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84-65-1

Basic Information
CAS No.: 84-65-1
Name: Anthraquinone
Article Data: 560
Molecular Structure:
Molecular Structure of 84-65-1 (Anthraquinone)
Formula: C14H8O2
Molecular Weight: 208.216
Synonyms: EPA Pesticide Chemical Code 122701;Hoelite;Morkit;Anthraquinone [BSI:ISO];9,10-Anthraquinone;9,10-Dioxoanthracene;Anthracene, 9,10-dihydro-9,10-dioxo-;Corbit;Anthradione;Bis-alkylamino anthraquinone;Anthrapel;9,10-Anthrachinon [Czech];9.10-Anthraquinone;anthra-9,10-quinone;anthracene-9,10-dione;Anthraquinone(AQ);
EINECS: 201-549-0
Density: 1.308 g/cm3
Melting Point: 284-286 °C(lit.)
Boiling Point: 377 °C at 760 mmHg
Flash Point: 141.4 °C
Solubility: water: <0.1 g/100 mL at 23 °C
Appearance: dull yellow powder
Hazard Symbols: IrritantXi
Risk Codes: 43-36/37/38
Safety: 36/37-37/39-26-24
PSA: 34.14000
LogP: 2.46200
Synthetic route
613-31-0

9,10-dihydroanthracene

84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With oxygen In acetone at 20℃; under 760.051 Torr; for 10h; Reagent/catalyst; Solvent; Irradiation;100%
With [bis(acetoxy)iodo]benzene; tert-butyl hydroxyperoxide; 3-chloro-benzenecarboperoxoic acid In 2,2,2-trifluoroethanol at 20℃; for 9h;99%
With 2-Picolinic acid; manganese(II) perchlorate hexahydrate; dihydrogen peroxide; sodium acetate In acetonitrile at 0 - 20℃;99%
120-12-7

anthracene

84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With nicotinium dichromate In acetic acid for 0.75h; Heating;100%
With potassium bromate In acetic acid Heating;100%
With ruthenium trichloride; dihydrogen peroxide; acetic acid100%
90-44-8

anthracen-9(10H)-one

84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With aluminum oxide; potassium permanganate; water In 1,2-dichloro-ethane for 75h; Ambient temperature;100%
With aluminum oxide; potassium permanganate for 75h;100%
With cerium(III) sulfate; barium bromate In water; acetonitrile for 20h; Heating;97%
58343-58-1

9,10-dihydro-9,10-dihydroxyanthracene

84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
In neat (no solvent) at 20℃; for 0.0333333h; Microwave irradiation;100%
With tert.-butylhydroperoxide; RhCl(PPh3)3 In benzene at 70℃; for 48h;87%
With tert.-butylhydroperoxide; RhCl(PPh3)3 In benzene at 70℃; for 48h;87%

9-methylsulfinyl-10-(methylthio)anthracene

A

624-92-0

Dimethyldisulphide

B

84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
Stage #1: 9-methylsulfinyl-10-(methylthio)anthracene With air; sulfuric acid In dichloromethane at 20℃; for 0.0833333h; Rearrangement;
Stage #2: With water; sodium hydrogencarbonate Hydrolysis;
A n/a
B 100%

1-anthracen-9-yl-ethane-1,2-diol

84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With osmium(VIII) oxide; trimethylamine-N-oxide In tetrahydrofuran; pyridine; water at 65℃;100%
100622-34-2

anthracene-9-boronic acid

84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With water; sodium hydroxide In tetrahydrofuran at 20℃; for 2h; Reagent/catalyst;99.03%
2395-97-3

9,10-dimethoxyanthracene

84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With zinc(II) nitrate; silica gel In tetrachloromethane for 0.25h; Heating;98%
With hydrogenchloride; iodosylbenzene for 0.0833333h; Oxidation;79%
With air; acetic acid Irradiation;
With bromine
With iodine
2444-68-0

9-vinylanthracene

84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With aluminum oxide; potassium permanganate In dichloromethane at 20℃; for 72h;98%
106-99-0

buta-1,3-diene

123-31-9

hydroquinone

84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With oxygen; pyrographite In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 120℃; under 760.051 Torr; for 48h; Schlenk technique; Cooling with ice;98%
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    Name: 9,10-Anthraquinone CAS NO.: 84-65-1 Molecular formula: C14H8O2 Relative molecular weight: 208.21 Appearance:faint yellow or light gray crystal Storage:Store in cool and dry place, away from sun light. Package:25kg Application: used in producin

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    Product Name: Anthraquinone MF: C14H8O2 MW: 208.21 EINECS: 201-549-0 Mol File: 84-65-1.mol Anthraquinone Structure Anthraquinone Chemical Properties Melting point 284-286 °C (lit.) Boiling point 379-381 °C (lit.) dens

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  • Casno:

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Chemistry

Molecular Structure of Anthraquinone (CAS NO.84-65-1):

Molecular Formula: C14H8O2
Molecular Weight: 208.2121
IUPAC Name: Anthracene-9,10-dione
Synonyms of Anthraquinone (CAS NO.84-65-1): Anthraquinone [BSI:ISO] ; 9,10-Anthracenedione ; 9,10-Anthrachinon ; 9,10-Anthrachinon [Czech] ; 9,10-Anthraquinone ; 9,10-Dioxoanthracene ; AI3-09073 ; Anthracene, 9,10-dihydro-9,10-dioxo- ; Bis-alkylamino anthraquinone ; CCRIS 649 ; Caswell No. 052A ; Corbit ; EINECS 201-549-0 ; EPA Pesticide Chemical Code 122701 ; HSDB 2074 ; Hoelite ; Morkit ; NSC 7957
CAS NO: 84-65-1
Classification Code: Agricultural Chemical ; Avicide ; Mutation data ; TSCA Flag T [Subject to the Section 4 test rule under TSCA] ; Tumor data
Melting Point: 284-286 °C
Index of Refraction: 1.659
Molar Refractivity: 58.66 cm3
Molar Volume: 159 cm3
Surface Tension: 55.8 dyne/cm
Density: 1.308 g/cm3
Flash Point: 141.4 °C
Enthalpy of Vaporization: 62.47 kJ/mol
Boiling Point: 377 °C at 760 mmHg
Vapour Pressure: 6.97E-06 mmHg at 25°C

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral > 5gm/kg (5000mg/kg)   Pesticide Manual. Vol. 9, Pg. 37, 1991.
quail LD50 unreported > 2gm/kg (2000mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C23, 1991.
rat LC50 inhalation > 1300mg/m3/4H (1300mg/m3)   Pesticide Manual. Vol. 9, Pg. 37, 1991.
rat LD50 intraperitoneal 3500mg/kg (3500mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(12), Pg. 27, 1977.
rat LD50 skin > 1gm/kg (1000mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A019, Pg. 1983,
rat LDLo oral 15gm/kg (15000mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 22, 1982.

Consensus Reports

 Anthraquinone (CAS NO.84-65-1) is reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes of Anthraquinone (CAS NO.84-65-1): IrritantXi
Risk Statements: 43-36/37/38 
R43: May cause sensitization by skin contact. 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 36/37-39-26-24 
S36/37: Wear suitable protective clothing and gloves. 
S39: Wear eye / face protection. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S24: Avoid contact with skin.
WGK Germany: 1
RTECS: CB4725000

Specification

1. Fire Fighting Measures 
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.  Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
2. Handling and Storage 
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation. 
Storage: Store in a cool, dry place. Store in a tightly closed container.