1108678-15-4Relevant articles and documents
Imido-hydrido complexes of Mo(IV): Catalysis and mechanistic aspects of hydroboration reactions
Khalimon, Andrey Y.,Farha, Philip M.,Nikonov, Georgii I.
supporting information, p. 18945 - 18956 (2015/11/11)
Imido-hydrido complexes (ArN)Mo(H)(Cl)(PMe3)3 (1) and (ArN)Mo(H)2(PMe3)3 (2) (Ar = 2,6-diisopropylphenyl) catalyse a variety of hydroboration reactions, including the rare examples of addition of HBCat to nitriles to form bis(borylated) amines RCH2N(BCat)2. Stoichiometric reactivity of complexes 1 and 2 with nitriles and HBCat suggest that catalytic reactions proceed via a series of agostic borylamido and borylamino complexes. For complex 1, catalysis starts with addition of nitriles across the Mo-H bond to give (ArN)Mo(Cl)(NCHR)(PMe3)2; whereas for complex 2 stoichiometric reactions suggest initial addition of HBCat to form the agostic complex Mo(H)2(PMe3)3(η3-NAr-HBcat) (16).
β-agostic silylamido and silyl-hydrido compounds of molybdenum and tungsten
Ignatov, Stanislav K.,Khalimon, Andrey Y.,Rees, Nicholas H.,Razuvaev, Alexei G.,Mountford, Philip,Nikonov, Georgii I.
, p. 9605 - 9622 (2009/12/25)
Reactions of bls(imldo) compounds (RN)2Mo(PMe3) n {n = 2, R = tBu; n = 3, R =2,6-dlmethylphenyl (Ar′) and 2,6-dlisopropylphenyl (Ar)) and (RN)2W(PMe 3)3 (R = 2,6-dimethylphenyl a
