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| CAS No.: | 84-65-1 |
|---|---|
| Name: | Anthraquinone |
| Molecular Structure: | |
|
|
|
| Formula: | C14H8O2 |
| Molecular Weight: | 208.216 |
| Synonyms: | EPA Pesticide Chemical Code 122701;Hoelite;Morkit;Anthraquinone [BSI:ISO];9,10-Anthraquinone;9,10-Dioxoanthracene;Anthracene, 9,10-dihydro-9,10-dioxo-;Corbit;Anthradione;Bis-alkylamino anthraquinone;Anthrapel;9,10-Anthrachinon [Czech];9.10-Anthraquinone;anthra-9,10-quinone;anthracene-9,10-dione;Anthraquinone(AQ); |
| EINECS: | 201-549-0 |
| Density: | 1.308 g/cm3 |
| Melting Point: | 284-286 °C(lit.) |
| Boiling Point: | 377 °C at 760 mmHg |
| Flash Point: | 141.4 °C |
| Solubility: | water: <0.1 g/100 mL at 23 °C |
| Appearance: | dull yellow powder |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 43-36/37/38 |
| Safety: | 36/37-37/39-26-24 |
| PSA: | 34.14000 |
| LogP: | 2.46200 |
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| Conditions | Yield |
|---|---|
| With oxygen In acetone at 20℃; under 760.051 Torr; for 10h; Reagent/catalyst; Solvent; Irradiation; | 100% |
| With [bis(acetoxy)iodo]benzene; tert-butyl hydroxyperoxide; 3-chloro-benzenecarboperoxoic acid In 2,2,2-trifluoroethanol at 20℃; for 9h; | 99% |
| With 2-Picolinic acid; manganese(II) perchlorate hexahydrate; dihydrogen peroxide; sodium acetate In acetonitrile at 0 - 20℃; | 99% |
| Conditions | Yield |
|---|---|
| With nicotinium dichromate In acetic acid for 0.75h; Heating; | 100% |
| With potassium bromate In acetic acid Heating; | 100% |
| With ruthenium trichloride; dihydrogen peroxide; acetic acid | 100% |
| Conditions | Yield |
|---|---|
| With aluminum oxide; potassium permanganate; water In 1,2-dichloro-ethane for 75h; Ambient temperature; | 100% |
| With aluminum oxide; potassium permanganate for 75h; | 100% |
| With cerium(III) sulfate; barium bromate In water; acetonitrile for 20h; Heating; | 97% |
- 58343-58-1
9,10-dihydro-9,10-dihydroxyanthracene
- 84-65-1
9,10-phenanthrenequinone
| Conditions | Yield |
|---|---|
| In neat (no solvent) at 20℃; for 0.0333333h; Microwave irradiation; | 100% |
| With tert.-butylhydroperoxide; RhCl(PPh3)3 In benzene at 70℃; for 48h; | 87% |
| With tert.-butylhydroperoxide; RhCl(PPh3)3 In benzene at 70℃; for 48h; | 87% |
| Conditions | Yield |
|---|---|
| Stage #1: 9-methylsulfinyl-10-(methylthio)anthracene With air; sulfuric acid In dichloromethane at 20℃; for 0.0833333h; Rearrangement; Stage #2: With water; sodium hydrogencarbonate Hydrolysis; | A n/a B 100% |
- 84-65-1
9,10-phenanthrenequinone
| Conditions | Yield |
|---|---|
| With osmium(VIII) oxide; trimethylamine-N-oxide In tetrahydrofuran; pyridine; water at 65℃; | 100% |
- 100622-34-2
anthracene-9-boronic acid
- 84-65-1
9,10-phenanthrenequinone
| Conditions | Yield |
|---|---|
| With water; sodium hydroxide In tetrahydrofuran at 20℃; for 2h; Reagent/catalyst; | 99.03% |
| Conditions | Yield |
|---|---|
| With zinc(II) nitrate; silica gel In tetrachloromethane for 0.25h; Heating; | 98% |
| With hydrogenchloride; iodosylbenzene for 0.0833333h; Oxidation; | 79% |
| With air; acetic acid Irradiation; | |
| With bromine | |
| With iodine |
| Conditions | Yield |
|---|---|
| With aluminum oxide; potassium permanganate In dichloromethane at 20℃; for 72h; | 98% |
| Conditions | Yield |
|---|---|
| With oxygen; pyrographite In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 120℃; under 760.051 Torr; for 48h; Schlenk technique; Cooling with ice; | 98% |
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Chemistry
Molecular Structure of Anthraquinone (CAS NO.84-65-1):
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Molecular Formula: C14H8O2
Molecular Weight: 208.2121
IUPAC Name: Anthracene-9,10-dione
Synonyms of Anthraquinone (CAS NO.84-65-1): Anthraquinone [BSI:ISO] ; 9,10-Anthracenedione ; 9,10-Anthrachinon ; 9,10-Anthrachinon [Czech] ; 9,10-Anthraquinone ; 9,10-Dioxoanthracene ; AI3-09073 ; Anthracene, 9,10-dihydro-9,10-dioxo- ; Bis-alkylamino anthraquinone ; CCRIS 649 ; Caswell No. 052A ; Corbit ; EINECS 201-549-0 ; EPA Pesticide Chemical Code 122701 ; HSDB 2074 ; Hoelite ; Morkit ; NSC 7957
CAS NO: 84-65-1
Classification Code: Agricultural Chemical ; Avicide ; Mutation data ; TSCA Flag T [Subject to the Section 4 test rule under TSCA] ; Tumor data
Melting Point: 284-286 °C
Index of Refraction: 1.659
Molar Refractivity: 58.66 cm3
Molar Volume: 159 cm3
Surface Tension: 55.8 dyne/cm
Density: 1.308 g/cm3
Flash Point: 141.4 °C
Enthalpy of Vaporization: 62.47 kJ/mol
Boiling Point: 377 °C at 760 mmHg
Vapour Pressure: 6.97E-06 mmHg at 25°C
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | oral | > 5gm/kg (5000mg/kg) | Pesticide Manual. Vol. 9, Pg. 37, 1991. | |
| quail | LD50 | unreported | > 2gm/kg (2000mg/kg) | Farm Chemicals Handbook. Vol. -, Pg. C23, 1991. | |
| rat | LC50 | inhalation | > 1300mg/m3/4H (1300mg/m3) | Pesticide Manual. Vol. 9, Pg. 37, 1991. | |
| rat | LD50 | intraperitoneal | 3500mg/kg (3500mg/kg) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 21(12), Pg. 27, 1977. | |
| rat | LD50 | skin | > 1gm/kg (1000mg/kg) | "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A019, Pg. 1983, | |
| rat | LDLo | oral | 15gm/kg (15000mg/kg) | "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 22, 1982. |
Consensus Reports
Anthraquinone (CAS NO.84-65-1) is reported in EPA TSCA Inventory.
Safety Profile
Hazard Codes of Anthraquinone (CAS NO.84-65-1): 
Xi
Risk Statements: 43-36/37/38
R43: May cause sensitization by skin contact.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 36/37-39-26-24
S36/37: Wear suitable protective clothing and gloves.
S39: Wear eye / face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S24: Avoid contact with skin.
WGK Germany: 1
RTECS: CB4725000
Specification
1. Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
2. Handling and Storage
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Store in a tightly closed container.