127029-79-2Relevant articles and documents
Pd0-Catalyzed Four-Component Reaction of Aryl Halide, CO, N-Tosylhydrazone, and Amine
Liu, Yiyang,Zhang, Zhen,Zhang, Songnan,Zhang, Yan,Wang, Jianbo,Zhang, Zhenhua
, p. 3658 - 3663 (2018)
A Pd0-catalyzed four-component cascade reaction of an aryl halide, CO, an N-tosylhydrazone, and an amine affording α-amino ketone has been developed. This reaction involves a sequential carbonylation, metal carbene migratory insertion, and amination. Control experiments and DFT calculations further reveal the reaction sequence and chemoselectivity of individual components in this cascade process.
Unusual redox behavior in the photoinduced electron-transfer reactions of amino ketones
Bergmark, William R.,Dewan, Charlotte,Whitten, David G.
, p. 8810 - 8812 (2007/10/02)
Irradiation of a wet benzene solution of 1,2-diphenyl-2-piperidino-l-ethanone and 9,10-dicyanoanthracene leads to the formation of benzil and deoxybenzoin. We have interpreted these products as arising from deprotonation leading to net oxidation coupled with reductive elimination. The latter pathway is noteworthy in that we show reductive elimination of an electron donor can be a chief consequence of photochemical single electron transfer (SET) quenching.
