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| CAS No.: | 75-62-7 |
|---|---|
| Name: | Bromotrichloro methane |
| Article Data: | 60 |
| Molecular Structure: | |
|
|
|
| Formula: | CBrCl3 |
| Molecular Weight: | 198.274 |
| Synonyms: | Bromotrichlormethane;Bromotrichloromethane;Carbon bromide trichloride (CBrCl3);Carbonbromotrichloride;Carbon trichlorobromide;Monobromotrichloromethane;NSC 8017;Trichlorobromomethane;Trichloromethyl bromide; |
| EINECS: | 200-886-0 |
| Density: | 2.145 g/cm3 |
| Melting Point: | ?6 °C(lit.) |
| Boiling Point: | 103.5 °C at 760 mmHg |
| Flash Point: | 18.6 °C |
| Solubility: | insoluble in water |
| Appearance: | Clear colourless to slightly yellow liquid |
| Hazard Symbols: |
 Xn
|
| Risk Codes: | 20/21/22-36/37/38 |
| Safety: | 36/37-36/37/39-26 |
| Transport Information: | UN 2810 |
| PSA: | 0.00000 |
| LogP: | 2.70900 |
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| Conditions | Yield |
|---|---|
| With bromine at 59℃; Temperature; Wavelength; Reagent/catalyst; Irradiation; Inert atmosphere; | 99% |
| With bromine im Licht; | |
| With bromine at 225 - 275℃; im Rohr; |
- 56-23-5
tetrachloromethane
A
- 75-62-7
Bromotrichloromethane
B
- 594-18-3
dibromodichloromethane
C
- 594-15-0
chlorotribromomethane
| Conditions | Yield |
|---|---|
| With aluminum tri-bromide for 8h; Heating; | A n/a B n/a C 12% |
| Conditions | Yield |
|---|---|
| With aluminum tri-bromide | |
| With aluminum tri-bromide | |
| With aluminium trichloride; hydrogen bromide |
| Conditions | Yield |
|---|---|
| With dibenzoyl peroxide | |
| In neat (no solvent) formation on heating with CBr4 in presence of dibenzoylperoxide;; | |
| In neat (no solvent) formation on heating with CBr4 in presence of dibenzoylperoxide;; |
| Conditions | Yield |
|---|---|
| at 400℃; in Glasrohr; |
- 56-23-5
tetrachloromethane
A
- 75-62-7
Bromotrichloromethane
B
- 594-18-3
dibromodichloromethane
C
- 594-15-0
chlorotribromomethane
D
- 558-13-4
carbon tetrabromide
| Conditions | Yield |
|---|---|
| With Bromoform; tetranormalbutyl ammonium fluoride for 0.166667h; Product distribution; Mechanism; Ambient temperature; equilibrium; products determined by GC-MS; |
| Conditions | Yield |
|---|---|
| With bromine at 26.9℃; Rate constant; Kinetics; Thermodynamic data; other temp.: 358, 399, 456, 532 deg K; | |
| With bromine at 26.85℃; under 990.079 Torr; Kinetics; Further Variations:; Temperatures; Pressures; |
| Conditions | Yield |
|---|---|
| With bromine; chlorine In trichlorofluoromethane at 10℃; for 0.25h; Irradiation; Yield given; | |
| With bromine; chlorine In trichlorofluoromethane at 10℃; for 0.25h; Irradiation; Yield given; |
- 594-18-3
dibromodichloromethane
A
- 56-23-5
tetrachloromethane
B
- 75-62-7
Bromotrichloromethane
C
- 594-15-0
chlorotribromomethane
D
- 558-13-4
carbon tetrabromide
| Conditions | Yield |
|---|---|
| With acidic acceptor; tetranormalbutyl ammonium fluoride for 0.166667h; Product distribution; Mechanism; Ambient temperature; equilibrium; products determined by GC-MS; |
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Chemistry
Molecular Formula: CBrCl3
Molar mass: 198.27 g/mol
EINECS: 200-886-0
Density: 2.145 g/cm3
Flash Point: 18.6 °C
Index of Refraction: 1.538
Boiling Point: 103.5 °C at 760 mmHg
Vapour Pressure: 37.2 mmHg at 25°C
Melting point: −6 °C(lit.)
Water solubility: Insoluble
Appearance: Clear colourless to slightly yellow liquid
Product categories of Bromocriptine mesylate (22260-51-1): Chain Transfer Agents;Halogenation;Synthetic Organic Chemistry;Polymer Additives;Organics;Bromination
Structure of Bromotrichloromethane (75-62-7):
XLogP3-AA: 2.9
H-Bond Donor: 0
H-Bond Acceptor: 0
IUPAC Name: Bromo(trichloro)methane
Canonical SMILES: C(Cl)(Cl)(Cl)Br
InChI: InChI=1S/CBrCl3/c2-1(3,4)5
InChIKey: XNNQFQFUQLJSQT-UHFFFAOYSA-N
Toxicity Data With Reference
| 1. | dnd-mam:lym 1 mmol/L | TOLED5 Toxicology Letters. 11 (1982),243. | ||
| 2. | orl-rat LDLo:100 mg/kg | IJMDAI Israel Journal of Medical Sciences. 10 (1974),301. | ||
| 3. | ipr-rat LD50:119 mg/kg | FAATDF Fundamental and Applied Toxicology. 2 (1982),161. |
Carcinogenicity of Bromotrichloromethane (75-62-7) hasn't been listed as a carcinogen by NTP,IARC,ACGIH, or CA Prop 65. And its toxicological properties have not been fully investigated.
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Poison by ingestion and intraperitoneal routes. Narcotic in high concentration. Mutation data reported. See also CHLOROFORM. Incompatible with ethylene. When heated to decomposition it emits very toxic fumes of Cl− and Br−.
Hazard Codes: Xn.gif){kind=small}
Risk Statements:
20: Harmful by inhalation
21: Harmful in contact with skin
22: Harmful if swallowed
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection
Specification
Bromotrichloromethane (75-62-7) also can be called Methane, bromotrichloro- ; Monobromotrichloromethane . is hazardous,so the first aid measures and others should be known.Such as: When on the skin: first,should flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing. Secondly,Get shoesmedical aid . Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Give artificial respiration while not breathing. When breathing is difficult, give oxygen.And as soon as to get medical aid.Then you have the ingesting of the product : Wash mouth out with water,and get medical aid immediately.Notes to physician: Treat supportively and symptomatically.
In addition, Bromotrichloromethane (75-62-7) can be stable under normal temperature and pressure conditions.It is not compatible with strong oxidizing agents,strong bases,and you must not take it with incompatible materials.And also prevent it to broken down into hazardous decomposition products: hydrogen bromide,carbon dioxide,carbon monoxide, hydrogen chloride.