10519-97-8

Basic information

• Product Name: ALLYLAMINOTRIMETHYLSILANE
• Synonyms: 1,1,1-trimethyl-N-2-propenyl-Silanamine;N-TRIMETHYLSILYLALLYLAMINE;ALLYLAMINOTRIMETHYLSILANE;Allylaminotrimethylsilane(N-Trimethylsilylallylamine);(2-Propenylamino)trimethylsilane;Allyl(trimethylsilyl)amine;N-Allyltrimethylsilylamine;Trimethyl(allylamino)silane
• CAS NO: 10519-97-8
• Molecular Formula: C₆H₁₅NSi
• Molecular Weight: 129.28
• Product Categories: Nitrogen Compounds;Organic Building Blocks;Protected Amines
• Mol File: 10519-97-8.mol
• Article Data: 7

Chemical Properties

• Melting Point: <0℃
• Boiling Point: 110-112 °C
• Flash Point: 10 °C
• Appearance: clear colorless to light yellow liquid
• Density: 0,77 g/cm3
• Vapor Pressure: 36.6mmHg at 25°C
• Refractive Index: 1.411-1.416
• Storage Temp.: Flammables area
• PKA: 12.33±0.70(Predicted)
• CAS DataBase Reference: ALLYLAMINOTRIMETHYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYLAMINOTRIMETHYLSILANE(10519-97-8)
• EPA Substance Registry System: ALLYLAMINOTRIMETHYLSILANE(10519-97-8)

Safety Data

• Hazard Codes: C-F,C
• Statements: 34-11
• Safety Statements: 45-36/37/39-25-16-26-23
• RIDADR: 2924
• TSCA: No
• Hazardous Substances Data: 10519-97-8(Hazardous Substances Data)

Usage

Chemical Properties

clear colorless to light yellow liquid

Uses

1,1,1-Trimethyl-N-2-propen-1-ylsilanamine is a potential precursor for synthesis of silicon carbonitride films. Also, it is an intermediate used in the synthesis of Z-3-(Tributylstannyl)-2-propen-1-amine (T773980).

InChI:InChI=1/C6H15NSi/c1-5-6-7-8(2,3)4/h5,7H,1,6H2,2-4H3

Upstream product

• 107-11-9 1-amino-2-propene 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 50487-71-3 4-methyl-N-(2-propenyl)benzenesulfonamide 
• 20152-18-5 1,4-bis(3-aminopropyldimethylsilyl)benzene 
• 7688-51-9 N,N-bis(trimethylsilyl)allylamine 
• 919-30-2 3-aminopropyltriethoxysilane 
• 2469-55-8 1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane 
• 26028-43-3 1,3,5-triallylhexahydro-1,3,5-triazine 
• 107-46-0 Hexamethyldisiloxane 

Relevant articles and documents

Synthesis of oligosiloxanes with 3-aminopropyl groups and their testing as surfactants in the preparation of polymer microspheres

Polydimethyl-co-methyl(3-aminopropyl)siloxanes differing in the content of amino groups and molecular weight were synthesized by two pathways, namely, by hydrosilylation of oligodimethyl-co-methylhydrоsiloxane with N-(trimethylsilyl)allylamine (TMSAA) and by copolymerization of octamethylcyclotetrasiloxane with methyl(3-aminopropyl)cyclosiloxanes. The colloid-chemical properties of the synthesized oligomers were studied. The oligosiloxanes possess high surface activity and can reduce the interfacial tension in the interface surfactant solution in toluene–water to 6.7–4.2 mJ m2. Aggregatively stable polystyrene suspensions with particle of 0.5 and 0.8 μm in diameter were obtained in the presence of the synthesized oligomers.

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N-silyl-tethered radical cyclizations: a new synthesis of gamma-amino alcohols.

[reaction: see text] Various allylic and propargylic amines bearing a protecting group (PG) have been employed in N-silyl-tethered radical cyclizations. The resulting silapyrrolidine adducts could be smoothly oxidized, creating access to gamma-amino alcoh