925-60-0

Basic information

• Product Name: 1-Propyl acrylate
• Synonyms: Acrylicacid, propyl ester (6CI,7CI,8CI); NSC 32620; Propyl 2-propenoate; Propylacrylate
• CAS NO: 925-60-0
• Molecular Formula: C₆H₁₀O₂
• Molecular Weight: 0
• EINECS: 213-120-5
• Mol File: 925-60-0.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 120.9°Cat760mmHg
• Flash Point: 26.1°C
• Appearance: /
• Density: 0.904g/cm³
• CAS DataBase Reference: 1-Propyl acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propyl acrylate(925-60-0)
• EPA Substance Registry System: 1-Propyl acrylate(925-60-0)

Safety Data

• Statements: R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.
• Safety Statements: S16:Keep away from sources of ignition - No smoking.; S26:In case of contact with eyes, rinse immediately with plenty of
• Hazardous Substances Data: 925-60-0(Hazardous Substances Data)

Usage

General Description

1-Propyl acrylate is a colorless liquid that is used as a chemical building block in the production of polymers, coatings, adhesives, and other industrial products. It is also used as a reactive diluent in UV-curable coatings and inks. 1-Propyl acrylate is highly flammable and can cause skin and eye irritation upon contact. It is important to handle and store this chemical with care to avoid accidents and exposure. Additionally, 1-Propyl acrylate has been identified as a potential respiratory sensitizer, and exposure to high concentrations of this chemical may cause respiratory irritation. Proper ventilation and personal protective equipment should be used when working with 1-Propyl acrylate to minimize the risk of exposure and health hazards.

InChI:InChI=1/C6H10O2/c1-3-5-8-6(7)4-2/h4H,2-3,5H2,1H3

Upstream product

• 20473-73-8 2-acetoxy-propionic acid propyl ester 
• 79762-76-8 2,3-dibromo-propionic acid propyl ester 
• 71-23-8 propan-1-ol 
• 814-68-6 acryloyl chloride 
• 74-86-2 acetylene 
• 201230-82-2 carbon monoxide 
• 106-94-5 propyl bromide 
• 79-10-7 acrylic acid 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 14144-41-3 β-Propoxy-propionsaeure-propylester 
• 5349-56-4 3-Methoxy-propionsaeure-propylester 
• 106-19-4 di-n-propyl adipate 
• 139450-08-1 Propyl 2-iodo-3-p-toluenesulphonylpropanoate 

Relevant articles and documents

Phosphine-Catalyzed Cascade Annulation of MBH Carbonates and Diazenes: Synthesis of Hexahydrocyclopenta[c]pyrazole Derivatives

A phosphine-catalyzed cascade annulation of Morita-Baylis-Hillman (MBH) carbonates and diazenes was achieved, giving tetrahydropyrazole-fused heterocycles bearing two five-membered rings in moderate to excellent yields. The reaction underwent an unprecedented reaction mode of MBH carbonates, in which two molecules of MBH carbonates were fully merged into the ring system.

Synthesis of Esters by Functionalisation of CO2

The invention relates to a method for (I) producing a carboxylic ester of formula (I). Said method comprises the steps of: a) bringing an organosilane/borane of formula Si or B into contact with CO2, in the presence of a catalyst and an electrophilic compound of formula (III), the groups R1, R2, R3, R4, R5, Y, and M′ being as defined in claim 1; and optionally b) recovering the compound of formula (I) produced.

Increased activity of enzymatic transacylation of acrylates through rational design of lipases

A rational design approach was used to create the mutant Candida antarctica lipase B (CALB, also known as Pseudozyma antarctica lipase B) V190A having a kcat three times higher compared to that of the wild type (wt) enzyme for the transacylation of the industrially important compound methyl methacrylate. The enzymatic contribution to the transacylation of various acrylates and corresponding saturated esters was evaluated by comparing the reaction catalysed by CALB wt with the acid (H2SO4) catalysed reaction. The performances of CALB wt and mutants were compared to two other hydrolases, Humicola insolens cutinase and Rhizomucor mihei lipase. The low reaction rates of enzyme catalysed transacylation of acrylates were found to be caused mainly by electronic effects due to the double bond present in this class of molecules. The reduction in rate of enzyme catalysed transacylation of acrylates compared to that of the saturated ester methyl propionate was however less than what could be predicted from the energetic cost of breaking the π-system of acrylates solely. The nature and concentration of the acyl acceptor was found to have a profound effect on the reaction rate.