114894-59-6

Basic information

• Product Name: ethyl (2Z)-3-(dimethylamino)prop-2-enoate
• Synonyms: ethyl (2Z)-3-(dimethylamino)prop-2-enoate
• CAS NO: 114894-59-6
• Molecular Weight: 143.186
• Mol File: 114894-59-6.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: ethyl (2Z)-3-(dimethylamino)prop-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2Z)-3-(dimethylamino)prop-2-enoate(114894-59-6)
• EPA Substance Registry System: ethyl (2Z)-3-(dimethylamino)prop-2-enoate(114894-59-6)

Safety Data

• Hazardous Substances Data: 114894-59-6(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 34780-29-5 3-oxo-propionic acid ethyl ester 
• 506-59-2 N,N-dimethylammonium chloride 
• 20353-93-9 Gold's reagent 
• 141-78-6 ethyl acetate 
• 64-18-6 formic acid 
• 124-40-3 dimethyl amine 
• 4637-24-5 N,N-dimethyl-formamide dimethyl acetal 
• 372-31-6 ethyl 4,4,4-trifluoroacetoacetate 
• 5815-08-7 tert-Butoxybis(dimethylamino)methane 
• 74119-34-9 3-Dimethylamino-2-(formylaminomethyl)acrylsaeure-ethylester 
• 4071-88-9 trimethylsilanyl-acetic acid ethyl ester 
• 34433-91-5 N-formyl-β-alanine ethyl ester 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 1429510-36-0 ethyl 5-[2-nitro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-1-[(S)-tetrahydrofuran-3-yl]-1H-pyrazole-4-carboxylate 
• 1429511-40-9 Ethyl 5-(2-amino-4-bromophenyl)-1-[(S)-tetrahydrofuran-3-yl]-1H-pyrazolo-4-carboxylate 
• 1429511-39-6 ethyl 5-[4-(6-ethoxy-2,4-dimethylpyridin-3-yl)-2-nitrophenyl]-1-[(S)-tetrahydrofuran-3-yl]-1H-pyrazole-4-carboxylate 
• 1429511-14-7 ethyl 5-[4-(6-isopropyloxy-2,4-dimethylpyridin-3-yl)-2-nitrophenyl]-1-[(S)-tetrahydrofuran-3-yl]-1H-pyrazole-4-carboxylate 
• 1429511-13-6 ethyl 5-[4-(2-isopropyloxy-3,5-dimethylpyridin-4-yl)-2-nitrophenyl]-1-[(S)-tetrahydrofuran-3-yl]-1H-pyrazole-4-carboxylate 
• 134653-70-6 ethyl 2-[(dimethylamino)methylene]-3-oxobutanoate 
• 1429511-06-7 ethyl 5-[4-(2-methoxy-3,5-dimethylpyridin-4-yl)-2-nitrophenyl]-1-[(S)-tetrahydrofuran-3-yl]-1H-pyrazole-4-carboxylate 
• 1429510-35-9 ethyl 5-(4-bromo-2-nitrophenyl)-1-[(S)-tetrahydrofuran-3-yl]-1H-pyrazole-4-carboxylate 
• 1357289-04-3 (4R,12aS)-3,4,6,8,12,12a-hexahydro-4-methyl-6,8-dioxo-7-(phenylmethoxy)-2H-pyrido[1',2':4,5]pyrazino[2,1-b][1,3]oxazine-9-carboxylic acid ethyl ester 
• 1246616-87-4 C₂₀H₂₁NO₇ 
• 1246616-84-1 C₂₂H₂₇NO₈ 
• 1246616-83-0 C₁₈H₁₉NO₆ 
• 29363-98-2 3-(4-chloro-phenyl)-isoxazole-4-carboxylic acid ethyl ester 
• 53219-65-1 diethyl-1,4-dihydro-4-phenyl-pyridine-3,5-dicarboxylate 

Relevant articles and documents

Preparation method of ethyl 3-(N,N-dimethylamino)acrylate

The invention relates to a preparation method of ethyl 3-(N,N-dimethylamino)acrylate, which comprises the following steps: carrying out heating reaction on formic acid, ethyl acetate and dimethylamineto obtain ethyl 3-(N,N-dimethylamino)acrylate and water. The preparation method of the ethyl 3-(N,N-dimethylamino)acrylate is short in reaction route, high in yield and purity and low in safety risk.

Ethyl N,N-dimethylaminoacrylate synthesis method

The invention relates to the technical field of synthesis of fine chemical intermediates, particularly to an ethyl N,N-dimethylaminoacrylate synthesis method, which comprises that ethyl acetate, carbon monoxide and dimethylamine are used as starting raw materials, and are subjected to a reaction under the action of a solid alkali catalyst to form the target product ethyl N,N-dimethylaminoacrylate,wherein the solid alkali catalyst is preferably a supported solid alkali catalyst. According to the present invention, the problems that the raw material source is difficult, the price is expensive,the process condition is harsh, the three-waste amount is high, the yield is low, the cost is high, the method is not suitable for industrial production and the like in the prior art are solved; and the synthesis method of the present invention has characteristics of convenient raw material source, low cost, environmentally-friendly reaction condition, substantially-reduced side-product, high total yield, high raw material utilization rate, low production cost and high product purity, and is suitable for large-scale industrial continuous production.

Gold nanoparticles on OMS-2 for heterogeneously catalyzed aerobic oxidative α,β-dehydrogenation of β-heteroatom-substituted ketones

In the presence of Au nanoparticles supported on manganese oxide OMS-2 (Au/OMS-2), various kinds of β-heteroatom-substituted α,β-unsaturated ketones (heteroatom = N, O, S) can be synthesized through α,β-dehydrogenation of the corresponding saturated ketones using O2 (in air) as the oxidant. The catalysis of Au/OMS-2 is truly heterogeneous, and the catalyst can be reused.