10292-66-7

Basic information

• Product Name: Benzene, 1-cyclopropyl-2-methoxy-
• CAS NO: 10292-66-7
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 10292-66-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzene, 1-cyclopropyl-2-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-cyclopropyl-2-methoxy-(10292-66-7)
• EPA Substance Registry System: Benzene, 1-cyclopropyl-2-methoxy-(10292-66-7)

Safety Data

• Hazardous Substances Data: 10292-66-7(Hazardous Substances Data)

Upstream product

• 1607-29-0 bis((1-methylcyclopropyl)formyl)peroxide 
• 100-66-3 methoxybenzene 
• 1065010-87-8 potassium cyclopropyltrifluoroborate 
• 766-51-8 2-Chloroanisole 
• 411235-57-9 cyclopropylboronic acid 
• 612-15-7 o-methoxystyrene 
• 1372474-95-7 sodium 3-(N-methyl-N-nitrososulfamoyl)benzoate 
• 578-57-4 2-bromoanisole 
• 75-09-2 dichloromethane 
• 98910-57-7 2-methoxyphenyl mesylate 
• 3698-28-0 2-allylanisole 
• 106-96-7 propargyl bromide 
• 64-19-7 acetic acid 

Downstream Products

• 28987-72-6 2-Cyclopropyl-6-nitrophenol 
• 81484-47-1 1-(3-cyclopropyl-4-methoxyphenyl)ethan-1-one 
• 81484-58-4 3,5-dinitro-2,4-dicyclopropylanisole 
• 81484-51-7 5-nitro-2,4-dicyclopropylanisole 
• 81484-45-9 2,4-dicyclopropylanisole 

Relevant articles and documents

Aryl and vinyl cyclopropanes through the in situ generation of B- cyclopropyl-9-BBN and its Suzuki-Miyaura coupling

Dihydroboration of propargyl bromide with 9-BBN-H followed by treatment of the adduct with aqueous sodium hydroxide affords the hydroxy(cycloropropyl)borate complex (1), which undergoes efficient palladium-catalyzed cross-coupling to produce a variety of aryl and vinyl cyclopropanes (2) in good to excellent yields. (C) Elsevier Science Ltd.

1,3-Oxyalkynylation of Aryl Cyclopropanes with Ethylnylbenziodoxolones Using Photoredox Catalysis

Alkynes and cyclopropanes are vital motifs in chemistry. Herein, a photoredox catalyzed 1,3-oxyalkynylation of aryl cyclopropanes with ethylnylbenziodoxolones (EBXs) in an atom-economic fashion is described. This cascade comprises single-electron oxidatio

Reductive Cyclopropanations Catalyzed by Dinuclear Nickel Complexes

Dinuclear Ni complexes supported by naphthyridine-diimine (NDI) ligands catalyze the reductive cyclopropanation of alkenes with CH2Cl2 as the methylene source. The use of mild terminal reductants (Zn or Et2Zn) confers significant functional-group tolerance, and the catalyst accommodates structurally and electronically diverse alkenes. Mononickel catalysts bearing related N chelates afford comparatively low cyclopropane yields (≤20 %). These results constitute an entry into catalytic carbene transformations from oxidized methylene precursors.

Cross-coupling of mesylated phenol derivatives with potassium cyclopropyltrifluoroborate

C-O activation of mesylates by a palladium catalyst and subsequent cross-coupling with potassium cyclopropyltrifluoroborate have been achieved with high yield. Both electron-enriched and electron-deficient aryl mesylates are suitable electrophilic partners for the Suzuki-Miyaura reaction. The scope was successfully extended to heteroaryl mesylates with yields up to 94%. (Figure presented)