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| CAS No.: | 87-63-8 |
|---|---|
| Name: | 2-Chloro-6-methylaniline |
| Article Data: | 19 |
| Molecular Structure: | |
|
|
|
| Formula: | C7H8ClN |
| Molecular Weight: | 141.6 |
| Synonyms: | o-Toluidine,6-chloro- (8CI);(2-Chloro-6-methylphenyl)amine;2-Amino-3-chlorotoluene; |
| EINECS: | 201-759-2 |
| Density: | 1.18 g/cm3 |
| Melting Point: | 2 °C |
| Boiling Point: | 215 °C at 760 mmHg |
| Flash Point: | 98.9 °C |
| Solubility: | immiscible with water |
| Appearance: | clear yellow to red-brown liquid |
| Hazard Symbols: |
 Xn,  Xi
|
| Risk Codes: | 36/37/38-20/21/22 |
| Safety: | 26-36-36/37/39 |
| Transport Information: | UN 3429 6.1/PG 3 |
| PSA: | 26.02000 |
| LogP: | 2.81180 |
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- 87-63-8
2-chloro-6-methylaniline
| Conditions | Yield |
|---|---|
| Stage #1: 3-chloro-5-methyl-4-nitroaniline With sulfuric acid; sodium nitrite In water at 0℃; for 0.5h; Stage #2: With hypophosphorous acid In water at 0℃; for 3h; Stage #3: With iron In water at 90℃; for 4h; Reagent/catalyst; | 82.5% |
- 69190-56-3
2-bromo-1-chloro-3-methylbenzene
- 87-63-8
2-chloro-6-methylaniline
| Conditions | Yield |
|---|---|
| With ammonium hydroxide; L-2-O-methyl-chiro-inositol; copper(II) acetate monohydrate In 1-methyl-pyrrolidin-2-one at 110℃; for 12h; | 82% |
| Conditions | Yield |
|---|---|
| With N-chloro-succinimide; 1-(3,5-bis(trifluoromethyl)phenyl)-3-((1S,2S)-2-(mesitylselanyl)-2,3-dihydro-1H-inden-1-yl)thiourea In chloroform-d1 at 0℃; for 12h; regioselective reaction; | 65% |
- 21352-09-0
N-(2-chloro-6-methylphenyl)acetamide
- 87-63-8
2-chloro-6-methylaniline
| Conditions | Yield |
|---|---|
| With hydrogenchloride In water at 50 - 55℃; for 7h; Time; | 61.7% |
- 87-63-8
2-chloro-6-methylaniline
| Conditions | Yield |
|---|---|
| With hydrogenchloride In sulfolane; water at 120℃; for 26h; | 60% |
- 31656-92-5
1-azido-2-methyl-benzene
- 87-63-8
2-chloro-6-methylaniline
| Conditions | Yield |
|---|---|
| With hydrogenchloride |
| Conditions | Yield |
|---|---|
| With sulfuric acid at 165℃; | |
| With sulfuric acid at 150 - 160℃; |
| Conditions | Yield |
|---|---|
| With hydrogenchloride |
- 150545-04-3
N-(2-chloro-6-methylphenyl)pivalamide
- 87-63-8
2-chloro-6-methylaniline
| Conditions | Yield |
|---|---|
| With hydrogen bromide for 4.5h; Heating; Yield given; |
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Chemistry
Molecular Structure of 2-Amino-3-chlorotoluene (CAS NO.87-63-8):
IUPAC Name: 2-chloro-6-methylaniline
CAS Number: 87-63-8
Molecular Formula: C7H8ClN
Molecular Weight: 141.61
EINECS: 201-759-2
Melting Point: 2°C
H bond acceptors: 1
H bond donors: 2
Freely Rotating Bonds: 1
Polar Surface Area: 3.24 Å2
Index of Refraction: 1.585
Molar Refractivity: 40.2 cm3
Molar Volume: 119.9 cm3
Surface Tension: 42.7 dyne/cm
Density: 1.18 g/cm3
Flash Point: 98.9 °C
Enthalpy of Vaporization: 45.13 kJ/mol
Boiling Point: 215 °C at 760 mmHg
Vapour Pressure: 0.151 mmHg at 25°C
Water Solubility: Immiscible
BRN: 774624
Solubility: Immiscible
InChI
InChI=1/C7H8ClN/c1-5-3-2-4-6(8)7(5)9/h2-4H,9H2,1H3
Smiles
c1(c(cccc1Cl)C)N
Product Categories: benzene derivative; Anilines, Aromatic Amines and Nitro Compounds
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| cat | LDLo | subcutaneous | 200mg/kg (200mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: ATAXIA LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Archiv fuer Hygiene und Bakteriologie. Vol. 110, Pg. 12, 1933. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Poison by subcutaneous route. Mutation data reported. When heated to decomposition it emits toxic vapors of NOx and Cl−.
Safety Information of 2-Amino-3-chlorotoluene (CAS NO.87-63-8):
Hazard Symbols:Xn
Risk Codes: 36/37/38-20/21/22
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 3429 6.1/PG 3
WGK Germany: 3
RTECS: XU5100000
HazardClass: 6.1
PackingGroup: III
Standards and Recommendations
DOT Classification: 6.1; Label: KEEP AWAY FROM FOOD
Specification
2-Amino-3-chlorotoluene , with CAS number of 87-63-8, can be called 2-Chloro-6-methylaniline ; 2-Methyl-6-chloroaniline ; 6-Chloro-2-methylaniline ; 6-Chloro-2-toluidine ; 6-Chloro-o-toluidine . It is a clear yellow to red-brown liquid. 2-Amino-3-chlorotoluene (CAS NO.87-63-8) can be used as a medicine, pesticide, dye intermediate.
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