100573-50-0

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 75-77-4 chloro-trimethyl-silane 
• 2408-36-8 lithium cyanide 
• 7677-24-9 trimethylsilyl cyanide 
• 104-55-2 3-phenyl-propenal 

Downstream Products

• 83575-76-2 (E)-2-Dimethylamino-4-phenyl-2-trimethylsilanyloxy-but-3-enenitrile 
• 61912-03-6 2-hydroxy-4-phenyl-3-butenenitrile 
• 70532-73-9 (Z)-4-Phenyl-2-(trimethylsilyloxy)-2-butennitril 
• 70533-15-2 (E)-4-Phenyl-2-(trimethylsilyloxy)-2-butennitril 
• 83575-64-8 C₁₃H₁₆LiNOSi 
• 772-13-4 3-phenylbutanonamide 
• 108583-48-8 trans-4-Phenyl-2-methyl-2-trimethylsiloxy-3-butenenitrile 
• 81040-00-8 (Z)-4-Phenyl-2-(trimethylsilyloxy)-2-pentennitril 
• 1896-62-4 (E)-benzalacetone 
• 1005481-97-9 C₉⁽¹³⁾CH₁₀O 
• 129029-61-4 2-hydroxy-4-phenylbut-3-enoic acid 
• 112068-21-0 rac-(E)-2-hydroxy-4-phenyl-3-butenoic acid methyl ester 
• 22422-16-8 (E)-1-bromo-4-phenylbut-3-en-2-one 
• 117535-79-2 (E)-1-(4-methoxyphenyl)-4-phenylbut-3-en-2-one 

Relevant academic research and scientific papers

Strategic design and refinement of Lewis acid-base catalysis by rare-earth-metal-containing polyoxometalates

Efficient polyoxometalate (POM)-based Lewis acid-base catalysts of the rare-earth-metal-containing POMs (TBA6RE-POM, RE = Y3+, Nd3+, Eu3+, Gd3+, Tb3+, or Dy 3+) were designed and

Easily accessible lithium compound catalyzed mild and facile hydroboration and cyanosilylation of aldehydes and ketones

Simple and readily accessible lithium compounds such as 2,6-di-tert-butyl phenolate lithium (1a), 1,1′ dilithioferrocene (1b) and nacnac lithium (1c) are found to be efficient single site catalysts for hydroboration of a range of aldehydes and ketones wit

Rasta resin-PPh3BnCl and its use in chromatography-free carbonyl cyanosilylation reactions

Rasta resin-PPhnCl, a new heterogeneous polystyrene-based phosphonium salt, has been synthesized and used to catalyze cyanosilylation reactions of aldehydes and ketones. It was found to be more efficient as a catalyst than a similar heterogeneous phosphon

Methyltriphenylphosphonium iodide catalyzes the addition of trimethylsilyl cyanide to aldehydes

Methyltriphenylphosphonium iodide catalyzes the formation of cyanohydrin trimethylsilyl ethers of aliphatic, aromatic and heterocyclic aldehydes.

Synthesis of magnetically recoverable imidazolium hydrogen carbonate and its application as an N-heterocyclic carbene catalyst to cyanosilylation of aldehydes and ketones

We prepared a magnetically recoverable imidazolium hydrogen carbonate by immobilizing an imidazolium hydrogen carbonate on magnetite and applied it as an N-heterocyclic carbene catalyst to the cyanosilylation of aldehydes and ketones. By employing the magnetite-supported imidazolium hydrogen carbonate as a catalyst, the cyanosilylation proceeded at 60?°C to provide the corresponding trimethylsilylated cyanohydrin in a fair chemical yield. Moreover, after the reaction, the magnetic catalyst was readily recovered by use of an external magnet and could be reused up to five times.

Cyanosilylation of carbonyl compounds with trimethylsilyl cyanide catalyzed by an yttrium-pillared silicotungstate dimer

An yttrium-pillared silicotungstate dimer (see picture) catalyzes the cyanosilylation of structurally diverse ketones and aldehydes with trimethylsilyl cyanide (TMSCN). The reactions proceed selectively and afford the corresponding cyanohydrin trimethylsi

OXIDATION OF α,β-UNSATURATED ALDEHYDES

A variety of methods for the conversion of α,β-unsaturated aldehydes to the corresponding acids have been explored.The best approach uses sodium chlorite and gives the desired transformation even in systems where steric hindrance and/or sensitive functionality are present.

Inorganic/organic salts as heterogeneous basic catalysts for cyanosilylation of carbonyl compounds

The addition of TMSCN to carbonyl compounds catalyzed by K 2CO3 as heterogeneous catalyst gave the corresponding cyanohydrin trimethylsilyl ethers from 20 minutes to 24 hours with 62% to 99% yields without solvent at room temperature

A tricyclic aluminum alkoxide catalyst for aldehyde trimethylsilylcyanation

Trimethylsilylcyanation of aldehydes is efficiently accomplished with a low concentration of catalyst 1 under mild conditions in acetonitrile. This protocol tolerates a variety of electron-rich, neutral, and deficient aryl, heterocyclic, and alkyl aldehyd

Trimethylsilylcyanation of aldehydes and ketones catalyzed by diorganotin dichlorides

Dibutyltin dichloride and diphenyltin dichloride functioned as effective catalysts for the trimethylsilylcyanation of aldehydes and ketones. Isolated yields ranged from 71% to 97%.