CAS No.67-72-1,Perchloroethane Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	67-72-1
Name:	Perchloroethane
Article Data:	390

Formula:	C₂Cl₆
Molecular Weight:	236.74
Synonyms:	Phenohep;Ethane,hexachloro- (8CI,9CI);1,1,1,2,2,2-Hexachloroethane;1,2-Dichloro-1,1,2,2-tetrachloroethane;Avlothane;Distokal;Distopan;Distopin;Egitol;Ethane hexachloride;Falkitol;Fasciolin;Fron 110;Hexachlorethane;Mottenhexe;NSC 9224;Perchloroethane;
EINECS:	200-666-4
Density:	1.821 g/cm³
Melting Point:	184 °C
Boiling Point:	186.8 °C at 760 mmHg
Flash Point:	61.3 °C
Solubility:	0.05 g/L (22 °C) in water
Appearance:	white crystalline powder
Hazard Symbols:	Xn, N, T, F
Risk Codes:	40-51/53-36/37/38-39/23/24/25-36/38-23/24/25-11
Safety:	36/37-61-45-36/37/39-26-24-16-7
Transport Information:	UN 9037
PSA:	0.00000
LogP:	3.72680

Synthetic route

: 10170-69-1
dimanganese decacarbonyl

A: 14100-30-2
pentacarbonylchloromanganese(I)

B: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With tetrachloromethane In tetrachloromethane byproducts: CCl3; Irradiation (UV/VIS); Irradiation λ >350 nm, CCl4, Ar atm.;; detected by IR spectra and GCA;;	A n/a B 100%

: hexacarbonyl-bis(η5-methylcyclopentadienyl)dimolybdenum

A: MoCl(CO)3(η5-C5H4CH3)

B: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With tetrachloromethane In tetrachloromethane Irradiation (UV/VIS); Irradiation λ >490 nm, CCl4, Ar atm.;; detected by IR spectra and GCA;;	A n/a B 100%
With tetrachloromethane In tetrachloromethane; acetone Irradiation (UV/VIS); Irradiation λ >490 nm, acetone:CCl4=3:1, Ar atm.;; detected by IR spectra and GCA;;	A >99 B 70%

: perchloro-1,3-butanediol

: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); chlorine at 130℃; under 11251.1 Torr; Reagent/catalyst; Temperature; Pressure;	99%

: C21H14N2O2

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 1885-81-0
p-chlorophenyl isocyanide

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 98% D n/a

...Expand

: Cp(CO)2Re(CH3)2

: 75-62-7
Bromotrichloromethane

A: 74-83-9
methyl bromide

B: tricarbonylcyclopentadienylrhenium

C: C5H5(CO)2Re(CH3)Br

D: C5H5Re(CO)2(CH3)Cl

E: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With carbon monoxide In further solvent(s) Irradiation (UV/VIS); Irradiation of complex at 350-380 nm under 20 atm of CO in CBrCl3;;	A 81-87 B 97% C 78-85 D <4 E >65

...Expand

: 56-23-5
tetrachloromethane

: 118334-80-8
N-acyloxyphthalimide

A: 136918-14-4
phthalimide

B: 67-72-1
hexachloroethane

C: 1-(tert-butyl)-4-(3-chloropropyl)benzene

D CO2: CO2

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane In water; tert-butyl alcohol for 3h; Product distribution; Quantum yield; Irradiation; ratio, without DABCO;	A 95% B 70% C 74% D n/a

...Expand

: 77743-10-3
(2,5,6-trimethylbenzyl)bis(dimethylglyoximato)pyridinecobalt(III)

: 75-62-7
Bromotrichloromethane

A: bromo Co(III)(dmgH)2py

B: 67-72-1
hexachloroethane

C: 54757-29-8
2-(Bromomethyl)-1,3,4-trimethylbenzene

D: 1,2,4-Trimethyl-3-(2,2,2-trichloro-ethyl)-benzene

Conditions

Conditions	Yield
In chloroform Excess of CHCl3, 50°C for 5 h;; detected by NMR spectra and GLC;;	A n/a B n/a C 5% D 95%

...Expand

: 56-23-5
tetrachloromethane

: 84784-54-3
1,4-diphenyl-2,3-benzo-7,7,8,8-tetramethyl-7,8-digermabicyclo<2,2,2>octadiene

A: 67-72-1
hexachloroethane

B: 796-30-5
1,4-diphenylnaphthalene

C: 22702-77-8
1,2-dichlorotetramethyldigermane

D: 1529-48-2
dichlorodimethylgermanium

Conditions

Conditions	Yield
In benzene Irradiation (UV/VIS); UV irradn. of a soln. of germanium compd. and CCl4 in C6H6 in a degassed sealed Pyrex tube for 3 h at room temp.; not isolated, detected by NMR, analyzed by GC and GC-MS;	A 38% B 95% C 71% D 27%

...Expand

: 115975-16-1
C24H22N2O3

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 84967-87-3
N-(β-Chlor-isopropyl)benzamid

D: 983-79-9
benzophenone azine

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C 92% D n/a

...Expand

: 93845-09-1
C26H19NO2

A: 119-61-9
benzophenone

B: 67-72-1
hexachloroethane

C: 983-79-9
benzophenone azine

D: 2051-62-9
4'-biphenyl chloride

Conditions

Conditions	Yield
With tetrachloromethane Ambient temperature; Irradiation; Yields of byproduct given;	A n/a B n/a C n/a D 88%

...Expand

Raw Materials

108-95-2

2697-95-2

79-34-5

7440-66-6

74-87-3

74-86-2

Downstream Products

75-00-3

75-07-0

2526-64-9

76-15-3

7647-01-0

819-43-2

Total:46 Page 1 of 2 1 2 Next>>

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Chemistry

Molecular structure of Hexachloroethane (CAS NO.67-72-1) is:

Product Name: Hexachloroethane
CAS Registry Number: 67-72-1
IUPAC Name: 1,1,1,2,2,2-hexachloroethane
Molecular Weight: 236.7394 [g/mol]
Molecular Formula: C₂Cl₆
XLogP3: 4.1
EINECS: 200-666-4
Melting Point: 184 °C
Storage temp.: 2-8 °C
Water Solubility: 0.05 g/L (22 °C)
Surface Tension: 42.8 dyne/cm
Density: 1.821 g/cm³
Flash Point: 61.3 °C
Enthalpy of Vaporization: 40.57 kJ/mol
Boiling Point: 186.8 °C at 760 mmHg
Vapour Pressure: 0.895 mmHg at 25°C
Stability: Stable. Non-combustible. May react with hot metals, strong oxidizing agents.
Product Categories: refrigerants;Organics;Alpha Sort;E-LAlphabetic;H;HA -HT;Volatiles/ Semivolatiles

Uses

Hexachloroethane (CAS NO.67-72-1) is comonly used as raw materials for organic synthesis,and it also can be used as degassing agents of aluminum and its alloy.Also, it can be used in most aluminium foundries around the world to remove hydrogen.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
dog	LDLo	intravenous	325mg/kg (325mg/kg)		Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934.
guinea pig	LD50	oral	4970mg/kg (4970mg/kg)		American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.
mouse	LD50	intraperitoneal	4500mg/kg (4500mg/kg)		Arzneimittel-Forschung. Drug Research. Vol. 11, Pg. 902, 1961.
rabbit	LD	oral	> 1gm/kg (1000mg/kg)		American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.
rabbit	LD50	skin	32gm/kg (32000mg/kg)		American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.
rabbit	LDLo	subcutaneous	4gm/kg (4000mg/kg)		Quarterly Journal of Pharmacy & Pharmacology. Vol. 7, Pg. 205, 1934.
rat	LCLo	inhalation	5900ppm/8H (5900ppm)	BEHAVIORAL: MUSCLE WEAKNESS	American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.
rat	LD50	oral	4460mg/kg (4460mg/kg)		American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.
rat	LDLo	intraperitoneal	2900mg/kg (2900mg/kg)		American Industrial Hygiene Association Journal. Vol. 40, Pg. 187, 1979.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. A poison by intravenous route. Moderately toxic by intraperitoneal route. Mildly toxic by ingestion. Experimental reproductive effects. Mutation data reported. Liver injury has resulted from exposure to this material. An insecticide. Slightly explosive by spontaneous chemical reaction. Dehalogenation of this material by reaction with alkalies, metals, etc., will produce spontaneously explosive chloroacetylenes. When heated to decomposition it emits highly toxic fumes of Cl⁻ and phosgene.
Hazard Codes: Harmful Xn, Dangerous N, Toxic T, Flammable F
Risk Statements: 40-51/53-36/37/38-39/23/24/25-36/38-23/24/25-11
R40:Limited evidence of a carcinogenic effect.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R36/37/38:Irritating to eyes, respiratory system and skin.
R39/23/24/25:Danger of very serious irreversible effects and Toxic by inhalation, in contact with skin and if swallowed.
R36/38:Irritating to eyes and skin.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R12:Extremely flammable.
Safety Statements: 36/37-61-45-36/37/39-26-24-16-7
S36/37:Wear suitable protective clothing and gloves.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24:Avoid contact with skin.
S16:Keep away from sources of ignition.
S7:Keep container tightly closed.
RIDADR: UN 9037
WGK Germany: 3
RTECS: KI4025000
HazardClass: 9
PackingGroup: III

Specification

Hexachloroethane , its cas register number is 67-72-1. It also can be called 1,1,1,2,2,2-Hexachloroethane ; Avlothane ; Distokal ; Egitol ; Ethane hexachloride ; Ethane, hexachloro- ; Ethylene hexachloride ; Falkitol ; Hexachlor-aethan ; Mottenhexe ; Perchloroethane ; Phenohep ; Ethane, 1,1,1,2,2,2-hexachloro- .It is a colorless, crystalline solid with a camphor-like odor.It may cause illness from inhalation or ingestion and may irritate skin, eyes and mucous membranes. When heated to high temperatures it may emit toxic fumes. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It insoluble in water.It can react with hot iron, zinc and aluminum.