13056-98-9

Basic information

• Product Name: 1-(3-phenyl)-3,3-diethyltriazene
• Synonyms: 1-(3-phenyl)-3,3-diethyltriazene;1-PHENYL-3,3-DIETHYLTRIAZENE;3,3-Diethyl-1-phenyltriazene
• CAS NO: 13056-98-9
• Molecular Formula: C₁₀H₁₅N₃
• Molecular Weight: 177.28
• Mol File: 13056-98-9.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 299.18°C (rough estimate)
• Flash Point: 99.8°C
• Appearance: /
• Density: 1.0940 (rough estimate)
• Vapor Pressure: 0.036mmHg at 25°C
• Refractive Index: 1.6250 (estimate)
• CAS DataBase Reference: 1-(3-phenyl)-3,3-diethyltriazene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(3-phenyl)-3,3-diethyltriazene(13056-98-9)
• EPA Substance Registry System: 1-(3-phenyl)-3,3-diethyltriazene(13056-98-9)

Safety Data

• Hazardous Substances Data: 13056-98-9(Hazardous Substances Data)

Usage

General Description

1-(3-phenyl)-3,3-diethyltriazene is a chemical compound with the molecular formula C11H16N4. It belongs to the class of organic compounds known as trizenes, which are compounds containing a triazene group, a nitrogen-nitrogen double bond with a nitrogen attached to each carbon. It is used as a reagent in chemical synthesis, and its main application is in the preparation of potential anticancer agents. The compound is a clear, colorless to light yellow liquid with a faint amine odor, and it is insoluble in water but soluble in organic solvents. 1-(3-phenyl)-3,3-diethyltriazene should be handled with care as it is toxic and may cause irritation to the respiratory system, skin, and eyes.

InChI:InChI=1/C10H15N3/c1-3-13(4-2)12-11-10-8-6-5-7-9-10/h5-9H,3-4H2,1-2H3/b12-11+

Upstream product

• 100-59-4 phenylmagnesium chloride 
• 109-89-7 diethylamine 
• 62-53-3 aniline 
• 100-34-5 benzene diazonium chloride 

Downstream Products

• 21572-75-8 diphenylmethyl tert-butyl nitroxide 
• 108-86-1 bromobenzene 
• 591-50-4 iodobenzene 
• 71-43-2 benzene 
• 108-95-2 phenol 
• 993-63-5 hexaethyl distannane 
• 1709-50-8 N,N-diethylbenzenesulfonamide 
• 98-09-9 benzenesulfonyl chloride 
• 351186-42-0 N‐morpholinobenzenesulfonamide 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 3651-02-3 4-phenylazo-1-naphthol 
• 833-50-1 2-phenylbenzo[d]oxazole 
• 52179-66-5 1,2-diphenylimidazole 
• 3558-24-5 1-methyl-2-phenyl-1H-indole 

Relevant articles and documents

KINETICS AND MECHANISM OF ACID CATALYZED DECOMPOSITION OF 1-PHENYL-3,3-DIALKYLTRIAZENES

Five model 1-phenyl-3,3-dialkyltriazenes (methyl, ethyl, 2-propyl, butyl, cyclohexyl) have been synthesized and their acid-catalyzed decomposition kinetics have been investigated spetrophotometrically in aqueous ethanol (40 vol.percent) with pivalic acid as the catalyst.The results show that the rate-determining step is catalyzed by the proton.The decrease in the observed rate constant at higher concentrations of pivalic acid is explained by the formation of an unreactive complex of the nondissociated acid and respective triazene.The steric effect of alkyl groups on the catalytic rat constants is discussed.

Ionic Liquid Promoted Diazenylation of N-Heterocyclic Compounds with Aryltriazenes under Mild Conditions

An efficient, mild, and metal-free approach to direct diazenylation of N-heterocyclic compounds with aryltriazenes using Br?nsted ionic liquid as a promoter has been developed for the first time. Many N-heterocyclic azo compounds were synthesized in good to excellent yields at room temperature under an open atmosphere. Notably, the promoter 1,3-bis(4-sulfobutyl)-1H-imidazol-3-ium hydrogen sulfate could be conveniently recycled and reused with the same efficacies for at least four cycles.

Synthesis of triazenes by using aryl diazonium silica sulfates under mild conditions

An efficient, fast and straightforward procedure for the synthesis of aryltriazenes is described in the present paper by using aryl diazonium silica sulfates and secondary amines. Using the present method, different kinds of aryl diazonium silica sulfates