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75-62-7

Basic Information
CAS No.: 75-62-7
Name: Bromotrichloro methane
Article Data: 60
Molecular Structure:
Molecular Structure of 75-62-7 (Bromotrichloro methane)
Formula: CBrCl3
Molecular Weight: 198.274
Synonyms: Bromotrichlormethane;Bromotrichloromethane;Carbon bromide trichloride (CBrCl3);Carbonbromotrichloride;Carbon trichlorobromide;Monobromotrichloromethane;NSC 8017;Trichlorobromomethane;Trichloromethyl bromide;
EINECS: 200-886-0
Density: 2.145 g/cm3
Melting Point: ?6 °C(lit.)
Boiling Point: 103.5 °C at 760 mmHg
Flash Point: 18.6 °C
Solubility: insoluble in water
Appearance: Clear colourless to slightly yellow liquid
Hazard Symbols: HarmfulXn
Risk Codes: 20/21/22-36/37/38
Safety: 36/37-36/37/39-26
Transport Information: UN 2810
PSA: 0.00000
LogP: 2.70900
Synthetic route
67-66-3

chloroform

75-62-7

Bromotrichloromethane

Conditions
ConditionsYield
With bromine at 59℃; Temperature; Wavelength; Reagent/catalyst; Irradiation; Inert atmosphere;99%
With bromine im Licht;
With bromine at 225 - 275℃; im Rohr;
56-23-5

tetrachloromethane

A

75-62-7

Bromotrichloromethane

B

594-18-3

dibromodichloromethane

C

594-15-0

chlorotribromomethane

Conditions
ConditionsYield
With aluminum tri-bromide for 8h; Heating;A n/a
B n/a
C 12%
56-23-5

tetrachloromethane

75-62-7

Bromotrichloromethane

Conditions
ConditionsYield
With aluminum tri-bromide
With aluminum tri-bromide
With aluminium trichloride; hydrogen bromide
128-08-5

N-Bromosuccinimide

67-66-3

chloroform

75-62-7

Bromotrichloromethane

67-66-3

chloroform

558-13-4

carbon tetrabromide

75-62-7

Bromotrichloromethane

Conditions
ConditionsYield
With dibenzoyl peroxide
In neat (no solvent) formation on heating with CBr4 in presence of dibenzoylperoxide;;
In neat (no solvent) formation on heating with CBr4 in presence of dibenzoylperoxide;;
34069-94-8

trichloro-acetyl bromide

A

75-62-7

Bromotrichloromethane

B

67-72-1

hexachloroethane

Conditions
ConditionsYield
at 400℃; in Glasrohr;
56-23-5

tetrachloromethane

A

75-62-7

Bromotrichloromethane

B

594-18-3

dibromodichloromethane

C

594-15-0

chlorotribromomethane

D

558-13-4

carbon tetrabromide

Conditions
ConditionsYield
With Bromoform; tetranormalbutyl ammonium fluoride for 0.166667h; Product distribution; Mechanism; Ambient temperature; equilibrium; products determined by GC-MS;
3170-80-7

trichloromethyl radical

75-62-7

Bromotrichloromethane

Conditions
ConditionsYield
With bromine at 26.9℃; Rate constant; Kinetics; Thermodynamic data; other temp.: 358, 399, 456, 532 deg K;
With bromine at 26.85℃; under 990.079 Torr; Kinetics; Further Variations:; Temperatures; Pressures;
67-66-3

chloroform

A

56-23-5

tetrachloromethane

B

75-62-7

Bromotrichloromethane

Conditions
ConditionsYield
With bromine; chlorine In trichlorofluoromethane at 10℃; for 0.25h; Irradiation; Yield given;
With bromine; chlorine In trichlorofluoromethane at 10℃; for 0.25h; Irradiation; Yield given;
594-18-3

dibromodichloromethane

A

56-23-5

tetrachloromethane

B

75-62-7

Bromotrichloromethane

C

594-15-0

chlorotribromomethane

D

558-13-4

carbon tetrabromide

Conditions
ConditionsYield
With acidic acceptor; tetranormalbutyl ammonium fluoride for 0.166667h; Product distribution; Mechanism; Ambient temperature; equilibrium; products determined by GC-MS;
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Chemistry

Molecular Formula: CBrCl3
Molar mass: 198.27 g/mol
EINECS: 200-886-0
Density: 2.145 g/cm3
Flash Point: 18.6 °C
Index of Refraction: 1.538
Boiling Point: 103.5 °C at 760 mmHg
Vapour Pressure: 37.2 mmHg at 25°C
Melting point: −6 °C(lit.)
Water solubility: Insoluble
Appearance: Clear colourless to slightly yellow liquid
Product categories of Bromocriptine mesylate (22260-51-1): Chain Transfer Agents;Halogenation;Synthetic Organic Chemistry;Polymer Additives;Organics;Bromination
Structure of Bromotrichloromethane (75-62-7):
             
XLogP3-AA: 2.9
H-Bond Donor: 0
H-Bond Acceptor: 0
IUPAC Name: Bromo(trichloro)methane
Canonical SMILES: C(Cl)(Cl)(Cl)Br
InChI: InChI=1S/CBrCl3/c2-1(3,4)5 
InChIKey: XNNQFQFUQLJSQT-UHFFFAOYSA-N

Toxicity Data With Reference

1.    

dnd-mam:lym 1 mmol/L

    TOLED5    Toxicology Letters. 11 (1982),243.
2.    

orl-rat LDLo:100 mg/kg

    IJMDAI    Israel Journal of Medical Sciences. 10 (1974),301.
3.    

ipr-rat LD50:119 mg/kg

    FAATDF    Fundamental and Applied Toxicology. 2 (1982),161.

Carcinogenicity of Bromotrichloromethane (75-62-7) hasn't been listed as a carcinogen by NTP,IARC,ACGIH, or CA Prop 65. And its toxicological properties have not been fully investigated.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion and intraperitoneal routes. Narcotic in high concentration. Mutation data reported. See also CHLOROFORM. Incompatible with ethylene. When heated to decomposition it emits very toxic fumes of Cl and Br.
 

Hazard Codes: Xn
Risk Statements:
20:  Harmful by inhalation
21:  Harmful in contact with skin
22:  Harmful if swallowed 
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin
Safety Statements:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing 
37:  Wear suitable gloves
39:  Wear eye/face protection

Specification

 Bromotrichloromethane (75-62-7) also can be called Methane, bromotrichloro- ; Monobromotrichloromethane . is hazardous,so the first aid measures and others should be known.Such as: When on the skin: first,should  flush skin with plenty of water immediatelyfor at least 15 minutes while removing contaminated clothing. Secondly,Get shoesmedical aid . Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.Then get medical aid soon.While ,it's Inhaled: Remove from exposure and move to fresh air immediately.Give artificial respiration while not breathing. When breathing is difficult, give oxygen.And as soon as to get medical aid.Then you have the ingesting of the product : Wash mouth out with water,and get medical aid immediately.Notes to physician: Treat supportively and symptomatically.
In addition, Bromotrichloromethane (75-62-7) can be stable under normal temperature and pressure conditions.It is not compatible with strong oxidizing agents,strong bases,and you must not take it with incompatible materials.And also prevent it to broken down into hazardous decomposition products: hydrogen bromide,carbon dioxide,carbon monoxide, hydrogen chloride.