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333-20-0

Basic Information
CAS No.: 333-20-0
Name: Potassium thiocyanate
Molecular Structure:
Molecular Structure of 333-20-0 (Potassium thiocyanate)
Formula: KCNS
Molecular Weight: 97.18
Synonyms: Arterocyn;Aterocyn;Potassium isothiocyanate;Thiocyanic acid, potassium salt (1:1);
EINECS: 206-370-1
Density: 1.886
Melting Point: 173 °C(lit.)
Boiling Point: 500°C
Flash Point: 500°C
Solubility: 2170 g/L (20 °C) in water
Appearance: white crystalline powder
Hazard Symbols: HarmfulXn, IrritantXi
Risk Codes: 32-52/53-20/21/22
Safety: 13-61-36/37
Transport Information:
PSA: 49.09000
LogP: 0.66498
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  • Potassium thiocyanate CAS NO:333-20-0

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    Potassium thiocyanate CAS NO:333-20-0

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Chemistry

IUPAC Name: Potassium thiocyanate
Synonyms of Potassium thiocyanate (CAS NO.333-20-0): Arterocyn ; Kyonate ; Potassium isothiocyanate ; Potassium thiocyanate ; Thiocyanic acid, potassium salt (1:1)
CAS NO: 333-20-0
Molecular Formula: KCNS
Molecular Weight: 97.18
Molecular Structure:
EINECS: 206-370-1
H bond acceptors: 1
H bond donors: 0 
Freely Rotating Bonds: 0
Polar Surface Area: 62.59 Å2
Flash Point: 42.1 °C 
Enthalpy of Vaporization: 38.3 kJ/mol
Boiling Point: 146 °C at 760 mmHg
Vapour Pressure: 4.73 mmHg at 25°C 
Melting Point: 173 °C(lit.)
Storage temp: Store at RT. 
Density: 1.886
Solubility : H2O: 8 M at 20°C, clear, colorless
Sensitive : Hygroscopic
Appearance: Colorless to white, odorless crystals
SMILES: [K+].[S-]C#N
InChI: InChI=1/CHNS.K/c2-1-3;/h3H;/q;+1/p-1
InChIKey: ZNNZYHKDIALBAK-REWHXWOFAT
Std. InChI: InChI=1S/CHNS.K/c2-1-3;/h3H;/q;+1/p-1
Std. InChIKey: ZNNZYHKDIALBAK-UHFFFAOYSA-M
Product Categories of Potassium thiocyanate (CAS NO.333-20-0): Inorganics

Uses

 Potassium thiocyanate (CAS NO.333-20-0) is the starting product for the synthesis of carbonyl sulfide. Potassium thiocyanate is used for the production of artificial mustard oil, fungicide, insecticide. It is occasionally used for moderately realistic blood effects in film and theater. Besides, it can be painted onto a surface or kept as a colourless solution.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo intravenous 100mg/kg (100mg/kg)   Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 29, Pg. 152, 1940.
frog LDLo intramuscular 100mg/kg (100mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1391, 1935.
frog LDLo oral 300mg/kg (300mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1391, 1935.
frog LDLo unreported 250mg/kg (250mg/kg)   Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 29, Pg. 152, 1940.
guinea pig LDLo oral 600mg/kg (600mg/kg)   Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 29, Pg. 152, 1940.
guinea pig LDLo subcutaneous 150mg/kg (150mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1391, 1935.
human LDLo oral 80mg/kg (80mg/kg) BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS"

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: MUSCLE WEAKNESS
JAMA, Journal of the American Medical Association. Vol. 119, Pg. 1177, 1942.
man TDLo oral 428mg/kg (428mg/kg) BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS"

BEHAVIORAL: TOXIC PSYCHOSIS

GASTROINTESTINAL: ULCERATION OR BLEEDING FROM STOMACH
Archiv fuer Toxikologie. Vol. 23, Pg. 66, 1967.
mouse LD50 intraperitoneal 600mg/kg (600mg/kg)   British Journal of Pharmacology and Chemotherapy. Vol. 4, Pg. 1, 1949.
mouse LD50 intravenous 88200ug/kg (88.2mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 29, Pg. 152, 1940.
mouse LD50 oral 594mg/kg (594mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 29, Pg. 152, 1940.
pigeon LDLo intramuscular 750mg/kg (750mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1391, 1935.
pigeon LDLo subcutaneous 500mg/kg (500mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1391, 1935.
rabbit LDLo intravenous 150mg/kg (150mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1391, 1935.
rabbit LDLo oral 500mg/kg (500mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1391, 1935.
rabbit LDLo subcutaneous 550mg/kg (550mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1391, 1935.
rat LD50 oral 854mg/kg (854mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 29, Pg. 152, 1940.
rat LDLo subcutaneous 1gm/kg (1000mg/kg)   Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 29, Pg. 152, 1940.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety Information about Potassium thiocyanate (CAS NO.333-20-0):
Hazard Codes: HarmfulXn,Xi
Risk Statements: 32-52/53-20/21/22
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. 
R32: Contact with acid liberates very toxic gas. 
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 13-61-36/37
S13: Keep away from food, drink and animal foodstuffs. 
S36/37: Wear suitable protective clothing and gloves. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
WGK Germany: 1
RTECS: XL1925000
Hazard Note: Irritant/Hygroscopic
HS Code: 28380000
A human poison by ingestion. Poison experimentally by intravenous route. An experimental teratogen. Moderately toxic by subcutaneous and ingestion routes. Large doses can cause skin eruptions, psychoses, and collapse. Incompatible with calcium chlorite and perchloryl fluoride. When heated to decomposition it emits very toxic fumes of CN, K2O, SOx, and NOx. See also THIOCYANATES.

Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. 
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Keep away from acids. Store protected from moisture.