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Basic Information
CAS No.: 609-06-3
Name: L-Xylose
Molecular Structure:
Molecular Structure of 609-06-3 (L-Xylose)
Formula: C5H10O5
Molecular Weight: 150.131
Synonyms: Xylose, L-(8CI);NSC 26213;L(+)-Xylose;
EINECS: 210-174-1
Density: 1.508 g/cm3
Melting Point: 150-152 °C(lit.)
Boiling Point: 415.5 °C at 760 mmHg
Flash Point: 219.2 °C
Solubility: within almost transparency
Appearance: fine crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 24/25-36-26
PSA: 97.99000
LogP: -2.73970
Synthetic route
124244-64-0

(2S,3R,4S)-5,5-Diethoxy-pentane-1,2,3,4-tetraol

609-06-3

L-xylose

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran95%
1195193-89-5

Tetra-O-acetyl-aldehydo-L-xylose

609-06-3

L-xylose

Conditions
ConditionsYield
With sodium ethanolate at 20 - 30℃;92%
5328-37-0

L-arabinose

A

609-06-3

L-xylose

B

1949-78-6

L-lyxose

C

24259-59-4

L-ribose

Conditions
ConditionsYield
With molybdenum(VI) oxide In water at 90℃; for 9h; Bilik reaction;A n/a
B n/a
C 19%
139404-79-8

(2S,3S,4R)-5-hexene-1,2,3,4-tetrol

609-06-3

L-xylose

Conditions
ConditionsYield
With ozone; sodium sulfite 1.) MeOH, -78 deg C, 2. a) -78 deg C, 1 h, b) r.t., 15 h; Yield given. Multistep reaction;
137491-74-8

3,4,5,6-tetra-O-acetyl-1,2-dideoxy-L-xylo-hex-1-enitol

609-06-3

L-xylose

Conditions
ConditionsYield
Yield given. Multistep reaction;
50-81-7

ascorbic acid

A

98-01-1

furfural

B

609-06-3

L-xylose

C

124-38-9

carbon dioxide

O1,O3;O2,O4-diethylidene-D-glucitol

O1,O3;O2,O4-diethylidene-D-glucitol

609-06-3

L-xylose

Conditions
ConditionsYield
With lead(IV) acetate; acetic acid anschliessendes Erwaermen mit wss.Schwefelsaeure;
With lead(II,IV) oxide; acetic acid anschliessendes Behandeln mit wss.Schwefelsaeure,zuletz bei 100grad;
With sodium periodate anschliessendes Behandeln mit wss.Saeure;
O2,O4-benzylidene-D-glucitol

O2,O4-benzylidene-D-glucitol

609-06-3

L-xylose

Conditions
ConditionsYield
With lead(IV) acetate; acetic acid Erwaermen des Reaktionsprodukts mit wss.Essigsaeure;
With water; periodic acid Erwaermen des Reaktionsprodukts mit Essigsaeure;
O2,O4-furfurylidene-D-glucitol

O2,O4-furfurylidene-D-glucitol

609-06-3

L-xylose

Conditions
ConditionsYield
With lead(IV) acetate; ammonium hydroxide; acetic acid anschliessendes Erhitzen;
78008-36-3, 92822-62-3, 99744-77-1

(S)-cyclohexylidene glyceraldehyde

polymer bonded 2-phenyl-1,3,2-dioxaborole

polymer bonded 2-phenyl-1,3,2-dioxaborole

A

609-06-3

L-xylose

B

1949-78-6

L-lyxose

C

24259-59-4

L-ribose

D

5328-37-0

L-arabinose

Conditions
ConditionsYield
In dichloromethane Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
In dichloromethane Ambient temperature; Yield given. Yields of byproduct given;
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Specification

The CAS registry number of L-(-)-Xylose is 609-06-3. The systematic name is L-xylose. Its EINECS registry number is 210-174-1. In addition, the molecular formula is C5H10O5 and the molecular weight is 150.13. It is a kind of white fine crystalline powder and belongs to the classes of Carbohydrate; Basic Sugars (Mono & Oligosaccharides); Biochemistry; Sugars; Xylose; Carbohydrate Sources (Sugars/Extracts); MonosaccharidesBase Ingredients; Sugars for Media; Carbohydrate Synthesis; Specialty Synthesis; Monosaccharides.

Physical properties about this chemical are: (1)ACD/LogP: -2.39; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -2.39; (4)ACD/LogD (pH 7.4): -2.39; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1.19; (8)ACD/KOC (pH 7.4): 1.19; (9)#H bond acceptors: 5; (10)#H bond donors: 4; (11)#Freely Rotating Bonds: 8; (12)Polar Surface Area: 53.99 Å2; (13)Index of Refraction: 1.543; (14)Molar Refractivity: 31.41 cm3; (15)Molar Volume: 99.5 cm3; (16)Polarizability: 12.45 ×10-24cm3; (17)Surface Tension: 81.4 dyne/cm; (18)Density: 1.508 g/cm3; (19)Flash Point: 219.2 °C; (20)Enthalpy of Vaporization: 77.23 kJ/mol; (21)Boiling Point: 415.5 °C at 760 mmHg; (22)Vapour Pressure: 1.22E-08 mmHg at 25°C.

Preparation of L-(-)-Xylose: it can be prepared by 5,5-diethoxy-pentane-1,2,3,4-tetraol. This reaction will need reagent 0.5 M aq. HCl and solvent tetrahydrofuran. The yield is about 95%.

L-(-)-Xylose can be prepared by 5,5-diethoxy-pentane-1,2,3,4-tetraol

Uses of L-(-)-Xylose: it can react with propylamine to get N-propyl-b-L-arabinopyranosylamine. This reaction will need solvent methanol. The yield is about 88%.

L-(-)-Xylose can react with propylamine to get N-propyl-b-L-arabinopyranosylamine

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. During using it, wear suitable protective clothing and avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C[C@H](O)[C@@H](O)[C@H](O)CO
(2)InChI: InChI=1/C5H10O5/c6-1-3(8)5(10)4(9)2-7/h1,3-5,7-10H,2H2/t3-,4+,5+/m0/s1
(3)InChIKey: PYMYPHUHKUWMLA-VPENINKCBR