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Basic Information
CAS No.: 537-26-8
Name: tropacocaine
Article Data: 11
Molecular Structure:
Molecular Structure of 537-26-8 (tropacocaine)
Formula: C15H19 N O2
Molecular Weight: 245.321
Synonyms: 1aH,5aH-Tropan-3b-ol, benzoate (ester) (8CI); 8-Azabicyclo[3.2.1]octan-3-ol, 8-methyl-,benzoate (ester), (3-exo)- (9CI); 8-Azabicyclo[3.2.1]octan-3-ol, 8-methyl-,benzoate (ester), exo-; Tropacocaine (6CI,7CI); 3b-Benzoyloxytropane; Benzoylpseudotropine;Pseudotropine benzoate; Pseudotropine, benzoate (ester); Tropacaine;Tropacocain; y-Tropinebenzoate
Density: 1.15g/cm3
Melting Point: 49°
Boiling Point: 339.9°Cat760mmHg
Flash Point: 122.3°C
Solubility: 1.055g/L(15 oC)
PSA: 29.54000
LogP: 2.40650
Related products
Synthetic route
98-88-4

benzoyl chloride

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537-26-8

tropacocain

Conditions
ConditionsYield
With triethylamine In toluene for 4h; Reflux;90%
With TEA In toluene for 3h; Heating;
98-88-4

benzoyl chloride

3β-hydroxy-8-methyl-8-azabicyclo[3.2.1]octane

537-26-8

tropacocain

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran at 20 - 30℃; for 2h;54%
93-97-0

benzoic acid anhydride

135-97-7

pseudotropine

537-26-8

tropacocain

Conditions
ConditionsYield
With water
50-00-0

formaldehyd

18470-33-2, 20811-95-4, 123202-90-4

Nortropacocaine

537-26-8

tropacocain

Conditions
ConditionsYield
With formic acid for 10h; Heating; Yield given;
18470-33-2, 20811-95-4, 123202-90-4

Nortropacocaine

537-26-8

tropacocain

Conditions
ConditionsYield
With formaldehyd; formic acid Heating; Yield given;
35772-45-3

tropacocaine-N oxide

7782-99-2

sulphurous acid

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tropacocain

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benzoic acid

120-29-6

3-tropanol

537-26-8

tropacocain

Conditions
ConditionsYield
With di-tert-butyl-diazodicarboxylate; polimer-immobilized triphenylphosphine In dichloromethane at 20℃; for 24h;
59171-91-4

cyclohepta-3,5-dien-1-yl benzoate

537-26-8

tropacocain

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1: 57 percent / ethanol; CCl4 / 1.) -20 deg C, 5 h, 2.) -10 deg C, 14 d
2: 98 percent / H2 / 5percent Pd/C / methanol / 7 h
3: Na2CO3 / 1.) chloroform, water, 0 deg C, 30 min, 2.) RT, 2h
4: 36 percent / pyridine, SOCl2 / CHCl3 / 1 h / Heating
5: 75 percent / potassium tert-butoxide / benzene; hexamethylphosphoric acid triamide / 2 h / Ambient temperature
6: H2 / 5percent Pd/C / methanol / 8 h / 760 Torr
7: aq. formic acid / 10 h / Heating
View Scheme
95687-87-9

N-<(benzyloxy)carbonyl>nortropacocaine

537-26-8

tropacocain

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: H2 / 5percent Pd/C / methanol / 8 h / 760 Torr
2: aq. formic acid / 10 h / Heating
View Scheme
Multi-step reaction with 2 steps
1: H2 / Pd/C / methanol
2: HCHO, HCO2H / Heating
View Scheme
95687-98-2

all-cis-3-(benzoyloxy)-5-(<(benzyloxy)carbonyl>amino)-cycloheptanol

537-26-8

tropacocain

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 36 percent / pyridine, SOCl2 / CHCl3 / 1 h / Heating
2: 75 percent / potassium tert-butoxide / benzene; hexamethylphosphoric acid triamide / 2 h / Ambient temperature
3: H2 / 5percent Pd/C / methanol / 8 h / 760 Torr
4: aq. formic acid / 10 h / Heating
View Scheme
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65-85-0
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