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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
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  • Name [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
  • EINECS460-040-3
  • CAS No. 72287-26-4
  • DensityN/A
  • PSA27.18000
  • LogP7.76790
  • SolubilityN/A
  • Melting Point275-280 °C(lit.)
  • FormulaC34H28Cl2FeP2Pd
  • Boiling PointN/A
  • Molecular Weight851.095
  • Flash PointN/A
  • Transport InformationN/A
  • AppearanceN/A
  • Safety23-24/25-26-36/37
  • Risk Codes20/21/22-36/37/38-40
  • Molecular Structure
    Molecular Structure of 72287-26-4 ([1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II))
  • Hazard SymbolsHarmfulXn, IrritantXi
  • SynonymsHarmfulXn, IrritantXi
  • Article Data25

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Synthetic route

12150-46-8

1,1'-bis-(diphenylphosphino)ferrocene

14592-56-4, 21264-30-2, 90243-59-7

bis(acetonitrile)palladium(II) chloride

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

Conditions
ConditionsYield
In benzene stirred at room temp. for 12 h; ppt. filtered, washed with benzene, dried in vac., recrystn. (CHCl3); elem. anal.;97%
12150-46-8

1,1'-bis-(diphenylphosphino)ferrocene

14568-12-8, 38929-74-7, 244265-98-3, 12386-08-2, 15280-84-9

Pd(DMSO)2Cl2

67-66-3

chloroform

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

Conditions
ConditionsYield
for 0.5h; Heating;

sodium hexaflorophosphate

736-52-7

1-((5-nitrofuran-2-yl)methylene)-4-phenylthiosemicarbazone

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

75-09-2

dichloromethane

[palladium(II)(1,1’-bis(diphenylphosphino)ferrocene)(5-nitrofuryl-N-phenylthiosemicarbazonato)](hexafluorophosphate)*1.5(dichloromethane)

Conditions
ConditionsYield
Stage #1: 1-((5-nitrofuran-2-yl)methylene)-4-phenylthiosemicarbazone; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct In methanol at 20℃; for 1h;
Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling;
Stage #3: dichloromethane In methanol		71%

sodium hexaflorophosphate

24186-28-5

4-ethyl-1-(5-nitrofuran2-yl-methylene)thiosemicarbazide

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

75-09-2

dichloromethane

[palladium(II)(1,1’-bis(diphenylphosphino)ferrocene)(5-nitrofuryl-N-ethylthiosemicarbazonato)](hexafluorophosphate) dichloromethane disolvate

Conditions
ConditionsYield
Stage #1: 4-ethyl-1-(5-nitrofuran2-yl-methylene)thiosemicarbazide; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct In methanol at 20℃; for 1h;
Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling;
Stage #3: dichloromethane In methanol		64%

sodium hexaflorophosphate

24199-84-6

5-nitrofurfural 4-methyl-thiosemicarbazone

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

75-09-2

dichloromethane

[palladium(II)(1,1’-bis(diphenylphosphino)ferrocene)(5-nitrofuryl-N-methylthiosemicarbazonato)](hexafluorophosphate) dichloromethane disolvate

Conditions
ConditionsYield
Stage #1: 5-nitrofurfural 4-methyl-thiosemicarbazone; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct In methanol at 20℃; for 1h;
Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling;
Stage #3: dichloromethane In methanol		62%

sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

75-09-2

dichloromethane

831-71-0, 146827-83-0

5-nitro-furfural thiosemicarbazone

[palladium(II)(1,1’-bis(diphenylphosphino)ferrocene)(5-nitrofuryl-thiosemicarbazonato)](hexafluorophosphate) dichloromethane monosolvate

Conditions
ConditionsYield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; 5-nitro-furfural thiosemicarbazone In methanol at 20℃; for 1h;
Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling;
Stage #3: dichloromethane In methanol		61%

sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

42887-08-1

Sodium salt of tropolone

[Pd(Trop)(1,1′-bis(dipheny1phosphino)ferrocene)](hexafluorophosphate)

Conditions
ConditionsYield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; Sodium salt of tropolone In methanol at 20℃; for 24h;
Stage #2: sodium hexaflorophosphate In methanol for 24h;		49%

sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

17387-01-8

sodium salt of 4-isopropyltropolone

[Pd(Hino)(1,1′-bis(dipheny1phosphino)ferrocene)](hexafluorophosphate)

Conditions
ConditionsYield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; sodium salt of 4-isopropyltropolone In methanol for 6h; Reflux;
Stage #2: sodium hexaflorophosphate In methanol for 24h;		44%

sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

4008-48-4

nitroxoline

[PdII(5-nitro-8-quinolinolynate)(1,1’-bis(diphenylphosphino)ferrocene)](PF6)

Conditions
ConditionsYield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; nitroxoline With triethylamine In methanol for 5h; Reflux;
Stage #2: sodium hexaflorophosphate In methanol for 0.25h;		41%

sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

773-76-2

chloroxine

[PdII(5,7-dichloro-8-quinolinolynate)(1,1’-bis(diphenylphosphino)ferrocene)](PF6)

Conditions
ConditionsYield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; chloroxine With triethylamine In methanol at 20℃; for 15 - 24h;
Stage #2: sodium hexaflorophosphate In methanol for 0.25h;		37%

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties

The Molecular Structure of  [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (CAS NO.72287-26-4):

Empirical Formula: C34H28Cl2FeP2Pd
Molecular Weight: 731.7046
Nominal Mass: 730 Da
Average Mass: 731.7046 Da
Monoisotopic Mass: 729.942753 Da 
Melting Point: 275-280 °C(lit.)
Product Categories: Metal Compounds;pharmacetical;API intermediates;Catalysts-Ligands;Catalysts for Organic Synthesis;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Homogeneous Catalysts;Metal Complexes;Metallocenes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;Palladium 

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Safety Profile

Hazard Codes: HarmfulXnIrritantXi
Risk Statements: 20/21/22-36/37/38-40 
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed
R36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements: 23-24/25-26-36/37 
S23:Do not breathe vapour
S24/25:Avoid contact with skin and eyes
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37:Wear suitable protective clothing and gloves
Hazard Note: Irritant

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Specification

 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (CAS NO.72287-26-4) is also called as1,1-Bis(diphenylphosphino)ferrocenedichloropalladium(ii) ; 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ; 1,1'-Bis(diphenylphosphino)ferrocenepalladium(ii) dichloride ; Pdcl2(dppf);dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (ii) dichloromethane add ; [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium ; (ii)Dichloromethane adduct .

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