxyphenyl)ethanol; 1-(4-Hydroxy-3-methoxyphenyl)ethyl alcohol;1-Guaiacylethanol; 4-(1-Hydroxyethyl)-2-methoxyphenol; Apocynol; NSC 47035; a-Methylvanillyl alcohol | ||||||||
Density: | 1.176g/cm3 | ||||||||
Melting Point: |
100-104 °C(lit.) |
||||||||
Boiling Point: | 301.5°Cat760mmHg | ||||||||
Flash Point: | 136.2°C | ||||||||
Hazard Symbols: | |||||||||
Risk Codes: | 22-36/37/38 | ||||||||
Safety: |
|
||||||||
PSA: | 49.69000 | ||||||||
LogP: | 1.45410 |
Conditions | Yield |
---|---|
With sodium tetrahydroborate In ethanol for 3h; Ambient temperature; | 74% |
With iron(III) chloride; C6H13BN2 In dichloromethane at 20℃; | 65% |
With sodium hydroxide; sodium tetrahydroborate |
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 1h; Inert atmosphere; | 63% |
In diethyl ether; toluene at 20℃; Grignard reaction; | 54% |
In tetrahydrofuran at 20℃; for 2h; Inert atmosphere; |
1-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)ethanol
A
Apocynol
B
2-methoxy-phenol
C
1-(3-methoxy-4-hydroxyphenyl)ethanone
D
phenol
Conditions | Yield |
---|---|
With sodium hydroxide; nickel at 25℃; Product distribution; Further Variations:; Temperatures; other substrates, other current densities; Catalytic hydrogenation; Electrochemical reaction; | A 41% B 43% C 1.3% D 2% |
Conditions | Yield |
---|---|
With sodium hydroxide; sodium tetrahydroborate Hydrieren des Reaktionsprodukts an Palladium/Kohle in Aethanol; |
Conditions | Yield |
---|---|
In diethyl ether for 1h; Heating; |
Conditions | Yield |
---|---|
With hydrogenchloride; sodium cyanoborohydride In methanol for 18h; Product distribution; | A 95 % Spectr. B 5 % Spectr. |
Apocynol
Conditions | Yield |
---|---|
With potassium hydroxide; water |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: BF3 2: NaBH4; aqueous NaOH View Scheme |