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4028-23-3

Basic Information
CAS No.: 4028-23-3
Name: ALLYLDIMETHYLCHLOROSILANE
Article Data: 21
Molecular Structure:
Molecular Structure of 4028-23-3 (ALLYLDIMETHYLCHLOROSILANE)
Formula: C5H11ClSi
Molecular Weight: 134.681
Synonyms: Silane,allylchlorodimethyl- (6CI,7CI,8CI);Silane, chlorodimethyl-2-propenyl- (9CI);Allyldimethylchlorosilane;Allyldimethylsilylchloride;Chlorodimethyl(2-propenyl)silane;
EINECS: 223-706-2
Density: 0.879 g/cm3
Boiling Point: 114.5 °C at 760 mmHg
Flash Point: 5.6 °C
Solubility: Soluble in most organic solvents; reacts with alcohols, amines, and water.
Appearance: clear colorless to light yellow liquid
Hazard Symbols: FlammableF, CorrosiveC
Risk Codes: 11-34
Safety: 16-26-36/37/39-45
Transport Information: UN 2985 3/PG 2
PSA: 0.00000
LogP: 2.61630
Synthetic route
78847-25-3

allyl(2-chloropropyl)dimethylsilane

A

4028-23-3

Allylchlorodimethylsilane

B

Chloro-dimethyl-(2-methyl-pent-4-enyl)-silane

Conditions
ConditionsYield
Heating;A 95%
B 5%
75-78-5

dimethylsilicon dichloride

106-95-6

allyl bromide

A

4028-23-3

Allylchlorodimethylsilane

B

1113-12-8

diallyl(dimethyl)silane

Conditions
ConditionsYield
Stage #1: allyl bromide With indium In 1,3-dimethylimidazolidine at 20℃; for 1h;
Stage #2: dimethylsilicon dichloride In 1,3-dimethylimidazolidine at 70℃; for 3h;
A 90%
B 8%
762-72-1

allyl-trimethyl-silane

A

75-77-4

chloro-trimethyl-silane

B

4028-23-3

Allylchlorodimethylsilane

C

75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
With tungsten(VI) oxychloride In benzene at 50℃; for 60h;A 87%
B 7%
C 4%
2622-05-1

allylmagnesium bromide

75-78-5

dimethylsilicon dichloride

4028-23-3

Allylchlorodimethylsilane

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 25℃; for 16h;80%
1113-12-8

diallyl(dimethyl)silane

A

4028-23-3

Allylchlorodimethylsilane

B

75-78-5

dimethylsilicon dichloride

Conditions
ConditionsYield
With tungsten(VI) oxychloride In benzene at 50℃; for 60h;A 25%
B 74%
With tungsten(VI) oxychloride In benzene at 50℃; for 60h;A 25%
B 74%
75-78-5

dimethylsilicon dichloride

1730-25-2

allylmagnesium bromide

4028-23-3

Allylchlorodimethylsilane

Conditions
ConditionsYield
In diethyl ether for 2h; Heating;66%
28%
In diethyl ether
75-78-5

dimethylsilicon dichloride

107-05-1

3-chloroprop-1-ene

4028-23-3

Allylchlorodimethylsilane

Conditions
ConditionsYield
Stage #1: 3-chloroprop-1-ene With iodine; magnesium In diethyl ether at 20℃; for 12h;
Stage #2: dimethylsilicon dichloride In diethyl ether at 20℃; for 18h; Further stages.;
44%
60-29-7

diethyl ether

107-37-9

allyltrichlorosilane

75-16-1

methylmagnesium bromide

A

4028-23-3

Allylchlorodimethylsilane

B

1873-92-3

allyldichloromethylsilane

107-37-9

allyltrichlorosilane

75-16-1

methylmagnesium bromide

4028-23-3

Allylchlorodimethylsilane

Conditions
ConditionsYield
With diethyl ether
10605-40-0

(3-chloropropyl)dimethylchlorosilane

4028-23-3

Allylchlorodimethylsilane

Conditions
ConditionsYield
With piperidine
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    ALLYLDIMETHYLCHLOROSILANE

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  • Allylchlorodimethylsilane 4028-23-3

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    4028-23-3

    Allylchlorodimethylsilane 4028-23-3

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    ALLYLDIMETHYLCHLOROSILANE

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    4028-23-3

    Allylchlorodimethylsilane

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    The CAS register number of Allylchlorodimethylsilane is 4028-23-3. It also can be called as Silane, chlorodimethyl-2-propen-1-yl- and the IUPAC name about this chemical is chloro-dimethyl-prop-2-enylsilane. The molecular formula about this chemical

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  • AllylchlorodiMethylsilane

  • Casno:

    4028-23-3

    AllylchlorodiMethylsilane

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Specification

The CAS register number of Allylchlorodimethylsilane is 4028-23-3. It also can be called as Silane, chlorodimethyl-2-propen-1-yl- and the IUPAC name about this chemical is chloro-dimethyl-prop-2-enylsilane. The molecular formula about this chemical is C5H11ClSi and molecular weight is 134.68. It belongs to the following product categories, such as Monomer; Pentafluorophenylsilylation, etc. (GC Derivatizing Reagents); Si-Cl Compounds; Silylation (GC Derivatizing Reagents); Analytical Chemistry; GC Derivatizing Reagents; Monochlorosilanes; Si (Classes of Silicon Compounds); Vinylsilanes, Allylsilanes and so on.

Physical properties about Allylchlorodimethylsilane are: (1)ACD/LogP: 3.00; (2)ACD/LogD (pH 5.5): 3; (3)ACD/LogD (pH 7.4): 3; (4)#Freely Rotating Bonds: 2; (5)Index of Refraction: 1.416; (6)Molar Refractivity: 38.5 cm3; (7)Molar Volume: 153.2 cm3; (8)Polarizability: 15.26x10-24cm3; (9)Surface Tension: 18.4 dyne/cm; (10)Enthalpy of Vaporization: 33.83 kJ/mol; (11)Boiling Point: 114.5 °C at 760 mmHg; (12)Vapour Pressure: 23.6 mmHg at 25°C.

Preparation: this chemical can be prepared by dichloro-dimethyl-silane and allylmagnesium bromide. This reaction will need solvent diethyl ether. The reaction time is 2 hour(s) at heating. The yield is about 66%.

Uses of Allylchlorodimethylsilane: it can be used to produce allyldimethylsilyl benzhydryl ether with diphenylmethanol at heating. This reaction will need reagent Et3N and solvent diethyl ether with reaction time of 4 hours. The yield is about 83.2%.

When you are using this chemical, please be cautious about it as the following:
This chemical is highly flammable and it can cause burns. When you are using it, wear suitable protective clothing, gloves and eye/face protection, you also need keep away from sources of ignition. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice and in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

You can still convert the following datas into molecular structure:
(1)SMILES: C=CC[Si](C)(C)Cl
(2)InChI: InChI=1/C5H11ClSi/c1-4-5-7(2,3)6/h4H,1,5H2,2-3H3
(3)InChIKey: KMVZWUQHMJAWSY-UHFFFAOYAR
(4)Std. InChI: InChI=1S/C5H11ClSi/c1-4-5-7(2,3)6/h4H,1,5H2,2-3H3
(5)Std. InChIKey: KMVZWUQHMJAWSY-UHFFFAOYSA-N