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| CAS No.: | 6018-89-9 |
|---|---|
| Name: | Nickel(II) acetate tetrahydrate |
| Article Data: | 22 |
| Molecular Structure: | |
|
|
|
| Formula: | C4H16NiO8 |
| Molecular Weight: | 248.84 |
| Synonyms: | Diacetatonickeltetrahydrate;Nickel acetate [Ni(OAc)2.4H2O], tetrahydrate;Nickel acetate tetrahydrate;Nickel diacetate tetrahydrate;Nickel(2+) acetate tetrahydrate;Nickel(2+)diacetate tetrahydrate;Nickel(Ⅱ)acetate; |
| EINECS: | 206-761-7 |
| Density: | 1.798 g/mL at 25 °C(lit.) |
| Melting Point: | °Cd ec.) |
| Boiling Point: | 117.1 °C at 760 mmHg |
| Flash Point: | 40 °C |
| Solubility: | 182 g/L (20 °C) in water |
| Appearance: | Green monoclinic crystal |
| Hazard Symbols: |
 Xn
|
| Risk Codes: | 45-22-43-40 |
| Safety: | 53-36/37-45-24-22 |
| PSA: | 89.52000 |
| LogP: | -0.22960 |
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- 719261-06-0
nickel(II) carbonate
- 7732-18-5
water
- 64-19-7
acetic acid
- 6018-89-9
nickel(II) acetate tetrahydrate
| Conditions | Yield |
|---|---|
| In water recrystalization (D2O); |
| Conditions | Yield |
|---|---|
| In acetic acid | |
| In acetic acid aq. acetic acid; |
| Conditions | Yield |
|---|---|
| In water Electrolysis; | |
| In water Electrolysis; |
| Conditions | Yield |
|---|---|
| In acetic acid aq. acetic acid; |
| Conditions | Yield |
|---|---|
| With oxygen In acetic acid heating while passing O2 over a suspension of Ni and NiBr2 in 40% acetic acid at 100°C for more than 3.5 h;; | |
| In acetic acid dissolving in concd. acetic acid, heating;; | |
| With O2; Ni bromide In acetic acid aq. acetic acid; heating while passing O2 over a suspension of Ni and NiBr2 in 40% acetic acid at 100°C for more than 3.5 h;; | |
| In acetic acid aq. acetic acid; dissolving in concd. acetic acid, heating;; | |
| In acetic acid dissolving in concd. acetic acid, heating;; |
| Conditions | Yield |
|---|---|
| In acetic acid in autoclave at 120°C;; | |
| In acetic acid aq. acetic acid; in autoclave at 120°C;; | |
| In acetic acid in autoclave at 120°C;; |
| Conditions | Yield |
|---|---|
| In acetic acid in autoclave at 120°C;; | |
| In acetic acid aq. acetic acid; in autoclave at 120°C;; | |
| In acetic acid in autoclave at 120°C;; |
| Conditions | Yield |
|---|---|
| In water | |
| In water |
| Conditions | Yield |
|---|---|
| With water In water | |
| With H2O In water |
- 917-23-7
5,10,15,20-tetraphenyl-21H,23H-porphine
- 6018-89-9
nickel(II) acetate tetrahydrate
- 14172-92-0
5,10,15,20-tetraphenylporphinatonickel(II)
| Conditions | Yield |
|---|---|
| In pyridine other Radiation; porphyrin, metal salt and pyridine were sealed in a glass tube, microwave power of 300 W, heated from room temp. to 180°C, stirred for 15min, cooled to 50°C; vessel was opened, decanted, TLC (silica gel), UV; | 100% |
| In methanol; chloroform tetraphenylporphyrin (300 mg) and Ni(OAc)2*4H2O (1 g) refluxed (16 h) inCHCl3/MeOH (2:1); cooled; solvent removed (vac.); dissolved in CHCl3; chromd. (silica, CHCl3); | 99% |
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Consensus Reports
Standards and Recommendations
ACGIH TLV: TWA 0.2 mg(Ni)/m3; Human Carcinogen
NIOSH REL: (Inorganic Nickel) TWA 0.015 mg(Ni)/m3
Specification
The Nickel acetate tetrahydrate, with the CAS registry number 6018-89-9 and EINECS registry number 206-761-7, has the systematic name of nickel(2+) acetate hydrate (1:2:4). It is a kind of hygroscopic green monoclinic crystal. And the molecular formula of this chemical is C4H16NiO8. What's more, it is usually used as chemical reagent, and it is also used as catalyst in the nickelage and coloration of metal and nickelage.
The physical properties of Nickel acetate tetrahydrate are as followings: (1)ACD/LogP: -0.29; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.07; (4)ACD/LogD (pH 7.4): -2.86; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 2.73; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 37.3 Å2; (13)Flash Point: 40 °C; (14)Enthalpy of Vaporization: 23.7 kJ/mol; (15)Boiling Point: 117.1 °C at 760 mmHg; (16)Vapour Pressure: 13.9 mmHg at 25°C.
Preparation: Dissolve the basic nickel carbonate in excessive dilute acetic acid. Then, after a series of filtration, evaporation, cooling crystallization and drying, you can get product.
You should be cautious while dealing with this chemical. It is harmful if swallowed, and may cause sensitization by skin contact. What's more, it may cause cancer. Therefore, you had better take the following instructions: Do not breathe dust; Avoid contact with skin ; Avoid exposure - obtain special instruction before use; Wear suitable protective clothing and gloves, and in case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: [Ni+2].[O-]C(=O)C.[O-]C(=O)C.O.O.O.O
(2)InChI: InChI=1/2C2H4O2.Ni.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2
(3)InChIKey: OINIXPNQKAZCRL-NUQVWONBAQ
The toxicity data is as follows:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 45700ug/kg (45.7mg/kg) | Research Communications in Chemical Pathology and Pharmacology. Vol. 30, Pg. 133, 1980. | |
| mouse | LD50 | oral | 410mg/kg (410mg/kg) | Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 22, Pg. 455, 1980. | |
| rat | LD50 | oral | 350mg/kg (350mg/kg) | Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 22, Pg. 455, 1980. |