118315-76-7

Basic information

• Product Name: 2-Propenoic acid, 3-(3-chlorophenyl)-, ethyl ester, (2Z)-
• CAS NO: 118315-76-7
• Molecular Formula: C11H11ClO2
• Molecular Weight: 210.66
• Mol File: 118315-76-7.mol
• Article Data: 38

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(3-chlorophenyl)-, ethyl ester, (2Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(3-chlorophenyl)-, ethyl ester, (2Z)-(118315-76-7)
• EPA Substance Registry System: 2-Propenoic acid, 3-(3-chlorophenyl)-, ethyl ester, (2Z)-(118315-76-7)

Safety Data

• Hazardous Substances Data: 118315-76-7(Hazardous Substances Data)

Upstream product

• 108-90-7 chlorobenzene 
• 140-88-5 ethyl acrylate 
• 873-63-2 m-chlorobenzyl alcohol 
• 105-36-2 ethyl bromoacetate 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 17577-28-5 (ethoxycarbonylmethyl)triphenylphosphonium chloride 
• 4152-90-3 m-chlorobenzylamine 
• 587-04-2 m-Chlorobenzaldehyde 
• 188945-44-0 ethyl 2-[bis(2-isopropylphenoxy)phosphoryl]acetate 
• 925-60-0 n-propyl acrylate 
• 625-99-0 3-iodochlorobenzene 
• 456-39-3 3-chlorobenzenediazonium tetrafluoroborate 
• 141-78-6 ethyl acetate 
• 65946-56-7 1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene 

Downstream Products

• 7116-35-0 ethyl 3-(3-chlorophenyl)propanoate 
• 1431372-69-8 1-chloro-3-[(E)-3-(2-methylallyloxy)prop-1-enyl]benzene 
• 1431372-53-0 3-(3-chlorophenyl)-2,2-dimethylcyclopentanone 
• 14290-89-2 (Z)-3-(3-chlorophenyl)acrylic acid 
• 69310-70-9 7-(3-chloro-phenyl)-2,4-dioxo-1,3,4,5,6,7-hexahydro-2H-pyrano[2,3-d]pyrimidine-6-carboxylic acid ethyl ester 
• 52925-45-8 3-chlorocinnamyl bromide 
• 1187248-67-4 C₁₁H₁₁BrClN₃O₂ 
• 63204-33-1 5-(3-chlorobenzyl)-2-methylthio-4-pyrimidone 
• 63204-32-0 5-(3-chlorobenzyl)-1,2-dihydro-2-thioxo-4(3H)-pyrimidinone 
• 63204-15-9 2-[2-(5-Methyl-4-imidazolylmethylthio)ethylamino]-5-(3-chlorobenzyl)-4-pyrimidone dihydrochloride 
• 71621-61-9 2-[(3-chlorophenyl)-(2-methoxyphenoxy)-methyl]morpholine 
• 863969-86-2 4-nitro-benzenesulfonic acid 2-[[3-(3-chloro-phenyl)-2-hydroxy-3-(2-methoxy-phenoxy)-propyl]-(4-nitro-benzenesulfonyl)-amino]-ethyl ester 
• 863969-85-1 toluene-4-sulfonic acid 2-[[3-(3-chloro-phenyl)-2-hydroxy-3-(2-methoxy-phenoxy)-propyl]-(toluene-4-sulfonyl)-amino]-ethyl ester 

Relevant articles and documents

Heterogeneous Heck reaction catalyzed by Pd/C in ionic liquid

Pd/C-catalyzed Heck reactions of aryl halides with olefins proceeded in moderate to satisfactory yields in ionic liquid [bmim]PF6. The ionic liquid involving a catalyst was easily recycled.

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1-Aryl triazenes upon treatment with TFA or HBF4 undergo Heck reaction via in-situ generated aryldiazonium salts.

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Rh(III)-Catalyzed Enaminone-Directed C-H Coupling with α-Diazo-α-phosphonoacetate for Reactivity Discovery: Fluoride-Mediated Dephosphonation for C-C Coupling Reactions

Rh(III)-catalyzed enaminone-directed C-H coupling with α-diazo-α-phosphonoacetate has been used for the identification of fluoride-mediated dephosphonation C-C coupling reactivity for the synthesis of 4-hydroxy-1-naphthoates. Intermolecular C-C coupling of α-phosphonoacetate and benzaldehyde for (E)-selective α,β-unsaturated ester synthesis has also been achieved.

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