2431-23-4

Basic information

• Product Name: Ethanone, 2-hydroxy-1-(4-methylphenyl)-2-phenyl-
• CAS NO: 2431-23-4
• Molecular Formula: C15H14O2
• Molecular Weight: 226.275
• Mol File: 2431-23-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Ethanone, 2-hydroxy-1-(4-methylphenyl)-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 2-hydroxy-1-(4-methylphenyl)-2-phenyl-(2431-23-4)
• EPA Substance Registry System: Ethanone, 2-hydroxy-1-(4-methylphenyl)-2-phenyl-(2431-23-4)

Safety Data

• Hazardous Substances Data: 2431-23-4(Hazardous Substances Data)

Upstream product

• 4410-31-5 (RS)-mandelamide 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 1075-47-4 4-methylphenylglyoxal 
• 71-43-2 benzene 
• 106-38-7 para-bromotoluene 
• 532-28-5 (RS)-mandelonitrile 
• 2001-28-7 2-phenyl-1-p-tolyl-ethanone 
• 25438-37-3 phenyl(trimethylsiloxy)acetonitrile 
• 52939-89-6 5-phenyl-4-p-tolyl-2,5-dihydro-oxazole 
• 7446-70-0 aluminium trichloride 
• 3235-02-7 p-methylbenzaldehyde oxime 
• 2431-02-9 2-hydroxy-1-phenyl-2-p-tolyl-ethanone 
• 56637-44-6 2-(4-methylphenyl)-1,3-dithiane 
• 1569271-99-3 phenyl(2-p-tolyl-1,3-dithian-2-yl)methanol 

Downstream Products

• 41104-54-5 2-chloro-1-(4-methylphenyl)-2-phenyl-1-ethanone 
• 100-52-7 benzaldehyde 
• 99-94-5 p-Toluic acid 
• 127029-79-2 2-morpholinyl-2-phenyl-1-(4-methylphenyl)-1-ethanone 
• 62137-65-9 (+)-(1R,2S)-cis-1-(4-methylphenyl)-2-phenylethylene oxide 
• 73908-27-7 (1R,2S)-2-Chloro-2-phenyl-1-p-tolyl-ethanol 
• 2431-02-9 2-hydroxy-1-phenyl-2-p-tolyl-ethanone 
• 5359-57-9 ethyl α-phenyl-α-(4-methylphenyl)acetate 
• 62137-63-7 threo-p-Methyldiphenylethandiol 
• 2431-00-7 p-methylbenzil 

Relevant articles and documents

Synthesis of chiral α-diarylacetic esters by stereospecific 1,2-aryl migration promoted by in situ generated acetals from benzoins

A simple protocol for the synthesis of α-diarylacetic esters from benzoins is described. In situ generated acetal assists rapid 1,2-aryl migration in a stereospecific manner, paving the way to make enantioenriched α-diarylacetic esters from easily accessi

An eco-friendly method for synthesis of symmetrical and unsymmetrical benzoin derivatives

A rapid, highly efficient and mild green synthesis of symmetrical and unsymmetrical benzoin derivatives was achieved from the reaction of benzaldehyde derivatives with potassium cyanide in dimethyl sulfoxide under argon gas and ultrasound. This simple method affords benzoin derivatives at room temperature in short reaction times with high yield and purity.

Direct Formation of Benzoins from Diarylmethanones via a Rearrangement Reaction Promoted by Samarium Metal in DMF

Diarylmethanones react readily with DMF when promoted by samarium metal in DMF with TMSCl or iodine as an activator, to afford benzoins in good to excellent yields via rearrangement of aryl groups. As for asymmetric diarylmethanones, products resulting from the migration of either aryl group were obtained, where the migration of aryl groups shows certain priority.