110674-68-5

Upstream product

• 52562-19-3 2-isopropenylaniline 
• 100-52-7 benzaldehyde 
• 15833-00-8 o-aminophenyldimethylcarbinol 
• 134-20-3 2-carbomethoxyaniline 
• 551-93-9 2-aminoacetophenone 

Downstream Products

• 1448670-20-9 5-methyl-11-phenylisoindolo[2,1-a]quinoline-7,10-dione 
• 1448670-30-1 5-methyl-13-phenylbenzo[5,6]isoindolo[2,1-a]quinoline-7,12-dione 
• 402822-97-3 1-benzyl-4-methyl-1,2-dihydro-quinoline 
• 402822-93-9 N-allyl-N-benzyl-2-(1-methylvinyl)aniline 
• 4789-76-8 4-methyl-2-phenylquinoline 
• 106012-41-3 N-[2-(1-methylethenyl)phenyl]benzamide 
• 324738-55-8 benzyl(2-isopropenyl)carbamyl chloride 
• 490035-95-5 N-benzyl-2-(prop-1-en-2-yl)benzen-amine 

Relevant academic research and scientific papers

Phenanthrenequinone-Sensitized Photocatalytic Synthesis of Polysubstituted Quinolines from 2-Vinylarylimines

Visible-light-excited 9,10-phenanthrenequinone (PQ*) was used as a photocatalyst for the synthesis of polysubstituted quinolines via the electrocyclization of 2-vinylarylimines. Up to quantitative yields of 2,4-disubstituted quinolines were received after 1 h of excitation with blue LEDs at room temperature when MgCO3 was used as an additive in DCM. On the basis of experimental and DFT studies, we propose that PQ? induces one-electron oxidation of the imine substrate that triggers the electrocyclization mechanism.

Palladium-Catalyzed Phosphoryl-Carbamoylation of Alkenes: Construction of Nonbenzylic C(sp3)?P(O)R2 Bonds via C(sp3)?Pd(II)?P(O)R2 Reductive Elimination

We report the first example of palladium-catalyzed phosphoryl-carbamoylation of alkene-tethered carbamoyl chlorides with P(O)H compounds. Both H-phosphinates and secondary phosphine oxides are compatible with this reaction. DPE-Phos was used as ligand to facilitate nonbenzylic C(sp3)?P bonds formations via C(sp3)?Pd(II)?P reductive elimination. By using this protocol, a range of phosphorylated oxindoles and lactams were obtained in moderate to good yields. (Figure presented.).

One-pot ring-closing metathesis/1,3-dipolar cycloaddition through assisted tandem ruthenium catalysis: Synthesis of a dye with isoindolo[2,1-a]quinoline structure

The one-pot tandem reaction of N-alkyl-N-allyl-2-vinylaniline derivatives with benzo- or naphthoquinones and a ruthenium-alkylidene catalyst leads to isoindolo[2,1-a]quinolines in a variety of colors, which can be altered by exchanging the substituent on the core heterocycle (see scheme). This reaction offers a new synthetic method for π-conjugated small molecules from simple aniline derivatives. Copyright

Palladium catalysed tandem cyclisation-anion capture processes. Part 8 [1]: In situ and preformed organostannanes. Carbamyl chlorides and other starter species

A sequential one-pot process is reported involving in situ, palladium catalysed, formation of a series of tributylstannyl-1,2-carbo and heterocyclic dialkylidene-5-membered rings from the corresponding 1,6-diynes and Bu 3SnH. These substrates a

Novel synthesis of oxindoles from carbamoyl chlorides via palladium catalysed cyclisation-anion capture

The synthesis of 3,3-disubstituted and 3-methyleneox-indoles by palladium(0) catalysed cyclisation of carbamoyl chlorides onto proximate alkene or alkyne groups has been achieved in good yields.