1113-12-8Relevant articles and documents
Marvel,Woolford
, p. 1641 (1960)
Gas phase reactions of 1,1-dimethylsilabutadiene
Conlin, Robert T.,Namavari, Mohammad
, p. 259 - 268 (1989)
Pyrolysis of 1,1-dimethyl-1-siletene at 363 deg C in a static reaction vessel produces three major products which are formal dimers of the starting material or the reactive isomer, the siladiene.Reactions with ethylene, propene, vinyltrimethylsilane and butadiene have been examined.Mechanisms leading to the Si2C10H20 products are discussed.The influence of temperature and concentration of coreactant on competing reaction pathways is interpreted.
Zinc mediated allylations of chlorosilanes promoted by ultrasound: Synthesis of novel constrained sila amino acids
Ramesh, Remya,Reddy, D. Srinivasa
supporting information, p. 4093 - 4097 (2014/06/10)
A simple, fast and efficient method for allylation and propargylation of chlorosilanes through zinc mediation and ultrasound promotion is reported. As a direct application of the resulting bis-allylsilanes, three novel, constrained sila amino acids are prepared for the first time. The design and synthesis of the constrained sila analogue of GABA (γ-amino butyric acid) is a highlight of this work. This journal is the Partner Organisations 2014.
Reactions of dilithiobutadienes with monochlorosilanes: Observation of facile loss of organic groups from silicon
Hudrlik, Paul F.,Dai, Donghua,Hudrlik, Anne M.
, p. 1257 - 1264 (2007/10/03)
Reactions of 1,4-dilithiobutadienes (from 1,4-diiodo-1,2,3,4- tetraethylbutadiene (1) and 2,2′-dibromobiphenyl (7) with t-BuLi) with Me3SiCl gave siloles (3 and 9a) as the major products. No evidence for a disilylated butadiene was obtained. Use of higher molecular weight chlorosilanes ((allyl)Me2SiCl, BnMe2SiCl, and PhMe 2SiCl) with dibromide 7 gave dimethylsilole 9a and a silane (10a, 10b, or 10c) resulting from trapping of the organic group by the chlorosilane.
