1119010-84-2

Upstream product

• 75-15-0 carbon disulfide 
• 107-13-1 acrylonitrile 
• 62-53-3 aniline 

Downstream Products

• 33424-10-1 phenyl-(5-pyridin-4-yl[1,3,4]thiadiazol-2-yl)-amine 
• 1437-57-6 5-Phenyl-2-phenylamino-1,3,4-thiadiazol 
• 94565-97-6 5-(2-hydroxyphenyl)-2-phenylamino-2,4-dihydro-3H-1,3,4-thiadiazole 
• 74959-56-1 5-(4-methylphenyl)-N-phenyl-2-amino-1,3,4-thiadiazole 
• 38376-37-3 5-benzyl-N-phenyl-1,3,4-thiadiazol-2-amine 
• 1152-54-1 N,N-diphenyl-[1,3,4]thiadiazole-2,5-diamine 

Relevant academic research and scientific papers

OH-/silica-mediated one-pot synthesis of dithiocarbamates under solvent-free conditions

An efficient, versatile, and environmentally benign method for the synthesis of dithiocarbamates under solvent-free conditions is reported. The Michael addition of electron-deficient alkenes with alkyl or aryl amines and CS2 in the presence of OH-/silica in a one-pot three-component reaction protocol gave the corresponding dithiocarbamates in good to excellent yields. This method is suitable for a wide range of amines and a variety of Michael acceptors in solvent-free conditions. The results of the present work show the desired products in excellent yields. Copyright Taylor and Francis Group, LLC 2012.

An efficient synthesis of aryldithiocarbamic acid esters from Michael addition of electron-deficient alkenes with arylamines and CS2 in solid media alkaline Al2O3

An efficient synthesis of dithiocarbamic acid esters from Michael addition of electron-deficient alkenes with arylamines and CS2 in solid media alkaline Al2O3 was presented. This method was suitable for a wide range of amines and a variety of Michael receptors. Specially, a series of aryldithiocarbamic acid esters was obtained from arylamines through this method. The protocol offers clean reactions and high yields with simple experimental procedures. Besides, the alkaline Al2O3 could be reused.