15990-45-1Relevant articles and documents
Revisit to Henry reaction by non conventional heterogeneous and efficient catalyst for nitroalcohol synthesis
Jadhav, Swati D.,Patil, Rupesh C.,Jagdale, Ashutosh A.,Patil, Suresh S.
, p. 593 - 606 (2021/11/03)
A sustainable, green and efficient process for the synthesis of 2-nitro alcohol derivatives from different substituted aromatic aldehydes with nitroalkane by stirring at ambient temperature with high product yield is reported. Adoption of very mild reaction conditions, use of Calcined Eggshell (CES) as natural catalyst and simple workup are expected to contribute to the development of environmentally benign synthetic method for Henry (nitroaldol) reaction. CES is ecologically safe, inexpensive, and attractive heterogeneous base catalyst obtained from renewable resources, thus opening a new perspective for this process. Graphical abstract: [Figure not available: see fulltext.]
Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media
Ivanov, R. E.,Zharkov, M. N.,Zlotin, S. G.
, p. 209 - 212 (2022/02/22)
Abstract: For the first time the reactions of radical nitration of alkenes and oxiranes with nitrogen dioxide in the liquid and supercritical carbon dioxide (sc-CO2) media were carried out. Using octene-1, styrene, and their derivatives as exam
Synthesis of functionalized carbon microspheres and their catalyst activity in C—O and C—N bond formation reactions
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Page/Page column 8-9, (2019/02/14)
Disclosed herein is a simple process for functionalization/grafting of carbon microspheres obtained from bagasse with various active functional groups onto it and use of the same as catalyst for various organic reactions, having very high selectivity and conversion rate.
