1119010-84-2Relevant articles and documents
OH-/silica-mediated one-pot synthesis of dithiocarbamates under solvent-free conditions
Bardajee, Ghasem Rezanejade,Afsari, Hamid Samareh,Sadraei, Seyediraj,Taimoory, Seyedehmaryamdokht
experimental part, p. 871 - 878 (2012/07/31)
An efficient, versatile, and environmentally benign method for the synthesis of dithiocarbamates under solvent-free conditions is reported. The Michael addition of electron-deficient alkenes with alkyl or aryl amines and CS2 in the presence of OH-/silica in a one-pot three-component reaction protocol gave the corresponding dithiocarbamates in good to excellent yields. This method is suitable for a wide range of amines and a variety of Michael acceptors in solvent-free conditions. The results of the present work show the desired products in excellent yields. Copyright Taylor and Francis Group, LLC 2012.