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112-32-3

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112-32-3 Usage

General Description

n-Octyl formate is a chemical compound with the formula C9H18O2. It is an ester derived from formic acid and n-octanol. This colorless liquid is commonly used as a flavoring agent in the food industry, providing a fruity and sweet aroma. It is also used in the production of perfumes and fragrances. Additionally, n-octyl formate is used as a solvent in various industries and as a reagent in organic synthesis. It is important to note that n-octyl formate should be handled with caution, as it can irritate the skin and respiratory system upon exposure.

Check Digit Verification of cas no

The CAS Registry Mumber 112-32-3 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 2 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 112-32:
(5*1)+(4*1)+(3*2)+(2*3)+(1*2)=23
23 % 10 = 3
So 112-32-3 is a valid CAS Registry Number.
InChI:InChI=1/C9H18O2/c1-2-3-4-5-6-7-8-11-9-10/h9H,2-8H2,1H3

112-32-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name octyl formate

1.2 Other means of identification

Product number -
Other names OCTYL FORMATE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:112-32-3 SDS

112-32-3Relevant articles and documents

Catalyst Poisoning Phenomenon in Phase Transfer Catalysis: Effect of Aqueous Phase Concentration

Sasson, Yoel,Zahalka, Hayder Ali

, p. 1347 - 1349 (1983)

Catalyst poisoning was studied in the phase transfer-catalysed esterification of alkyl chlorides by sodium formate; the poisoning effect is minimized by use of highly concentrated formate solutions where high conversion and first order kinetics are observed.

Lipase-catalyzed transesterification of ethyl formate to octyl formate

Janssen, Leonie M.G.,Van Oosten, Remco,Paul, Caroline E.,Arends, Isabel W.C.E.,Hollmann, Frank

, p. 7 - 10 (2014)

The preparation of octyl formate via lipase-catalyzed transesterification of ethyl formate with 1-octanol is demonstrated. To shift the equilibrium of the reaction, ethyl formate was added in surplus but could be partially recovered for subsequent reactions. The same was true for the biocatalyst (Novo435), which could be reused at least 27 times. This method gives simple access to a hydrophobic formic acid ester, which can be used as a reactive organic phase in biocatalytic redox reactions. The enzymatically prepared octyl formate can be utilized by formate dehydrogenase to regenerate NADH from NAD+.

Method for preparing formate-type compound

-

Paragraph 0039; 0047; 0048, (2018/07/30)

The invention discloses a method for preparing a formate-type compound. The method comprises the following steps of: adopting an alcohol-type compound and 1,3-dihydroxyacetone as reaction raw materials, and under the existence of a composite catalyst and an oxidant, reacting for 2-48 hours in a reaction medium in a reactor at a reaction temperature of 25-100 DEG C so as to obtain the formate-typecompound. The method disclosed by the invention is simple, and is mild in reaction condition, and by the method, a target product can be obtained by low cost and high yield; the used catalyst has highcatalytic activity, and is easily separated from a reaction system to be repeatedly used; the whole process is environment-friendly, and the reaction raw material (1,3-dihydroxyacetone) is easily converted from a side product (glycerol) of biodiesel, so that the utilization of the glycerol is promoted.

Ruthenium-Catalyzed Synthesis of Dialkoxymethane Ethers Utilizing Carbon Dioxide and Molecular Hydrogen

Thenert, Katharina,Beydoun, Kassem,Wiesenthal, Jan,Leitner, Walter,Klankermayer, Jürgen

supporting information, p. 12266 - 12269 (2016/10/13)

The synthesis of dimethoxymethane (DMM) by a multistep reaction of methanol with carbon dioxide and molecular hydrogen is reported. Using the molecular catalyst [Ru(triphos)(tmm)] in combination with the Lewis acid Al(OTf)3resulted in a versatile catalytic system for the synthesis of various dialkoxymethane ethers. This new catalytic reaction provides the first synthetic example for the selective conversion of carbon dioxide and hydrogen into a formaldehyde oxidation level, thus opening access to new molecular structures using this important C1source.

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